File name: Pandora184s1_CapeElizabethME_20230324_L2Fit_fout2c4d20221222p1-8.txt File generation date: 20260323T204724.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v4d20221222.txt Level 1 file used: Pandora184s1_CapeElizabethME_20230324_L1_smca1c4d20221222p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20230324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0587 305.1998 305.3408 305.4818 305.6228 305.7638 305.9048 306.0458 306.1867 306.3277 306.4686 306.6095 306.7505 306.8914 307.0323 307.1732 307.3140 307.4549 307.5958 307.7366 307.8774 308.0183 308.1591 308.2999 308.4407 308.5814 308.7222 308.8630 309.0037 309.1445 309.2852 309.4259 309.5666 309.7073 309.8480 309.9887 310.1293 310.2700 310.4106 310.5513 310.6919 310.8325 310.9731 311.1137 311.2543 311.3948 311.5354 311.6759 311.8165 311.9570 312.0975 312.2380 312.3785 312.5190 312.6595 312.7999 312.9404 313.0808 313.2212 313.3616 313.5021 313.6424 313.7828 313.9232 314.0636 314.2039 314.3443 314.4846 314.6249 314.7652 314.9055 315.0458 315.1861 315.3263 315.4666 315.6068 315.7471 315.8873 316.0275 316.1677 316.3079 316.4481 316.5882 316.7284 316.8685 317.0087 317.1488 317.2889 317.4290 317.5691 317.7092 317.8492 317.9893 318.1293 318.2694 318.4094 318.5494 318.6894 318.8294 318.9694 319.1093 319.2493 319.3892 319.5292 319.6691 319.8090 319.9489 320.0888 320.2287 320.3686 320.5084 320.6483 320.7881 320.9279 321.0677 321.2075 321.3473 321.4871 321.6269 321.7666 321.9064 322.0461 322.1858 322.3255 322.4652 322.6049 322.7446 322.8843 323.0239 323.1636 323.3032 323.4428 323.5824 323.7220 323.8616 324.0012 324.1408 324.2803 324.4199 324.5594 324.6989 324.8384 324.9779 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230324T123757.5Z 8483.526360 99 1 47.54 2 69.27 108.84 85.07 74.33 0.00 1 0.00 1 0 25 1.194e-01 1.386e-02 1.553e-01 9.578e-03 3.985428e-01 4.917373e-03 4.609540e-03 -6.000000e+00 6.886335e-02 226.55 -2.00 3.57 -2.00 319.79 0.00e+00 3.492682e-04 1.444874e-03 4.882386e-04 -6.000000e+00 2.984652e-03 276.00 -2.00 20.00 -2.00 319.20 0.00e+00 2.798 0.000 302.00 328.00 3 5.3116e+00 1.3970e-02 3.4779e-02 -6.0000e+00 1.7089e-01 4.4873e-02 1.6584e-02 2.0829e-02 -6.0000e+00 1.8612e-01 -2.6323e-02 1.3368e-02 1.0533e-02 -6.0000e+00 1.1058e-01 8.4463e-03 6.8970e-03 3.1254e-03 -6.0000e+00 4.6174e-02 9.7487e-05 9.1045e-05 2.9805e-04 3.6756e-05 -6.0000e+00 3.3996e-03 2.2533e-03 3.4098e-06 12 8 8 10 0 0 99.93 22.40 0.78 0.00225 0.00294 17 5 1 5 0 2793.850 26.51 20.00 22.40 13.37 21.0 1033.93 -54852 54655 7391 -15527 51546 -5340 1406 -11657 -32993 -26741 5201 -43958 -25308 -26190 -30682 -3623 16316 -7061 31336 15573 4698 -9693 13490 -24365 -4476 -9067 -3804 10290 -10097 -6477 -3479 -7506 10220 -19478 7120 8142 11863 3460 4329 6073 -1425 2096 3750 -2003 6524 7987 9319 3695 582 2308 1722 -1832 6328 -527 -2837 5021 -311 1107 5668 663 -712 1281 1936 77 -650 -1786 -1174 791 -477 1996 2407 -1467 -36 -1275 -1144 -4231 -3754 -3487 -2442 -3497 -1834 -4246 -3498 -9 -2610 2550 1089 2671 2126 2266 1284 -1026 -2156 -145 877 917 193 1940 1098 270 -1414 -1389 -1606 -200 -1625 -1391 -452 -402 831 561 668 496 1894 -654 -246 -2647 -382 -698 -357 670 1473 362 1537 554 -32 -1420 -1950 -582 812 378 -546 -442 278 -1066 160 367 590 63 378 597 -78 -350 -921 -1708 638 144 -363 562 -100 26 -281 -1104 -895 130 -2090 -1161 -1446 -2084 -212 845 -492 1570 952 327 -782 894 -2524 -407 -901 -359 804 -926 -583 -334 -841 1059 -2812 756 850 1310 491 735 1186 -332 498 907 -520 1562 1892 2168 907 148 598 483 -579 1977 -188 -1077 1816 -121 422 2224 272 -307 587 969 42 -362 -953 -593 394 -262 1206 1578 -1038 -25 -850 -702 -2411 -1960 -1788 -1339 -2215 -1298 -3422 -3006 -8 -2513 2487 1132 2802 2228 2271 1206 -908 -1813 -120 778 913 217 2388 1438 350 -1740 -1563 -1722 -219 -1934 -1744 -590 -553 1210 886 1121 849 3101 -1031 -360 -3782 -538 -1032 -560 1089 2385 578 2355 821 -45 -1955 -2611 -794 1187 602 -932 -782 504 -2058 324 773 1271 138 825 1254 -158 -679 -1776 SS 20230324T124721.7Z 8483.532890 102 1 3.21 2 67.67 110.68 83.45 75.82 0.00 1 0.00 1 0 17 4.461e-02 1.027e-02 5.421e-02 6.883e-03 3.816651e-01 3.486566e-03 4.541716e-03 -6.000000e+00 2.572730e-02 226.55 -2.00 3.57 -2.00 318.60 0.00e+00 2.133483e-03 7.222649e-04 4.338000e-04 -6.000000e+00 1.115030e-03 276.00 -2.00 20.00 -2.00 317.98 0.00e+00 2.610 0.000 302.00 328.00 3 3.4482e+00 9.4448e-03 3.2704e-02 -6.0000e+00 6.3845e-02 5.1538e-02 1.0781e-02 1.9742e-02 -6.0000e+00 6.9534e-02 -9.6353e-03 7.4717e-03 9.9794e-03 -6.0000e+00 4.1314e-02 -9.0694e-03 3.9066e-03 3.3491e-03 -6.0000e+00 1.7251e-02 7.6016e-04 -3.2495e-04 2.0392e-04 3.5292e-05 -6.0000e+00 1.2700e-03 2.1354e-03 1.0686e-05 12 9 9 12 1 1 999.00 22.40 0.26 0.00214 -0.00031 2 13 1 5 0 1013.670 26.51 20.00 22.40 13.65 21.0 1036.94 -16031 6121 -1385 15449 -21047 4518 6219 13940 -9560 -8929 6450 -23576 3338 2432 2345 -5944 -4221 -4781 -858 -7925 7742 -6657 2500 -1859 -2623 505 221 -5276 -10872 -236 -3967 -1172 1660 -1610 -5486 -4857 106 -81 1193 -1798 -1957 -2105 2011 -1071 4882 2882 1619 1576 3680 -706 3915 1456 2238 904 797 -2485 2590 -593 549 75 511 -808 2208 1068 -1034 -837 -697 -390 558 1559 2443 1925 203 -56 -123 380 -3269 -2550 -1779 -307 -2367 -633 -1914 -655 -2726 1942 92 1051 566 671 714 339 241 -156 533 682 -322 909 -129 44 -1951 -797 -1595 -762 -1435 -210 -1459 -174 -992 1077 412 772 339 103 -152 -703 69 -172 883 -113 1412 66 1031 989 656 453 -704 -483 1039 620 -378 -469 -376 -636 -11 -292 657 839 341 35 -664 -528 -704 -667 230 -59 529 -947 152 217 505 -488 -480 303 -1598 202 178 203 -634 -479 -581 -106 -1096 935 -930 327 -270 -407 79 35 -839 -1759 -35 -671 -216 329 -342 -1160 -1011 23 -21 360 -594 -714 -814 775 -433 1871 1135 643 624 1433 -296 1679 695 1135 493 452 -1495 1506 -354 318 43 305 -487 1420 747 -744 -569 -449 -250 384 1199 2030 1670 177 -47 -95 263 -2352 -1786 -1220 -237 -2114 -569 -1871 -667 -3031 2197 104 1201 647 791 779 341 227 -148 541 775 -386 1194 -169 61 -2555 -944 -1948 -884 -1799 -275 -2030 -236 -1444 1657 636 1207 551 157 -215 -958 94 -246 1331 -180 2235 104 1552 1428 907 641 -974 -686 1472 956 -625 -753 -623 -1109 -20 -529 1210 1567 638 64 -1233 -940 -1240 SS 20230324T125225.8Z 8483.536410 106 1 46.83 2 66.81 111.69 82.57 76.62 0.00 1 0.00 1 0 17 9.767e-02 1.022e-02 3.816e-02 4.625e-03 3.616393e-01 2.342801e-03 4.344204e-03 -6.000000e+00 5.632179e-02 226.55 -2.00 3.57 -2.00 319.33 0.00e+00 2.479001e-03 5.854268e-04 8.414571e-04 -6.000000e+00 2.441070e-03 276.00 -2.00 20.00 -2.00 318.72 0.00e+00 2.520 0.000 302.00 328.00 3 4.6356e+00 6.5144e-03 3.1451e-02 -6.0000e+00 1.3977e-01 5.9636e-02 7.5472e-03 1.8864e-02 -6.0000e+00 1.5223e-01 -3.3542e-02 5.5337e-03 9.8797e-03 -6.0000e+00 9.0445e-02 6.1205e-03 2.8776e-03 3.5506e-03 -6.0000e+00 3.7764e-02 2.6069e-04 -2.9872e-04 1.4251e-04 4.1140e-05 -6.0000e+00 2.7804e-03 2.7876e-03 2.5067e-05 12 8 8 10 0 0 99.98 22.40 0.52 0.00279 0.00054 32 9 1 5 0 1463.270 26.51 19.97 22.40 13.92 21.2 1039.66 -51682 -35187 -17348 -16962 -14227 -51112 692 -33517 -9198 -17406 -35456 -34533 -25251 -20049 -310 -10958 -265 -6253 5328 3255 2065 493 8884 -1766 -7347 2694 5933 -1550 -2743 4284 4180 1961 867 -1867 1370 2877 3461 3128 3839 2036 133 2878 -514 4184 1544 2212 -281 2061 -1110 2452 -1618 3349 146 1595 204 877 -1808 361 -915 -241 -2256 1773 1983 3234 587 1045 -1928 171 -1290 1622 1529 1110 1104 1377 174 -1791 -2200 -2872 -1915 -1484 -1076 -1610 -1325 -487 -73 187 -94 1607 1725 34 593 -786 -1654 -648 -256 -394 339 430 270 -1245 384 -2416 -871 -1863 -1340 -1764 -479 -874 197 286 835 369 439 -755 -71 -934 86 -681 704 655 1242 1150 1063 421 1199 648 -93 269 421 11 79 -323 -477 312 -46 403 -194 517 445 -149 -614 -864 -670 -2543 -1645 -704 -654 -484 -2410 20 -1553 -370 -799 -1977 -2025 -1563 -1406 -21 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