File name: Pandora225s1_Cebu_20251101_L2Fit_fwvt1c2d20220603p1-8.txt File generation date: 20251107T011539.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 225 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora225_OF_v2d20220531.txt Instrument calibration file used: Pandora225s1_CF_v2d20220603.txt Level 1 file used: Pandora225s1_Cebu_20251101_L1_smca1c2d20220603p1-8.txt Full location name: University of San Carlos - Talamban Campus Short location name: Cebu Country of location: Philippines Location latitude [deg]: 10.3551 Location longitude [deg]: 123.9111 Location altitude [m]: 67 Local noon date: 20251101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial instrument deployment First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0330 492.1544 492.2759 492.3973 492.5187 492.6401 492.7615 492.8828 493.0042 493.1255 493.2468 493.3681 493.4894 493.6106 493.7319 493.8531 493.9743 494.0955 494.2167 494.3378 494.4590 494.5801 494.7012 494.8223 494.9434 495.0644 495.1855 495.3065 495.4275 495.5485 495.6695 495.7904 495.9114 496.0323 496.1532 496.2741 496.3950 496.5158 496.6366 496.7575 496.8783 496.9991 497.1198 497.2406 497.3613 497.4820 497.6027 497.7234 497.8441 497.9647 498.0854 498.2060 498.3266 498.4472 498.5677 498.6883 498.8088 498.9293 499.0498 499.1703 499.2908 499.4112 499.5317 499.6521 499.7725 499.8928 500.0132 500.1335 500.2539 500.3742 500.4945 500.6148 500.7350 500.8553 500.9755 501.0957 501.2159 501.3361 501.4562 501.5763 501.6965 501.8166 501.9367 502.0567 502.1768 502.2968 502.4168 502.5368 502.6568 502.7768 502.8968 503.0167 503.1366 503.2565 503.3764 503.4963 503.6161 503.7359 503.8558 503.9756 504.0953 504.2151 504.3348 504.4546 504.5743 504.6940 504.8137 504.9333 505.0530 505.1726 505.2922 505.4118 505.5314 505.6509 505.7705 505.8900 506.0095 506.1290 506.2484 506.3679 506.4873 506.6068 506.7262 506.8455 506.9649 507.0843 507.2036 507.3229 507.4422 507.5615 507.6808 507.8000 507.9192 508.0385 508.1576 508.2768 508.3960 508.5151 508.6343 508.7534 508.8725 508.9915 509.1106 509.2296 509.3487 509.4677 509.5867 509.7056 509.8246 509.9435 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20251031T214629.0Z 9435.907281 41 1 34.30 2 88.16 105.01 154.06 267.48 0.00 1 0.00 1 0 22 7.882e-03 7.703e-03 1.143e-03 1.136e-03 3.939452e+04 9.543092e+01 2.408918e+03 -6.000000e+00 4.378381e+02 294.36 -2.00 20.00 -2.00 505.46 0.00e+00 2.499594e-03 3.183664e-05 1.755564e-04 -6.000000e+00 2.241593e-04 294.36 -2.00 20.00 -2.00 500.69 0.00e+00 1.748390e+00 2.176792e-02 1.827190e-01 -6.000000e+00 1.513731e-01 227.31 -2.00 3.06 -2.00 502.24 0.00e+00 16.347 0.005 489.00 513.00 1 4.7602e+00 1.6691e-03 2.8259e-02 -6.0000e+00 1.1641e-02 -2.5690e-02 4.1561e-04 5.0168e-03 -6.0000e+00 3.0325e-03 1.3367e-03 2.6121e-03 7.3206e-05 1.5517e-04 -6.0000e+00 6.7456e-04 -3.6826e-02 4.9274e-04 12 8 8 10 0 0 84.18 26.04 2.81 -0.03683 -0.01871 14 2 1 4 0 2449.640 28.62 20.00 26.04 33.21 2.6 990.89 -2109 -1233 -507 249 762 761 1281 897 785 440 113 -406 -1003 -925 -1057 -987 -601 46 123 187 227 218 335 419 635 945 790 63 -627 -1238 -1418 -999 -235 375 718 689 245 -169 -233 -257 65 475 443 1051 997 1017 691 583 95 -479 -1493 -1726 -1429 -855 -287 359 741 471 664 556 542 668 906 589 498 186 -2 -210 -571 -1052 -917 -533 -413 -141 -326 -410 -614 -469 -754 -703 -44 143 -198 -291 -183 -327 -723 -412 -87 228 908 1302 1146 1056 862 632 784 -350 -1553 -1887 -1739 -1168 -544 43 606 552 273 -46 -130 -470 -461 -173 -204 154 450 1329 1494 926 274 -710 -840 -482 425 813 1050 1244 959 529 -59 -558 -893 -616 -1197 -1063 -849 -600 -114 346 504 335 371 467 731 1035 1031 433 -394 -1209 -1211 -1152 -1918 -1138 -485 235 735 750 1283 911 794 440 112 -400 -978 -890 -1019 -960 -594 46 128 188 228 220 338 426 650 966 806 64 -647 -1242 -1418 -1006 -231 383 754 723 255 -175 -239 -262 67 491 465 1114 1068 1091 739 615 99 -486 -1485 -1686 -1387 -843 -292 375 787 504 706 590 579 690 937 610 532 195 -2 -216 -580 -1058 -921 -539 -422 -146 -339 -419 -612 -457 -726 -669 -42 137 -191 -287 -183 -330 -725 -403 -83 218 873 1262 1099 965 772 530 655 -290 -1289 -1565 -1406 -995 -500 41 601 536 276 -46 -130 -463 -459 -171 -200 149 434 1300 1521 974 289 -735 -839 -465 420 777 1013 1211 945 521 -59 -554 -869 -589 -1162 -1041 -848 -617 -119 362 519 354 398 506 788 1106 1092 458 -414 -1271 -1275 -1225 SO 20251031T214903.7Z 9435.909071 47 1 32.68 2 87.55 105.13 154.66 267.56 0.00 1 0.00 1 0 29 6.735e-03 6.619e-03 7.161e-04 7.127e-04 3.596532e+04 5.861111e+01 2.234763e+03 -6.000000e+00 3.739475e+02 294.36 -2.00 20.00 -2.00 505.44 0.00e+00 1.918515e-03 1.995331e-05 1.437528e-04 -6.000000e+00 1.915144e-04 294.36 -2.00 20.00 -2.00 500.65 0.00e+00 1.549593e+00 1.368018e-02 1.648611e-01 -6.000000e+00 1.294123e-01 227.31 -2.00 3.06 -2.00 502.22 0.00e+00 14.772 0.004 489.00 513.00 1 4.1656e+00 1.0488e-03 2.5517e-02 -6.0000e+00 9.9501e-03 -2.2133e-02 2.6244e-04 4.5528e-03 -6.0000e+00 2.5950e-03 3.1101e-03 3.3693e-03 4.7255e-05 1.5716e-04 -6.0000e+00 5.7650e-04 8.1881e-03 1.6202e-04 12 9 9 12 1 1 52.83 26.03 2.24 0.00819 0.03156 24 4 1 4 0 1306.990 28.62 20.00 26.03 33.29 2.6 991.78 -1618 -1094 -256 353 601 909 1067 967 725 345 263 -468 -713 -1065 -907 -624 -312 146 155 133 76 72 352 641 459 559 650 30 -700 -1090 -1002 -910 -134 344 634 469 324 -289 -367 -70 -191 211 407 847 693 743 756 443 176 -734 -1114 -1427 -1385 -797 -197 241 571 393 401 529 623 795 577 700 407 114 -185 -286 -642 -801 -883 -604 -207 18 -127 -287 -507 -635 -746 -608 -113 100 -280 -220 -138 -249 -512 -367 -41 329 847 1090 1138 1015 757 684 246 -261 -1285 -1568 -1480 -1001 -648 -114 486 614 204 -241 -302 -495 -368 -390 -21 262 658 1124 1108 691 268 -511 -682 -366 359 624 876 850 728 291 201 -376 -710 -576 -912 -861 -664 -302 -22 460 217 347 354 466 606 941 923 496 -489 -982 -1147 -903 -1496 -1031 -240 342 596 919 1059 970 726 341 257 -456 -711 -1053 -896 -621 -304 146 159 138 79 75 366 670 485 591 684 32 -711 -1074 -981 -901 -135 350 661 489 333 -296 -372 -70 -194 216 422 888 735 788 796 461 180 -736 -1126 -1417 -1370 -800 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4.1524e-03 -6.0000e+00 3.0508e-03 1.2986e-03 2.8845e-03 7.5950e-05 1.5174e-04 -6.0000e+00 6.7855e-04 -6.5540e-02 6.5927e-04 12 8 8 10 0 0 50.33 26.03 2.11 -0.06554 -0.04553 11 2 1 4 0 3009.630 28.62 20.00 26.03 33.37 2.6 992.74 -1767 -1312 -146 495 668 838 1203 1348 997 537 168 -146 -791 -714 -1110 -799 -624 286 495 182 283 115 91 313 816 699 783 360 -855 -1539 -1479 -1092 -409 650 751 512 243 -292 -600 -349 -5 26 478 934 913 902 801 736 234 -489 -1416 -1486 -1556 -1160 -87 263 440 549 322 427 740 688 799 727 520 -59 -280 -420 -563 -1021 -1089 -839 -293 212 18 -552 -675 -712 -848 -871 -239 -84 -510 -338 -214 -133 -449 -438 -119 303 930 1570 1703 1282 980 420 341 -638 -1270 -1774 -1872 -1445 -399 292 687 527 -298 -560 -574 -580 -186 -218 14 -11 469 1089 1366 937 808 -243 -719 -935 161 797 925 933 505 546 191 -105 -469 -486 -838 -1110 -569 -369 121 398 402 437 403 866 755 1130 793 376 -534 -1085 -1303 -1019 -1654 -1250 -137 482 666 853 1196 1352 999 532 166 -142 -794 -707 -1104 -799 -609 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