File name: Pandora184s1_CapeElizabethME_20230419_L2Fit_fout2c4d20221222p1-8.txt File generation date: 20260323T205231.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v4d20221222.txt Level 1 file used: Pandora184s1_CapeElizabethME_20230419_L1_smca1c4d20221222p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20230419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0587 305.1998 305.3408 305.4818 305.6228 305.7638 305.9048 306.0458 306.1867 306.3277 306.4686 306.6095 306.7505 306.8914 307.0323 307.1732 307.3140 307.4549 307.5958 307.7366 307.8774 308.0183 308.1591 308.2999 308.4407 308.5814 308.7222 308.8630 309.0037 309.1445 309.2852 309.4259 309.5666 309.7073 309.8480 309.9887 310.1293 310.2700 310.4106 310.5513 310.6919 310.8325 310.9731 311.1137 311.2543 311.3948 311.5354 311.6759 311.8165 311.9570 312.0975 312.2380 312.3785 312.5190 312.6595 312.7999 312.9404 313.0808 313.2212 313.3616 313.5021 313.6424 313.7828 313.9232 314.0636 314.2039 314.3443 314.4846 314.6249 314.7652 314.9055 315.0458 315.1861 315.3263 315.4666 315.6068 315.7471 315.8873 316.0275 316.1677 316.3079 316.4481 316.5882 316.7284 316.8685 317.0087 317.1488 317.2889 317.4290 317.5691 317.7092 317.8492 317.9893 318.1293 318.2694 318.4094 318.5494 318.6894 318.8294 318.9694 319.1093 319.2493 319.3892 319.5292 319.6691 319.8090 319.9489 320.0888 320.2287 320.3686 320.5084 320.6483 320.7881 320.9279 321.0677 321.2075 321.3473 321.4871 321.6269 321.7666 321.9064 322.0461 322.1858 322.3255 322.4652 322.6049 322.7446 322.8843 323.0239 323.1636 323.3032 323.4428 323.5824 323.7220 323.8616 324.0012 324.1408 324.2803 324.4199 324.5594 324.6989 324.8384 324.9779 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230419T131624.7Z 8509.553063 157 1 46.97 2 54.40 110.56 53.54 120.42 0.00 1 0.00 1 0 25 2.831e-02 8.820e-03 2.102e-02 5.053e-03 2.640416e-01 2.568717e-03 3.186902e-03 -6.000000e+00 1.646178e-02 228.63 -2.00 3.57 -2.00 318.17 0.00e+00 1.382268e-03 4.560679e-04 3.967645e-04 -6.000000e+00 7.162185e-04 278.91 -2.00 20.00 -2.00 317.49 0.00e+00 1.713 0.000 302.00 328.00 3 5.3527e+00 6.8770e-03 2.2072e-02 -6.0000e+00 4.1012e-02 7.2374e-02 7.8012e-03 1.3744e-02 -6.0000e+00 4.4572e-02 -1.1269e-02 4.8727e-03 6.8471e-03 -6.0000e+00 2.6484e-02 -3.8005e-03 2.4385e-03 2.1389e-03 -6.0000e+00 1.1043e-02 3.1680e-04 3.6904e-04 1.5434e-04 2.3001e-05 -6.0000e+00 8.0638e-04 2.7812e-03 1.1718e-04 11 8 0 10 0 0 99.94 22.45 0.33 0.00278 0.00555 67 19 1 5 0 700.910 26.51 20.00 22.45 17.20 21.6 1030.75 -7557 2599 -4611 -5439 -15136 -9714 -5745 -5985 -4264 -6496 -12559 -9430 -1739 -3822 928 600 1503 3811 4137 -315 1467 -3446 2273 148 4323 1501 2030 -2121 2885 -5006 2586 3256 1011 -961 -4473 -2186 -808 -774 1195 -1741 422 -1862 556 256 1142 1573 885 405 -528 -1537 1999 572 817 943 729 -999 200 -228 -531 735 -740 1189 784 1133 -793 458 -920 -498 382 2677 885 1690 395 1394 -51 -295 -1265 -1443 -2407 14 -1252 -692 -1668 -515 -729 981 -56 1586 887 987 450 -788 -2309 -617 -1398 -107 -451 892 -252 -817 -862 -1640 -1159 -1009 -731 -1327 -749 -1308 -9 959 1067 993 166 -439 440 -822 175 -411 362 255 900 660 814 534 508 438 710 407 847 0 -249 -675 413 -624 412 -156 252 254 203 -88 93 -1148 -772 -614 209 -407 -456 -1255 -726 -432 -501 -387 -687 -1406 -1056 -202 -522 138 98 256 661 743 -61 284 -696 441 31 902 332 443 -456 556 -1031 522 709 242 -239 -1094 -514 -204 -227 409 -709 183 -866 260 121 