File name: Pandora184s1_CapeElizabethME_20250613_L2Fit_fout2c4d20221222p1-8.txt File generation date: 20250618T015549.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v4d20221222.txt Level 1 file used: Pandora184s1_CapeElizabethME_20250613_L1_smca1c4d20221222p1-8.txt Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20250613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0587 305.1998 305.3408 305.4818 305.6228 305.7638 305.9048 306.0458 306.1867 306.3277 306.4686 306.6095 306.7505 306.8914 307.0323 307.1732 307.3140 307.4549 307.5958 307.7366 307.8774 308.0183 308.1591 308.2999 308.4407 308.5814 308.7222 308.8630 309.0037 309.1445 309.2852 309.4259 309.5666 309.7073 309.8480 309.9887 310.1293 310.2700 310.4106 310.5513 310.6919 310.8325 310.9731 311.1137 311.2543 311.3948 311.5354 311.6759 311.8165 311.9570 312.0975 312.2380 312.3785 312.5190 312.6595 312.7999 312.9404 313.0808 313.2212 313.3616 313.5021 313.6424 313.7828 313.9232 314.0636 314.2039 314.3443 314.4846 314.6249 314.7652 314.9055 315.0458 315.1861 315.3263 315.4666 315.6068 315.7471 315.8873 316.0275 316.1677 316.3079 316.4481 316.5882 316.7284 316.8685 317.0087 317.1488 317.2889 317.4290 317.5691 317.7092 317.8492 317.9893 318.1293 318.2694 318.4094 318.5494 318.6894 318.8294 318.9694 319.1093 319.2493 319.3892 319.5292 319.6691 319.8090 319.9489 320.0888 320.2287 320.3686 320.5084 320.6483 320.7881 320.9279 321.0677 321.2075 321.3473 321.4871 321.6269 321.7666 321.9064 322.0461 322.1858 322.3255 322.4652 322.6049 322.7446 322.8843 323.0239 323.1636 323.3032 323.4428 323.5824 323.7220 323.8616 324.0012 324.1408 324.2803 324.4199 324.5594 324.6989 324.8384 324.9779 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250613T105120.7Z 9295.452323 217 1 6.57 2 72.43 74.34 93.32 234.26 0.00 1 0.00 1 0 17 3.258e-01 2.236e-02 2.801e-01 1.635e-02 4.597497e-01 8.550941e-03 5.519569e-03 -6.000000e+00 1.937012e-01 232.85 -2.00 3.57 -2.00 319.79 0.00e+00 2.978072e-03 2.575604e-03 1.916396e-03 -6.000000e+00 8.656623e-03 284.80 -2.00 20.00 -2.00 319.06 0.00e+00 3.265 0.001 302.00 328.00 3 4.3784e+00 2.4808e-02 4.1535e-02 -6.0000e+00 4.8616e-01 1.2202e-01 2.9479e-02 2.6040e-02 -6.0000e+00 5.2586e-01 -7.7047e-02 2.3124e-02 1.3187e-02 -6.0000e+00 3.1198e-01 1.7450e-02 1.1912e-02 3.9384e-03 -6.0000e+00 1.3046e-01 1.3963e-04 -1.1143e-03 4.9250e-04 5.4446e-05 -6.0000e+00 9.2903e-03 -1.7922e-02 -8.3911e-05 12 9 9 12 1 1 999.00 22.60 0.30 -0.01792 -0.02630 1 4 1 5 0 3281.690 26.83 20.01 22.60 22.83 31.3 1029.85 -8569 900000 -123856 9890 162128 900000 -39667 11858 183861 80719 -59072 131126 15341 -65019 -61866 26607 -26206 108903 -18905 -16249 -27384 10556 7597 8413 81582 5500 -24324 -27584 32281 -16908 31634 -14775 38009 -6979 21301 3181 -7058 1253 1015 -1665 15990 -7266 9008 -9709 2878 -375 5811 11713 16584 -6052 12361 -7183 10704 5299 2537 -501 4836 -139 10672 -4288 7992 -3221 43 2814 1567 -1484 -1245 -4893 3143 10258 4685 1704 -2424 595 -1684 -2362 -2005 -4505 6020 94 -2410 -1031 -1244 -1520 -1450 110 -1988 1992 2802 3042 -4440 -624 -1178 1013 -647 -525 965 972 -1754 -1534 297 514 -3087 -194 -3003 -1673 -1618 -1867 -134 -185 1509 2026 -673 -173 -497 -847 -3440 -325 1578 1481 2914 1805 1796 889 2072 1646 125 -837 1265 324 -191 -275 -1569 -757 1074 -444 646 -305 2652 -258 -411 -1427 -2165 -137 900000 -6999 158 2584 900000 -862 189 2931 1287 -2140 2090 333 -3863 -4303 975 -1796 2083 -1386 -1217 -2357 623 472 550 2731 412 -2481 -2814 1749 -1536 1966 -1672 2847 -868 1935 340 -900 172 168 -334 3007 -1842 2025 -2693 711 -97 1417 2707 3701 -1756 3211 -2484 3344 1867 963 -202 1888 -57 3844 -1777 3019 -1473 21 1467 852 -799 -639 -2605 1663 5722 3039 1192 -1762 401 -1074 -1366 -1061 -2391 3090 58 -1771 -838 -998 -1295 -1317 105 -2042 2026 2826 2953 -4330 -541 -1059 888 -566 -517 1063 1200 -2386 -2075 370 584 -3403 -210 -3589 -2093 -2127 -2602 -197 -272 2344 3235 -1086 -263 -773 -1258 -5238 -501 2324 2292 4483 2745 2644 1385 3044 2324 173 -1194 1927 500 -319 -479 -2877 -1446 2140 -943 1285 -624 5699 -553 -840 -2813 -4204 SS 20250613T105731.2Z 9295.456611 221 1 46.06 2 71.35 75.31 94.19 235.26 0.00 1 0.00 1 0 17 1.942e-01 1.073e-02 1.871e-01 7.432e-03 4.274387e-01 3.930352e-03 4.948989e-03 -6.000000e+00 1.150276e-01 232.85 -2.00 3.57 -2.00 320.07 0.00e+00 3.232737e-03 1.276854e-03 5.972168e-04 -6.000000e+00 5.035173e-03 284.80 -2.00 20.00 -2.00 319.36 0.00e+00 3.088 0.001 302.00 328.00 3 4.6149e+00 1.1682e-02 3.8594e-02 -6.0000e+00 2.8901e-01 5.0420e-02 1.4032e-02 2.3070e-02 -6.0000e+00 3.1245e-01 -1.9765e-03 1.1542e-02 1.1971e-02 -6.0000e+00 1.8569e-01 -1.0906e-02 5.9083e-03 4.8012e-03 -6.0000e+00 7.7452e-02 1.3859e-04 -2.9776e-04 2.3134e-04 5.2145e-05 -6.0000e+00 5.5333e-03 -1.9205e-02 6.7872e-05 12 8 8 10 0 0 99.29 22.61 0.92 -0.01921 -0.02144 16 4 1 5 0 2878.430 26.83 19.99 22.61 23.16 31.4 1032.40 -418 -60354 -74904 -24984 5470 -9084 -22043 -2543 114411 134738 -39050 5734 29195 -43956 2640 25850 9025 14869 -22690 12966 17562 20965 744 -14835 7039 -30710 -13464 5661 11347 1400 5457 7472 -13797 -17114 -10331 -8944 -5240 -4885 9138 1437 8227 -2232 -6884 1525 3741 -1749 4275 614 -2459 537 -156 1759 5206 -690 2848 970 3148 -1179 1355 4586 3741 1453 1201 