File name: Pandora31s1_CharlesCityVA_20220227_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T105816.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220227_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220227T180719.5Z 8093.755087 333 1 2.25 2 46.72 195.67 78.30 224.92 0.00 1 0.00 1 0 17 9.749e-03 6.278e-03 5.504e-03 3.701e-03 1.916828e-01 1.883367e-03 2.305736e-03 -6.000000e+00 5.531679e-03 225.77 -2.00 3.44 -2.00 315.05 0.00e+00 3.279043e-04 1.502947e-04 1.833246e-05 -6.000000e+00 2.242956e-04 278.99 -2.00 20.00 -2.00 314.78 0.00e+00 1.456 0.000 302.00 328.00 3 4.2550e+00 4.8271e-03 1.7380e-02 -6.0000e+00 1.3782e-02 2.2746e-02 5.3830e-03 9.5277e-03 -6.0000e+00 1.5058e-02 1.7814e-03 3.0739e-03 4.7233e-03 -6.0000e+00 8.8650e-03 -2.8905e-03 1.3490e-03 1.3404e-03 -6.0000e+00 3.6982e-03 1.4366e-03 -9.3565e-05 1.0559e-04 1.7999e-05 -6.0000e+00 2.6732e-04 -1.8189e-02 -5.8068e-06 12 1 1 12 1 1 999.00 22.12 0.28 -0.01819 -0.01889 2 13 1 5 0 687.980 25.39 20.01 22.12 15.42 30.8 970.17 -1101 253 -2957 -3539 -2230 -419 -1176 3382 3108 -701 -468 700 252 -112 -615 -913 -361 -1150 2247 -245 464 464 447 1597 -1006 93 -989 1249 224 3080 1615 3394 -451 -48 -1060 -658 849 734 -230 -855 -553 -1636 -1115 -1225 -832 12 -555 -823 -874 807 150 1154 876 750 387 685 486 997 261 1546 276 68 1419 338 -41 148 -97 -238 696 322 -116 -339 -436 241 -698 64 -439 574 -56 -213 -666 -959 -919 -907 -1100 -936 -482 -499 355 98 135 651 258 450 963 -543 469 35 254 240 -198 411 -478 -60 -651 -532 -697 -126 513 157 -199 -357 -98 -245 405 354 663 111 132 -284 -60 155 107 97 423 425 561 1420 508 499 64 146 -126 296 -539 -448 330 -65 -419 -105 -120 -86 -692 -358 85 -1000 -1115 -642 -118 -354 1071 1050 -246 -161 247 96 -47 -277 -429 -172 -560 1093 -124 233 232 228 837 -551 51 -540 639 111 1485 813 1761 -250 -26 -558 -348 477 457 -160 -647 -434 -1320 -909 -999 -676 10 -440 -641 -669 615 118 937 734 645 338 602 430 875 228 1343 247 64 1374 337 -41 137 -86 -210 638 317 -120 -357 -456 246 -684 59 -382 484 -49 -199 -662 -1003 -991 -1005 -1269 -1120 -592 -621 439 118 156 711 268 461 1016 -608 553 44 322 300 -239 474 -543 -70 -795 -668 -897 -165 689 218 -282 -505 -135 -324 509 432 807 139 172 -384 -82 211 144 127 538 526 676 1709 634 643 84 195 -169 406 -768 -654 486 -97 -629 -156 -176 -123 -988 SS 20220227T192521.3Z 8093.809274 383 1 5.80 2 53.89 219.09 89.83 237.57 0.00 1 0.00 1 0 17 7.967e-03 5.640e-03 3.908e-03 2.233e-03 2.246528e-01 1.130053e-03 2.674064e-03 -6.000000e+00 4.521868e-03 225.77 -2.00 3.44 -2.00 315.71 0.00e+00 3.689148e-04 1.030119e-04 2.773727e-05 -6.000000e+00 1.833023e-04 278.99 -2.00 20.00 -2.00 315.41 0.00e+00 1.692 0.000 302.00 328.00 3 4.2040e+00 2.9125e-03 2.0230e-02 -6.0000e+00 1.1267e-02 2.0176e-02 3.2545e-03 1.1119e-02 -6.0000e+00 1.2308e-02 -5.2668e-05 1.8709e-03 5.5146e-03 -6.0000e+00 7.2461e-03 -2.3269e-03 8.4506e-04 1.5703e-03 -6.0000e+00 3.0235e-03 1.1297e-03 -4.9072e-05 6.3986e-05 2.0013e-05 -6.0000e+00 2.1845e-04 -1.8626e-02 5.2401e-05 12 1 1 12 1 1 93.71 22.21 0.28 -0.01863 -0.01899 7 13 1 5 0 702.840 25.39 20.00 22.21 16.13 30.8 972.85 -1065 -1779 -752 -2469 -3352 1312 -713 600 1544 670 -1288 -94 246 -17 -453 -676 -578 -180 657 906 