535 731 406 182 -236 -700 924 287 432 522 416 -591 118 -134 -308 421 -445 752 540 820 -579 337 -639 -338 275 2114 773 1520 358 1198 -41 -215 -844 -928 -1647 11 -1065 -643 -1663 -533 -809 1143 -70 1983 1111 1182 501 -809 -2217 -572 -1384 -116 -542 1163 -348 -1110 -1094 -1934 -1305 -1178 -917 -1766 -1037 -1904 -13 1530 1777 1661 269 -662 605 -1087 230 -569 532 395 1411 1020 1220 767 692 568 881 515 1139 0 -378 -1055 653 -1040 718 -286 473 484 387 -164 166 -2002 -1327 SS 20230419T132505.4Z 8509.559090 160 1 1.71 2 52.94 112.48 52.20 122.46 0.00 1 0.00 1 0 17 1.035e-02 6.883e-03 2.458e-03 1.139e-03 2.508982e-01 5.844799e-04 3.033392e-03 -6.000000e+00 6.014884e-03 228.63 -2.00 3.57 -2.00 316.35 0.00e+00 7.330837e-04 6.647335e-05 1.106763e-04 -6.000000e+00 2.617845e-04 278.91 -2.00 20.00 -2.00 315.72 0.00e+00 1.655 0.000 302.00 328.00 3 9.0089e-01 1.5233e-03 2.1129e-02 -6.0000e+00 1.4985e-02 2.4762e-02 1.7061e-03 1.2989e-02 -6.0000e+00 1.6288e-02 -3.7532e-03 9.8439e-04 6.3554e-03 -6.0000e+00 9.6781e-03 -4.8051e-03 4.5320e-04 1.7979e-03 -6.0000e+00 4.0339e-03 3.0086e-02 -2.9792e-04 3.3535e-05 2.1567e-05 -6.0000e+00 2.9483e-04 3.0294e-03 1.4696e-05 12 9 1 12 1 1 34.34 22.45 0.37 0.00303 0.00079 32 280 1 5 0 46.480 26.51 20.01 22.45 17.63 21.7 1034.55 182 55 -336 -3022 -3713 -2329 -2216 -608 -182 -1931 -2778 -2206 -1597 -4 879 588 371 286 977 1303 1304 924 943 937 787 552 106 -1399 -791 -221 464 733 1003 -1463 -3131 -2945 -2632 -1172 -116 -349 -462 -386 -248 134 407 262 -39 -210 -321 1 974 443 1085 873 700 648 662 161 -45 360 735 1202 1777 1427 556 -595 -716 -725 514 1010 550 831 474 644 101 -585 -1266 -1832 -1322 -969 -1573 -1241 -1893 -1497 -590 -150 284 728 712 616 428 100 -423 -183 -220 -33 365 860 84 -343 -865 -1254 -1114 -442 -868 -1100 -631 -365 62 644 677 525 534 82 -142 -156 -11 130 661 334 260 366 587 500 828 95 102 381 318 -32 70 -343 -265 -279 199 125 392 304 145 -203 -244 -770 -784 32 10 -60 -568 -632 -372 -371 -112 -37 -416 -602 -489 -355 -1 248 182 121 97 341 468 476 337 350 335 296 215 41 -520 -300 -82 179 280 411 -626 -1292 -1194 -1155 -591 -64 -222 -298 -261 -172 94 282 181 -27 -139 -209 1 663 324 833 657 544 514 532 129 -36 283 595 1040 1550 1317 512 -513 -613 -609 457 938 525 823 469 649 95 -532 -1051 -1468 -1108 -906 -1554 -1262 -2063 -1614 -674 -183 344 899 876 728 494 112 -438 -184 -235 -37 449 1095 108 -453 -1075 -1525 -1300 -532 -1072 -1439 -817 -493 87 916 1006 784 764 115 -193 -202 -15 175 904 485 367 533 830 676 1116 122 126 477 424 -43 100 -500 -376 -414 311 196 626 496 236 -323 -375 -1203 -1212 SS 20230419T133049.8Z 8509.563076 164 1 46.91 2 51.98 113.78 51.33 123.84 0.00 1 0.00 1 0 17 1.165e-02 6.555e-03 4.721e-04 1.597e-04 2.453218e-01 8.135549e-05 2.938299e-03 -6.000000e+00 6.772102e-03 228.63 -2.00 3.57 -2.00 317.26 0.00e+00 8.907762e-04 1.143690e-05 1.722200e-04 -6.000000e+00 2.947496e-04 278.91 -2.00 20.00 -2.00 316.59 0.00e+00 1.620 0.000 302.00 328.00 3 -1.6877e-02 2.1459e-04 2.0662e-02 -6.0000e+00 1.6872e-02 1.8790e-02 2.4150e-04 1.2683e-02 -6.0000e+00 1.8339e-02 -3.2071e-03 1.4341e-04 6.2301e-03 -6.0000e+00 1.0897e-02 -5.5880e-03 6.9049e-05 1.8081e-03 -6.0000e+00 4.5416e-03 7.8939e-02 -2.8492e-04 4.8141e-06 2.0494e-05 -6.0000e+00 3.3198e-04 3.1330e-03 5.5476e-06 11 8 0 10 0 0 29.54 22.45 0.32 0.00313 0.00099 3061 853 1 5 0 15.060 26.51 20.01 22.45 18.25 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