File name: Pandora225s1_Cebu_20250422_L2Fit_fwvt1c2d20220603p1-8.txt File generation date: 20250422T161524.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 225 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora225_OF_v2d20220531.txt Instrument calibration file used: Pandora225s1_CF_v2d20220603.txt Level 1 file used: Pandora225s1_Cebu_20250422_L1_smca1c2d20220603p1-8.txt Full location name: University of San Carlos - Talamban Campus Short location name: Cebu Country of location: Philippines Location latitude [deg]: 10.3551 Location longitude [deg]: 123.9111 Location altitude [m]: 67 Local noon date: 20250422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial instrument deployment First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0330 492.1544 492.2759 492.3973 492.5187 492.6401 492.7615 492.8828 493.0042 493.1255 493.2468 493.3681 493.4894 493.6106 493.7319 493.8531 493.9743 494.0955 494.2167 494.3378 494.4590 494.5801 494.7012 494.8223 494.9434 495.0644 495.1855 495.3065 495.4275 495.5485 495.6695 495.7904 495.9114 496.0323 496.1532 496.2741 496.3950 496.5158 496.6366 496.7575 496.8783 496.9991 497.1198 497.2406 497.3613 497.4820 497.6027 497.7234 497.8441 497.9647 498.0854 498.2060 498.3266 498.4472 498.5677 498.6883 498.8088 498.9293 499.0498 499.1703 499.2908 499.4112 499.5317 499.6521 499.7725 499.8928 500.0132 500.1335 500.2539 500.3742 500.4945 500.6148 500.7350 500.8553 500.9755 501.0957 501.2159 501.3361 501.4562 501.5763 501.6965 501.8166 501.9367 502.0567 502.1768 502.2968 502.4168 502.5368 502.6568 502.7768 502.8968 503.0167 503.1366 503.2565 503.3764 503.4963 503.6161 503.7359 503.8558 503.9756 504.0953 504.2151 504.3348 504.4546 504.5743 504.6940 504.8137 504.9333 505.0530 505.1726 505.2922 505.4118 505.5314 505.6509 505.7705 505.8900 506.0095 506.1290 506.2484 506.3679 506.4873 506.6068 506.7262 506.8455 506.9649 507.0843 507.2036 507.3229 507.4422 507.5615 507.6808 507.8000 507.9192 508.0385 508.1576 508.2768 508.3960 508.5151 508.6343 508.7534 508.8725 508.9915 509.1106 509.2296 509.3487 509.4677 509.5867 509.7056 509.8246 509.9435 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20250421T214113.5Z 9242.903628 41 1 13.14 2 88.25 77.94 35.48 152.65 0.00 1 0.00 1 0 22 5.870e-03 5.765e-03 6.959e-04 6.938e-04 3.091175e+04 5.481419e+01 1.926496e+03 -6.000000e+00 3.264348e+02 294.67 -2.00 20.00 -2.00 505.41 0.00e+00 1.722490e-03 1.948766e-05 1.320824e-04 -6.000000e+00 1.670082e-04 294.67 -2.00 20.00 -2.00 500.66 0.00e+00 1.533698e+00 1.329403e-02 1.472600e-01 -6.000000e+00 1.129328e-01 228.81 -2.00 3.06 -2.00 502.23 0.00e+00 16.573 0.005 489.00 513.00 1 3.0905e+00 1.0203e-03 2.6860e-02 -6.0000e+00 8.6832e-03 -1.5531e-03 2.5618e-04 4.0617e-03 -6.0000e+00 2.2639e-03 7.1512e-03 2.4400e-03 4.7666e-05 1.5444e-04 -6.0000e+00 5.0235e-04 1.8912e-02 1.2855e-04 12 9 9 12 1 1 62.07 26.66 1.50 0.01891 0.03584 20 9 1 4 0 625.350 29.16 20.00 26.66 33.31 1.9 1003.91 -1358 -940 -99 163 700 820 999 882 614 258 124 -221 -815 -809 -731 -416 -88 276 267 207 161 149 335 546 456 632 624 -90 -709 -1078 -982 -673 -29 295 365 501 190 -172 -342 -203 -64 274 349 659 762 617 723 352 6 -712 -1107 -1391 -1189 -695 -249 224 398 392 409 360 363 526 497 368 320 170 -28 -371 -698 -716 -637 -482 -106 82 -136 -263 -396 -589 -717 -666 -333 -220 -289 -178 -19 -118 -362 -404 -2 173 596 1076 859 802 759 544 403 -477 -1272 -1380 -1262 -995 -722 -97 231 283 -47 -339 -437 -404 -237 -119 197 218 832 1058 1033 629 422 -148 -344 -203 259 439 607 823 574 442 206 -265 -234 -255 -576 -568 -468 -401 191 293 301 245 319 