826 128 1395 1291 448 509 -1279 -21 76 929 817 1713 459 -957 -1445 -1127 -983 132 -300 -753 -859 -805 -830 -1422 -637 -480 -524 -545 -95 1194 500 1116 971 734 661 1238 405 390 292 1092 1313 1380 1334 766 49 -525 -440 -29 506 446 36 416 -112 55 -82 126 -175 -289 -381 -820 -626 -1322 -1515 -1294 -1083 -814 -124 -278 -202 -117 446 407 234 631 660 112 757 -159 -63 -142 89 -569 -238 207 -651 -861 -507 -252 -46 -152 16 -43 -232 217 281 550 423 352 212 -126 -117 148 196 132 572 693 652 921 416 567 214 150 12 274 -110 -121 -220 -26 -361 -194 -549 -211 -427 -266 -449 -196 -591 -727 285 -162 151 419 177 -359 -26 76 -6 -170 -260 -228 -73 274 388 356 55 612 570 209 243 -606 -10 32 392 366 780 226 -474 -669 -526 -510 73 -191 -529 -623 -605 -616 -1063 -488 -364 -388 -391 -69 865 372 846 776 593 547 1037 346 330 243 903 1127 1234 1246 729 47 -479 -386 -25 454 424 36 427 -115 56 -79 113 -147 -242 -327 -767 -611 -1380 -1628 -1415 -1234 -962 -153 -343 -248 -141 520 444 241 655 705 125 904 -199 -82 -181 109 -664 -273 240 -804 -1094 -654 -339 -63 -216 22 -63 -329 291 364 688 531 451 284 -176 -163 208 268 177 744 881 811 1153 542 763 294 206 17 388 -161 -183 -341 -41 -561 -300 -845 -313 -638 SS 20220227T193324.8Z 8093.814870 389 1 2.93 2 54.92 221.19 91.13 238.76 0.00 1 0.00 1 0 17 1.486e-02 8.628e-03 1.121e-02 6.044e-03 2.286488e-01 3.055095e-03 2.704451e-03 -6.000000e+00 8.432016e-03 225.77 -2.00 3.44 -2.00 315.88 0.00e+00 8.181546e-04 2.899059e-04 3.055940e-05 -6.000000e+00 3.418075e-04 278.99 -2.00 20.00 -2.00 315.58 0.00e+00 1.735 0.000 302.00 328.00 3 4.8358e+00 7.8853e-03 2.0678e-02 -6.0000e+00 2.1009e-02 2.9513e-02 8.8141e-03 1.1289e-02 -6.0000e+00 2.2951e-02 3.0059e-03 5.0825e-03 5.5981e-03 -6.0000e+00 1.3512e-02 -4.0781e-03 2.3237e-03 1.5960e-03 -6.0000e+00 5.6384e-03 5.6802e-04 1.8415e-04 1.7324e-04 1.9882e-05 -6.0000e+00 4.0735e-04 -2.0018e-02 5.8294e-06 12 9 1 12 1 1 999.00 22.22 0.46 -0.02002 -0.01863 1 7 1 5 0 1374.040 25.47 20.00 22.22 16.35 30.8 973.72 1557 3405 177 -695 -6745 5977 -111 3032 -861 -2762 503 -565 2077 -4500 2176 -1579 -907 -1608 1745 208 171 1261 439 586 -2992 1457 -2266 588 -1214 1660 -2684 4303 777 -1762 -2579 -782 -3105 -183 675 -702 841 -1055 -1463 -1634 623 -116 986 -125 -431 1197 582 1120 28 1431 186 2724 503 1643 1014 312 -166 1910 3127 -260 278 -1056 -1183 -270 503 53 -164 -740 224 1226 1199 410 -642 325 -2350 -1154 -761 -1081 -1228 -553 -1229 -865 -1399 -333 -430 -479 795 -406 789 -353 508 1031 688 64 -269 362 -739 -40 -25 769 -1375 -1127 -423 144 407 985 -87 -1 621 -361 16 137 536 417 601 -29 82 -258 153 21 -200 1041 188 1347 -701 611 86 487 -637 226 -230 733 99 -339 -769 -373 328 -481 -325 345 780 41 -151 -1409 1116 -23 683 -215 -711 125 -148 587 -1486 748 -589 -344 -631 686 85 70 509 183 253 -1368 657 -1033 249 -499 672 -1174 1888 367 -843 -1181 -357 -1557 -101 416 -476 591 -768 -1085 -1217 457 -85 707 -89 -303 840 426 850 22 1152 153 2234 421 1358 833 258 -141 1683 2868 -250 262 -951 -1023 -231 449 51 -166 -764 228 1213 1132 365 -542 266 -2036 -1066 -750 -1125 -1323 -611 -1421 -1036 -1731 -416 -536 -582 915 -446 818 -365 541 1159 823 81 -350 462 -914 -47 -29 904 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