File name: Pandora184s1_CapeElizabethME_20230117_L2Fit_fout2c4d20221222p1-8.txt File generation date: 20260323T203634.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v4d20221222.txt Level 1 file used: Pandora184s1_CapeElizabethME_20230117_L1_smca1c4d20221222p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20230117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0587 305.1998 305.3408 305.4818 305.6228 305.7638 305.9048 306.0458 306.1867 306.3277 306.4686 306.6095 306.7505 306.8914 307.0323 307.1732 307.3140 307.4549 307.5958 307.7366 307.8774 308.0183 308.1591 308.2999 308.4407 308.5814 308.7222 308.8630 309.0037 309.1445 309.2852 309.4259 309.5666 309.7073 309.8480 309.9887 310.1293 310.2700 310.4106 310.5513 310.6919 310.8325 310.9731 311.1137 311.2543 311.3948 311.5354 311.6759 311.8165 311.9570 312.0975 312.2380 312.3785 312.5190 312.6595 312.7999 312.9404 313.0808 313.2212 313.3616 313.5021 313.6424 313.7828 313.9232 314.0636 314.2039 314.3443 314.4846 314.6249 314.7652 314.9055 315.0458 315.1861 315.3263 315.4666 315.6068 315.7471 315.8873 316.0275 316.1677 316.3079 316.4481 316.5882 316.7284 316.8685 317.0087 317.1488 317.2889 317.4290 317.5691 317.7092 317.8492 317.9893 318.1293 318.2694 318.4094 318.5494 318.6894 318.8294 318.9694 319.1093 319.2493 319.3892 319.5292 319.6691 319.8090 319.9489 320.0888 320.2287 320.3686 320.5084 320.6483 320.7881 320.9279 321.0677 321.2075 321.3473 321.4871 321.6269 321.7666 321.9064 322.0461 322.1858 322.3255 322.4652 322.6049 322.7446 322.8843 323.0239 323.1636 323.3032 323.4428 323.5824 323.7220 323.8616 324.0012 324.1408 324.2803 324.4199 324.5594 324.6989 324.8384 324.9779 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230117T135753.2Z 8417.581865 241 1 45.53 2 75.53 138.56 68.45 200.89 0.00 1 0.00 1 0 17 3.052e-01 1.375e-02 2.507e-01 9.216e-03 4.885651e-01 4.848939e-03 5.506599e-03 -6.000000e+00 1.763989e-01 223.56 -2.00 3.57 -2.00 320.50 0.00e+00 2.777750e-03 1.766189e-03 5.025931e-04 -6.000000e+00 8.050760e-03 272.93 -2.00 20.00 -2.00 319.99 0.00e+00 3.920 0.001 302.00 328.00 3 4.2266e+00 1.4407e-02 4.6474e-02 -6.0000e+00 4.3584e-01 8.9216e-02 1.7923e-02 2.6477e-02 -6.0000e+00 4.7669e-01 -3.0728e-02 1.7235e-02 1.3460e-02 -6.0000e+00 2.8075e-01 3.4864e-03 8.7667e-03 6.0891e-03 -6.0000e+00 1.1808e-01 8.8366e-05 6.4914e-04 2.8892e-04 5.9272e-05 -6.0000e+00 8.9257e-03 -1.2615e-03 1.1430e-04 12 8 8 10 0 0 99.70 22.31 0.85 -0.00126 0.00362 13 4 1 5 0 3501.690 26.41 20.00 22.31 11.63 20.4 977.10 900000 -34604 -4582 232157 4242 900000 -2671 900000 -107449 -55813 900000 202128 33993 -1355 -20676 -2406 24223 -31339 39301 21855 16109 4197 -32032 5770 -36787 13095 9986 -34354 -13172 -14698 -9300 -15443 2455 -26795 -11911 -4693 4540 -3733 9441 2738 7744 4789 5812 177 8807 4993 -2942 -10555 2806 4405 1901 11821 5341 10750 2989 5348 -3059 5530 5222 8204 1841 4024 9660 1033 832 1977 -1579 -3237 -1716 -1962 -4877 -938 -1376 -4560 -1776 -6971 -3595 -6886 678 -2037 -3028 -2609 -3322 -1520 -85 1351 4447 1186 2510 1397 898 -484 -2219 -1100 1104 -56 1119 1325 -28 487 215 -1289 539 305 173 -249 -1771 -827 1032 -521 1068 1252 1484 -911 -686 -1215 -808 -686 -204 184 755 492 309 -1 -332 -276 -232 -602 775 -875 -1305 -343 -286 343 277 422 281 106 201 263 960 -1254 -329 900000 -363 -41 2085 38 900000 -24 900000 -3158 -1048 900000 1815 361 -25 -574 -65 554 -1356 898 625 500 147 -1674 221 -2313 524 416 -2160 -656 -780 -531 -1084 162 -2494 -924 -337 326 -344 925 338 1012 688 864 28 1316 787 -507 -1991 522 847 408 2527 1319 2694 848 1532 -973 1604 1487 2255 560 1312 3323 423 350 790 -632 -1340 -766 -996 -2781 -534 -777 -2522 -877 -3268 -1514 -2999 301 -1076 -1854 -1783 -2471 -1175 -69 1155 3870 1093 2268 1223 735 -372 -1650 -824 889 -52 1164 1538 -35 597 246 -1364 527 307 187 -285 -2168 -1066 1413 -794 1722 2072 2402 -1430 -1006 -1716 -1147 -1018 -320 298 1217 773 471 -2 -467 -372 -304 -826 1155 -1456 -2339 -637 -551 693 596 946 647 246 466 586 2015 -2567 -659 SS 20230117T140259.4Z 8417.585410 244 1 47.03 2 74.93 139.62 68.80 202.07 0.00 1 0.00 1 0 17 1.552e-01 9.609e-03 1.572e-01 6.757e-03 4.824119e-01 3.509772e-03 5.563246e-03 -6.000000e+00 8.854789e-02 223.56 -2.00 3.57 -2.00 320.40 0.00e+00 2.559269e-03 1.221789e-03 7.551912e-04 -6.000000e+00 3.892779e-03 272.93 -2.00 20.00 -2.00 319.88 0.00e+00 3.772 0.001 302.00 328.00 3 3.7514e+00 1.0312e-02 4.4851e-02 -6.0000e+00 2.1847e-01 1.1576e-01 1.2682e-02 2.5091e-02 -6.0000e+00 2.3855e-01 -5.7138e-02 1.1769e-02 1.3588e-02 -6.0000e+00 1.4186e-01 1.2250e-02 6.0168e-03 5.2505e-03 -6.0000e+00 5.9617e-02 1.6354e-04 -2.6615e-04 2.0905e-04 6.1575e-05 -6.0000e+00 4.4741e-03 7.0872e-04 1.8084e-05 12 8 8 10 0 0 99.28 22.31 0.46 0.00071 -0.00129 39 11 1 5 0 1205.700 26.41 20.01 22.31 11.88 20.4 979.62 -85200 -18424 -31130 900000 -8567 7739 -31344 -65958 -65699 -39324 -47479 -64935 -32818 -1386 -36883 -28065 -13733 16464 -29624 -9029 -10686 372 -10915 -7819 -8073 -17057 1664 -2919 -5426 -2221 3506 955 -9907 2309 1129 -347 -5985 11907 -1724 3593 2867 -3432 5787 6780 8929 4837 2492 3002 4460 1403 2543 5989 2508 2875 1486 7067 -641 -3457 3678 -2041 629 1311 703 1703 2174 -1562 -145 -5507 1848 270 1532 -215 144 -1766 -1222 -3402 -450 -3888 -1746 -1683 500 -199 -3664 -1796 585 -270 1461 193 730 402 1390 -629 -1351 -374 1035 611 1160 1274 855 -1423 -25 -1181 -501 642 -1461 -940 -856 -55 -533 762 655 892 -350 -217 570 -924 -1075 -456 137 729 371 848 867 831 36 153 -599 -279 -36 -568 -770 64 -716 -487 224 326 760 27 427 80 193 -910 -300 -1590 -202 -410 900000 -80 59 -379 -1267 -1407 -754 -1024 -1828 -806 -31 -1414 -1143 -535 513 -1561 -406 -499 16 -530 -393 -435 -1052 86 -152 -283 -117 197 64 -825 178 85 -26 -527 1034 -208 482 431 -586 939 1113 1449 829 440 534 879 271 581 1452 681 832 456 2118 -212 -1166 1129 -659 205 464 279 729 948 -679 -60 -2438 830 140 854 -127 84 -990 -626 -1602 -191 -1704 -820 -914 305 -137 -2815 -1433 487 -241 1346 184 690 365 1163 -498 -1021 -284 850 572 1228 1506 1079 -1811 -29 -1271 -504 654 -1629 -1101 -1055 -71 -752 1159 1074 1500 -584 -343 835 -1315 -1544 -680 216 1189 606 1340 1326 1222 50 207 -793 -384 -55 -946 -1378 119 -1392 -995 483 733 1742 62 988 180 409 -1864 -602 SS 20230117T141346.5Z 8417.592899 247 1 47.99 2 73.69 141.90 69.58 204.54 0.00 1 0.00 1 0 17 3.056e-01 9.864e-03 1.301e-01 5.139e-03 4.549789e-01 2.621991e-03 5.361901e-03 -6.000000e+00 1.743103e-01 223.57 -2.00 3.57 -2.00 320.03 0.00e+00 1.506556e-03 8.227767e-04 1.094107e-03 -6.000000e+00 7.663759e-03 272.93 -2.00 20.00 -2.00 319.51 0.00e+00 3.503 0.001 302.00 328.00 3 3.8574e+00 7.4890e-03 4.1966e-02 -6.0000e+00 4.3007e-01 1.1780e-01 9.0159e-03 2.3955e-02 -6.0000e+00 4.6961e-01 -6.1162e-02 7.9118e-03 1.2633e-02 -6.0000e+00 2.7926e-01 1.4708e-02 4.1138e-03 4.0949e-03 -6.0000e+00 1.1735e-01 1.9642e-04 -5.3519e-04 1.5661e-04 5.2490e-05 -6.0000e+00 8.8089e-03 5.0719e-04 -8.2462e-06 12 8 8 10 0 0 99.51 22.32 0.34 0.00051 -0.00351 22 6 1 5 0 2180.910 26.41 20.00 22.32 12.69 20.4 985.57 -42456 26378 -3554 900000 22802 333035 -55918 7849 -43531 28953 -30317 -6831 -31803 18080 -6774 24192 -26385 2717 -10776 2854 -6670 10641 787 14375 -18236 -8895 -3351 -8617 -17681 -15156 -1033 -2986 -6003 -14701 -19678 1538 -4184 -4239 3204 -2296 -1419 -2488 -639 -1929 3780 2874 4000 4143 7689 2518 1306 3384 3976 2610 4384 544 2749 -1662 3467 -195 5759 1354 3301 1136 1400 -165 1180 -1374 -1207 319 -151 107 -122 695 -1445 -1912 887 -5318 -1836 -1137 -2424 -1044 -2898 -1524 -334 146 640 773 1449 784 701 -390 -2891 943 581 -333 694 1959 -140 -39 -1244 -746 -2215 440 -1654 -209 -658 -336 -888 873 558 383 822 -227 -182 -636 206 416 46 43 601 975 612 737 630 -725 -812 -129 231 -289 -549 -555 -486 -91 192 160 906 -111 176 -229 430 -742 -101 -812 288 -55 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