286 440 829 660 128 -455 -861 -934 -794 -1280 -878 -95 159 698 813 1010 901 626 260 124 -219 -797 -802 -725 -404 -87 280 272 213 165 153 346 566 465 645 651 -93 -714 -1079 -977 -675 -29 300 382 522 197 -177 -347 -205 -65 281 363 692 788 639 760 367 6 -713 -1105 -1364 -1159 -688 -249 230 416 401 428 376 372 543 515 381 327 175 -28 -373 -696 -722 -641 -477 -106 83 -139 -263 -397 -580 -697 -642 -321 -214 -284 -174 -19 -118 -358 -393 -2 170 575 1048 833 766 703 489 356 -416 -1105 -1194 -1112 -897 -682 -93 230 280 -48 -337 -436 -401 -238 -119 195 215 816 1055 1042 651 434 -149 -345 -198 256 427 595 812 572 439 206 -265 -228 -251 -558 -553 -464 -400 193 300 308 256 338 305 460 878 695 134 -472 -885 -960 -824 SO 20250421T214338.6Z 9242.905308 47 1 25.76 2 87.66 78.04 35.21 153.48 0.00 1 0.00 1 0 29 5.333e-03 5.235e-03 1.369e-04 1.365e-04 2.943749e+04 1.074871e+01 1.839320e+03 -6.000000e+00 2.966229e+02 294.67 -2.00 20.00 -2.00 505.41 0.00e+00 1.597094e-03 3.841691e-06 1.245187e-04 -6.000000e+00 1.517396e-04 294.67 -2.00 20.00 -2.00 500.68 0.00e+00 1.382987e+00 2.615807e-03 1.415261e-01 -6.000000e+00 1.025843e-01 228.81 -2.00 3.06 -2.00 502.24 0.00e+00 15.066 0.004 489.00 513.00 1 7.6744e-01 2.0088e-04 2.4740e-02 -6.0000e+00 7.8880e-03 -6.3532e-03 5.0400e-05 3.8746e-03 -6.0000e+00 2.0557e-03 9.1635e-02 2.1354e-03 9.4882e-06 1.4378e-04 -6.0000e+00 4.5636e-04 -6.5872e-04 2.6759e-04 12 9 9 12 1 1 13.54 26.65 1.39 -0.00066 0.01415 510 109 1 4 0 50.400 29.16 20.00 26.65 33.44 1.9 1004.85 -1249 -841 -207 220 569 765 906 889 519 344 144 -240 -615 -695 -701 -473 -154 154 215 231 215 111 296 380 475 572 569 -55 -623 -867 -901 -662 -16 273 407 358 147 -170 -312 -202 -76 215 358 536 653 615 551 328 -120 -570 -964 -1218 -1005 -642 -185 130 368 321 348 336 470 553 586 460 235 114 -64 -290 -577 -609 -593 -416 -89 -29 -143 -264 -404 -555 -706 -584 -275 -208 -220 -231 -100 -144 -337 -313 -2 181 540 905 890 873 717 513 341 -496 -1183 -1317 -1155 -845 -483 -173 153 264 -51 -263 -298 -333 -265 -137 18 234 660 967 970 650 259 -111 -353 -56 311 384 539 645 350 329 217 -249 -260 -297 -647 -543 -383 -298 49 339 292 221 308 331 552 749 627 120 -408 -830 -903 -722 -1168 -778 -198 212 562 771 906 897 523 343 146 -241 -610 -681 -687 -467 -155 155 221 233 218 113 301 389 489 589 585 -56 -634 -854 -882 -654 -17 280 429 377 154 -176 -319 -206 -78 222 374 553 679 641 570 336 -125 -574 -970 -1203 -986 -640 -186 134 377 331 357 344 482 573 610 477 241 115 -65 -294 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1.4297e-04 -6.0000e+00 4.4761e-04 -6.3779e-03 3.1337e-04 12 8 8 10 0 0 79.83 26.66 1.34 -0.00638 0.00699 1107 176 1 4 0 31.180 29.16 19.99 26.66 33.49 1.9 1005.17 -1253 -844 -238 203 568 757 871 854 549 343 151 -273 -600 -717 -689 -481 -158 150 179 253 201 102 266 394 445 590 571 -47 -618 -845 -868 -656 -21 249 376 365 144 -140 -292 -187 -90 191 354 547 643 621 548 357 -109 -539 -947 -1225 -1016 -655 -202 109 353 321 349 340 438 530 551 454 232 112 -25 -289 -591 -641 -596 -433 -87 -24 -95 -245 -369 -530 -728 -598 -318 -204 -249 -220 -86 -137 -308 -307 -12 152 535 880 843 824 667 463 294 -497 -1180 -1275 -1112 -804 -386 -123 152 227 -114 -307 -300 -307 -223 -69 49 247 645 942 919 644 286 -99 -340 -76 304 368 530 584 306 320 265 -200 -236 -281 -633 -537 -365 -281 40 322 292 244 310 331 531 720 598 112 -391 -824 -896 -755 -1163 -798 -226 200 554 754 885 876 563 347 151 -271 -588 -694 -667 -469 -156 153 182 259 206 105 274 408 464 614 594 -49 -619 -843 -862 -656 -21 258 390 377 148 -146 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