File name: Pandora184s1_CapeElizabethME_20221112_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T202453.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20221112_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20221112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221112T160749.2Z 8351.672097 432 1 46.73 2 61.50 175.34 93.62 313.08 0.00 1 0.00 1 0 17 1.804e-02 9.750e-03 1.198e-02 3.848e-03 2.140279e-01 1.938883e-03 2.657732e-03 -6.000000e+00 1.034817e-02 222.94 -2.00 3.57 -2.00 317.60 0.00e+00 1.173946e-03 2.981150e-04 4.336998e-04 -6.000000e+00 4.577491e-04 278.64 -2.00 20.00 -2.00 316.94 0.00e+00 2.086 0.000 302.00 328.00 3 5.0296e+00 5.0930e-03 2.3339e-02 -6.0000e+00 2.5456e-02 6.6523e-02 5.7542e-03 1.0958e-02 -6.0000e+00 2.7714e-02 -1.9838e-03 3.4917e-03 5.4857e-03 -6.0000e+00 1.6529e-02 -7.5332e-03 1.7278e-03 1.6788e-03 -6.0000e+00 7.0830e-03 3.4408e-04 -2.7192e-04 1.1835e-04 1.8746e-05 -6.0000e+00 5.1595e-04 -6.3100e-03 -1.0894e-05 12 8 8 10 0 0 99.99 22.41 0.52 -0.00631 -0.00835 55 15 1 5 0 849.530 26.51 20.00 22.41 22.39 20.6 1012.44 900000 -1460 4313 -3676 -41 -1831 -1616 -1929 -2511 -5656 -3012 -3119 -8676 -4454 54 -331 -2953 1292 2352 3906 -856 2242 633 3545 -1191 3639 782 -912 -753 135 -219 4047 334 -282 -3857 -824 -4383 -3203 -27 1524 -1756 123 -1610 148 -880 1806 -590 587 -1068 -1035 -151 353 1143 515 -258 251 932 212 300 -298 63 1120 2570 1821 1528 -118 -1029 -802 -69 1010 1381 577 2304 -49 1708 324 -1118 -2729 -1776 -1252 -1489 -1922 -1704 -1692 -827 -263 827 642 1923 561 760 -450 -1041 -2166 -666 -1410 -103 499 728 -649 -116 -1824 -1941 -2154 -640 -979 -582 -919 -243 715 1034 1196 648 358 -253 -706 -134 -304 175 1010 796 1075 659 994 -58 617 -1221 96 86 532 -783 -103 -434 -379 -29 395 222 499 272 362 -125 -612 -1379 900000 -182 530 -475 -5 -192 -169 -220 -320 -797 -416 -429 -1347 -749 10 -67 -654 282 526 887 -209 530 152 854 -315 953 213 -243 -186 32 -52 987 91 -81 -1107 -218 -1247 -1020 -10 644 -855 62 -857 79 -473 942 -311 297 -534 -510 -83 187 698 302 -158 156 641 147 205 -203 43 808 1975 1505 1288 -95 -769 -568 -49 796 1199 535 2131 -45 1465 256 -807 -1855 -1198 -919 -1229 -1762 -1677 -1750 -900 -306 1008 816 2438 704 892 -488 -1033 -2049 -634 -1467 -117 622 970 -883 -149 -2208 -2209 -2474 -776 -1273 -790 -1308 -359 1106 1678 1977 1047 543 -355 -923 -171 -398 243 1494 1225 1652 994 1441 -81 811 -1552 118 111 730 -1146 -154 -663 -596 -49 686 399 915 505 663 -223 -1058 -2345 SS 20221112T161745.8Z 8351.679002 435 1 46.54 2 61.40 178.03 94.88 314.80 0.00 1 0.00 1 0 17 2.254e-02 9.327e-03 1.060e-02 3.575e-03 2.189812e-01 1.787561e-03 2.690996e-03 -6.000000e+00 1.293694e-02 222.94 -2.00 3.57 -2.00 317.34 0.00e+00 1.095329e-03 2.618143e-04 2.695424e-04 -6.000000e+00 5.718017e-04 278.64 -2.00 20.00 -2.00 316.68 0.00e+00 2.079 0.000 302.00 328.00 3 5.1626e+00 4.6802e-03 2.3403e-02 -6.0000e+00 3.1825e-02 8.5444e-02 5.2801e-03 1.1219e-02 -6.0000e+00 3.4640e-02 -1.4049e-02 3.1932e-03 5.5909e-03 -6.0000e+00 2.0660e-02 -1.5982e-03 1.5824e-03 1.7232e-03 -6.0000e+00 8.8583e-03 2.9891e-04 2.6110e-04 1.0877e-04 1.9251e-05 -6.0000e+00 6.4457e-04 -7.8331e-03 9.8370e-05 11 8 0 10 0 0 99.95 22.41 0.26 -0.00783 -0.00587 22 6 1 5 0 2115.250 26.51 20.00 22.41 24.04 21.0 1026.96 900000 1694 940 -2340 -9655 -5438 -10454 8015 -7113 -1893 -4072 -8414 -3252 -3272 -1114 2711 -2143 1820 441 3847 88 4293 1930 4157 1526 -58 349 -1228 -490 562 2124 3079 -153 -338 -2946 -3051 -3080 -1092 171 564 124 -298 -608 333 -254 1290 264 487 -835 -1067 178 -62 1287 -322 1001 -158 937 -899 -771 -159 1062 505 1330 1501 817 -106 -1151 -1050 272 1232 1113 759 1677 1341 631 -1813 108 -3791 -1831 -2743 -1722 -819 -1471 -1701 108 -29 456 1390 1929 560 -99 111 -1012 -1007 -779 -242 -721 1129 107 -38 -245 -1163 -1824 -747 -1110 -1288 -1117 -330 -678 510 789 1405 832 306 -197 -403 -1083 92 -500 940 700 849 835 977 301 726 -956 376 742 -129 -453 -277 -829 -136 68 519 -60 431 415 -100 52 -486 -1053 900000 212 124 -310 -1242 -612 -1232 853 -981 -265 -587 -1258 -493 -560 -212 552 -485 408 104 900 22 1022 470 1021 403 -16 98 -336 -136 148 558 853 -47 -109 -944 -930 -972 -382 70 270 66 -170 -359 198 -152 757 155 276 -466 -589 99 -37 800 -213 677 -110 656 -642 -542 -110 736 372 1049 1262 704 -87 -876 -757 198 983 983 713 1583 1240 555 -1486 78 -2639 -1252 -2071 -1443 -753 -1465 -1785 118 -34 565 1774 2476 712 -119 122 -1017 -954 -752 -252 -835 1416 145 -53 -320 -1416 -2100 -856 -1367 -1698 -1539 -471 -1017 727 1180 2130 1234 470 -279 -532 -1405 122 -708 1405 1089 1320 1269 1429 420 961 -1222 467 960 -180 -666 -420 -1282 -215 114 907 -99 725 705 -168 94 -844 -1794 SS 20221112T163119.7Z 8351.688422 442 1 44.19 2 61.39 181.71 96.52 317.20 0.00 1 0.00 1 0 17 1.184e-02 7.273e-03 1.091e-03 4.061e-04 2.156034e-01 2.041070e-04 2.637188e-03 -6.000000e+00 6.792603e-03 222.94 -2.00 3.57 -2.00 317.12 0.00e+00 8.513880e-04 2.804820e-05 2.012811e-04 -6.000000e+00 3.002907e-04 278.64 -2.00 20.00 -2.00 316.47 0.00e+00 2.079 0.000 302.00 328.00 3 1.4103e+00 5.3072e-04 2.3293e-02 -6.0000e+00 1.6710e-02 3.8617e-02 5.9739e-04 1.0989e-02 -6.0000e+00 1.8189e-02 -7.1431e-03 3.5670e-04 5.4662e-03 -6.0000e+00 1.0848e-02 -4.5146e-03 1.7489e-04 1.6484e-03 -6.0000e+00 4.6507e-03 1.3079e-02 3.5575e-05 1.2307e-05 1.8522e-05 -6.0000e+00 3.3851e-04 -7.7721e-03 5.5697e-05 12 9 1 12 1 1 99.97 22.45 0.35 -0.00777 -0.00750 820 230 1 5 0 53.620 26.51 20.00 22.45 25.95 20.8 1039.39 900000 -423 -375 -2020 -3472 -3264 -2904 -1465 -275 -1551 -3514 -3407 -2205 -1252 -26 798 37 744 1147 1507 1676 1001 1459 1192 919 638 116 -880 -1107 -903 262 794 1030 -216 -3068 -3723 -3260 -2284 -750 -244 -471 -627 -142 -56 161 457 147 -55 -239 -392 395 758 969 870 833 557 874 215 84 49 471 1041 1680 1876 1151 -268 -789 -951 -97 1124 803 1065 836 792 482 -247 -1023 -1843 -1822 -1283 -1568 -1289 -1916 -1703 -996 -267 217 804 887 976 490 161 -671 -645 -497 -229 39 807 483 -147 -643 -1182 -1392 -716 -742 -1225 -852 -529 -272 569 766 822 580 192 -212 -402 -136 -39 381 588 472 491 686 638 588 289 -258 103 293 -44 17 -477 -326 -327 136 176 257 399 377 -91 -157 -615 -986 900000 -56 -52 -303 -477 -409 -362 -196 -41 -249 -580 -558 -380 -241 -6 190 9 194 307 415 473 284 412 349 283 205 38 -279 -328 -255 74 238 330 -74 -1041 -1209 -1093 -859 -329 -126 -271 -348 -81 -33 103 289 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