446 972 755 1671 -119 -1816 3443 196 863 739 570 580 -3898 -1334 -6024 -1508 -1101 -814 -1864 611 -3255 -1093 965 786 140 2052 -420 722 -571 -142 -97 384 118 -325 2402 447 -947 161 -707 -1399 -273 -1256 -1573 667 -1295 147 -10 170 674 -98 -812 -410 -451 -684 -679 -386 308 821 1435 535 1469 662 10 -438 952 -649 -282 -402 332 -328 -355 -279 1241 492 487 -134 10 -477 -449 -837 -5 -1385 -2126 -423 63 -126 -363 -39 829 977 -1055 106 500 -1912 87 784 357 598 -1420 598 798 926 41 -1017 413 -2752 -1029 347 636 89 367 561 -1436 -1951 -1069 -896 -546 -592 1162 233 1393 -449 -1515 317 769 -385 979 146 -611 134 -42 509 1570 -236 982 352 1141 -446 491 1599 1359 585 536 218 487 364 758 -55 -914 1859 120 552 473 350 330 -2094 -640 -2952 -755 -628 -530 -1373 475 -2784 -976 903 777 143 2068 -419 663 -490 -113 -77 326 113 -352 2839 577 -1235 195 -790 -1478 -289 -1442 -1922 837 -1752 209 -15 282 1145 -164 -1301 -609 -636 -966 -1002 -603 503 1349 2297 837 2188 948 13 -584 1278 -962 -454 -695 594 -612 -695 -579 2661 1092 1100 -305 23 -1010 -909 -1665 SS 20250613T110248.1Z 9295.460279 224 1 14.41 2 70.42 76.14 94.94 236.11 0.00 1 0.00 1 0 17 8.385e-02 8.413e-03 5.515e-02 4.318e-03 4.114688e-01 2.268953e-03 4.904092e-03 -6.000000e+00 4.965429e-02 232.85 -2.00 3.57 -2.00 319.43 0.00e+00 1.474255e-03 6.055579e-04 8.901437e-04 -6.000000e+00 2.173472e-03 284.80 -2.00 20.00 -2.00 318.68 0.00e+00 2.950 0.000 302.00 328.00 3 3.5998e+00 6.4548e-03 3.7146e-02 -6.0000e+00 1.2476e-01 2.9154e-02 7.5376e-03 2.2533e-02 -6.0000e+00 1.3488e-01 -2.1095e-02 5.6381e-03 1.1146e-02 -6.0000e+00 8.0154e-02 2.2249e-03 2.9248e-03 3.2087e-03 -6.0000e+00 3.3436e-02 4.5596e-04 -3.7727e-04 1.3083e-04 3.8696e-05 -6.0000e+00 2.3884e-03 -1.9371e-02 7.8310e-05 12 9 1 12 1 1 98.68 22.61 0.28 -0.01937 -0.02221 10 10 1 5 0 1309.310 26.83 20.00 22.61 23.40 31.3 1034.15 4421 3510 -6745 -7453 -38788 -30444 -31603 -15424 -34572 -14264 -41753 -17574 -28619 -71 -8567 -1107 -17206 7947 -9915 19022 2115 -19 -12327 -1068 -4532 -3381 -2576 -4050 -10367 -4343 -3627 -410 -4908 1211 -3072 635 -7438 -2062 2023 2435 -376 3163 -42 2386 493 1644 -1519 1147 3241 -691 1001 488 -158 1567 1883 435 1213 -420 1964 -553 990 1853 3193 1408 1614 255 -867 -1011 1249 -254 2918 902 1200 164 -137 -971 -950 -4016 -323 -1297 -1202 -1655 -2416 -2639 -227 -600 396 1202 1214 482 485 -39 -652 -523 -256 -142 347 967 411 -112 -587 -1125 -1308 -175 -1961 -828 -864 -854 -62 686 724 678 478 -341 -36 -487 -529 -51 435 536 266 597 1071 552 360 300 -585 301 487 28 -264 -221 -216 -74 -88 320 -1 368 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