File name: Pandora31s1_CharlesCityVA_20220307_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T105913.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220307_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220307 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220307T122030.6Z 8101.514243 65 1 50.78 2 81.23 103.43 109.83 52.00 0.00 1 0.00 1 0 17 3.951e-01 6.988e-03 2.331e-01 2.739e-03 6.660035e-01 1.517922e-03 7.037605e-03 -6.000000e+00 2.364223e-01 226.17 -2.00 3.44 -2.00 321.19 0.00e+00 8.251203e-04 5.981226e-04 6.738690e-04 -6.000000e+00 1.158172e-02 279.41 -2.00 20.00 -2.00 320.86 0.00e+00 6.197 0.004 302.00 328.00 3 1.6361e+00 4.5661e-03 7.0506e-02 -6.0000e+00 5.9154e-01 -2.9182e-02 6.6933e-03 3.5158e-02 -6.0000e+00 6.5218e-01 4.4190e-02 8.3058e-03 1.9839e-02 -6.0000e+00 3.6898e-01 -2.8887e-02 4.0791e-03 6.7002e-03 -6.0000e+00 1.6256e-01 1.2084e-04 2.5301e-04 8.3130e-05 7.6610e-05 -6.0000e+00 1.1591e-02 -2.4953e-02 1.2272e-04 11 8 0 10 0 0 92.93 23.27 0.48 -0.02495 -0.02305 122 22 1 5 0 416.100 26.32 20.00 23.27 24.36 31.8 1014.55 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -3079 5305 101234 -29196 900000 900000 -121589 33662 203531 122582 -36858 900000 7719 900000 -24384 304290 -53180 14735 -5149 38617 -26716 26925 26057 23999 4659 -8626 -1647 2846 56444 15947 2374 9488 15299 -9234 20029 7446 -2389 -1113 5372 14537 -6573 10324 3155 -3536 -263 510 -2296 1812 785 -298 -8234 1054 6026 2920 -4370 2631 -3489 141 -955 -290 -851 2 -2225 2638 106 16 -979 -1981 969 -1531 1705 -124 -833 -1203 -781 -97 -219 492 1232 -485 693 785 -797 670 396 363 1266 303 449 -3 -574 195 474 -83 -1270 -1670 -80 504 -52 -281 -315 -310 -68 -1 -455 407 806 398 528 266 -311 777 162 -678 -24 -160 151 560 293 -89 -194 -376 -40 -373 -115 -157 178 226 -290 136 -102 485 -121 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -8 14 270 -170 900000 900000 -2833 204 542 356 -499 900000 82 900000 -406 810 -1286 193 -84 458 -682 528 599 543 124 -272 -56 112 1628 828 159 640 1029 -816 1351 588 -215 -104 501 1355 -858 1283 430 -566 -43 88 -422 318 136 -52 -1636 214 1334 749 -1255 692 -981 40 -312 -109 -326 1 -882 1010 38 5 -305 -648 352 -632 798 -67 -499 -772 -536 -70 -156 358 885 -339 480 512 -515 449 301 300 1202 310 496 -3 -593 193 432 -77 -1291 -1802 -85 570 -65 -373 -463 -481 -105 -2 -647 553 1106 575 809 423 -491 1172 238 -968 -35 -225 206 804 449 -154 -349 -725 -81 -764 -251 -362 399 515 -661 311 -222 989 -242 SS 20220307T123236.7Z 8101.522647 70 1 50.79 2 78.89 105.37 107.95 54.21 0.00 1 0.00 1 0 25 1.735e-01 4.045e-03 1.124e-01 1.321e-03 5.618099e-01 6.776350e-04 6.184718e-03 -6.000000e+00 9.867113e-02 226.17 -2.00 3.44 -2.00 320.35 0.00e+00 5.686380e-04 2.148974e-04 3.736509e-04 -6.000000e+00 3.991650e-03 279.41 -2.00 20.00 -2.00 320.03 0.00e+00 5.009 0.002 302.00 328.00 3 1.5208e+00 1.9185e-03 5.7332e-02 -6.0000e+00 2.4608e-01 -2.8542e-03 2.3929e-03 2.8633e-02 -6.0000e+00 2.6870e-01 2.4225e-02 2.5456e-03 1.5106e-02 -6.0000e+00 1.5814e-01 -2.1542e-02 1.3337e-03 4.7599e-03 -6.0000e+00 6.5972e-02 4.5113e-04 -3.7026e-04 3.7877e-05 5.1919e-05 -6.0000e+00 4.7568e-03 -2.2826e-02 5.5202e-05 10 0 0 10 0 0 99.22 23.28 0.29 -0.02283 -0.02561 261 47 1 5 0 194.500 26.32 20.00 23.28 25.06 32.1 1018.24 67346 -6768 90910 64590 73481 -59014 -2696 84101 45101 33168 -47520 -22403 -24867 -8019 3413 223 -24167 -3924 1843 -3619 -4990 6378 -3128 -5450 -3038 998 -12311 -10672 -6371 -3028 -11162 4663 -3265 1437 -4133 -6619 -5900 1368 2092 -899 -586 681 1465 -3228 1753 -1034 -1093 -2801 839 2588 953 2241 651 230 610 915 -366 460 -258 989 -1259 1056 2278 1264 -267 853 -661 422 511 431 481 215 -232 902 0 498 -503 -553 -126 -765 -167 -1013 -1293 -1493 -980 -5 -95 78 475 338 834 682 340 534 311 211 751 258 246 -35 -611 -20 81 -15 -512 -1034 -503 -157 -128 -215 -122 -167 -174 105 -18 556 488 248 138 -131 -194 167 -111 -230 33 183 482 679 325 247 -54 -120 -226 -153 -70 -95 106 37 -262 231 -147 26 -17 156 -37 199 175 170 -484 -16 238 215 192 -596 -255 -364 -125 58 5 -708 -103 49 -109 -155 181 -105 -207 -123 41 -583 -479 -272 -137 -647 270 -234 102 -297 -502 -463 121 227 -119 -86 106 237 -558 293 -181 -195 -525 158 514 215 511 165 63 177 277 -115 143 -79 297 -406 369 888 550 -121 368 -286 187 235 227 277 129 -137 500 0 229 -236 -264 -63 -449 -113 -728 -1011 -1242 -871 -5 -87 74 446 305 743 568 273 441 288 210 853 313 319 -45 -739 -23 87 -16 -577 -1239 -633 -211 -177 -328 -193 -275 -284 163 -28 820 726 388 218 -215 -319 266 -171 -361 49 264 674 986 528 423 -95 -226 -444 -302 -149 -200 229 82 -580 491 -311 53 -32 SS 20220307T123802.5Z 8101.526418 73 1 50.86 2 77.85 106.25 107.09 55.18 0.00 1 0.00 1 0 17 6.124e-02 3.834e-03 2.558e-02 9.071e-04 5.217481e-01 4.608499e-04 5.838542e-03 -6.000000e+00 3.482522e-02 226.17 -2.00 3.44 -2.00 319.96 0.00e+00 7.343557e-04 1.308369e-04 2.918454e-04 -6.000000e+00 1.408784e-03 279.41 -2.00 20.00 -2.00 319.64 0.00e+00 4.613 0.002 302.00 328.00 3 1.2995e+00 1.2870e-03 5.2874e-02 -6.0000e+00 8.6852e-02 6.8099e-03 1.5383e-03 2.6422e-02 -6.0000e+00 9.4833e-02 8.2643e-03 1.4884e-03 1.3645e-02 -6.0000e+00 5.5813e-02 -1.3789e-02 7.9397e-04 4.1862e-03 -6.0000e+00 2.3285e-02 8.5143e-04 -4.1212e-04 2.6154e-05 4.6987e-05 -6.0000e+00 1.6788e-03 -2.3074e-02 5.3514e-05 10 0 0 10 0 0 99.42 23.28 0.29 -0.02307 -0.02617 347 62 1 5 0 146.550 26.32 20.00 23.28 25.28 31.8 1018.81 10935 -21929 12325 -26673 -30795 -29844 -12907 -12097 14807 -3764 -17071 -15703 -9418 -3961 -5016 -367 -16169 -3873 -4321 229 -5868 4384 -2318 -2964 -3862 -318 -7924 -7530 -5395 -1082 -2178 923 835 -325 -797 -2720 -2857 239 184 -833 -1003 722 -773 -800 293 -116 -925 -551 149 1632 387 1374 724 -111 412 434 -12 458 501 485 130 1131 1910 1157 111 303 -703 344 239 624 265 506 3 324 296 -84 -666 -722 -82 -668 -87 -1273 -1284 -1390 -651 -410 -79 301 355 358 422 711 325 855 400 585 691 263 55 7 -287 -387 278 -278 -589 -938 -620 -374 -40 -113 -109 -177 -82 -11 -26 391 447 300 9 -59 -268 124 -5 -71 217 232 620 688 398 84 -5 -108 -186 -25 -110 -149 151 42 -191 109 -156 30 -152 78 -246 102 -309 -346 -341 -139 -150 158 -52 -282 -294 -206 -93 -144 -12 -663 -154 -185 10 -274 188 -114 -160 -228 -19 -516 -468 -324 -67 -160 76 78 -32 -75 -266 -317 28 27 -145 -194 146 -166 -175 64 -26 -212 -129 36 411 109 392 226 -38 147 161 -4 173 185 178 50 477 899 559 55 144 -331 165 127 380 177 326 2 209 175 -45 -335 -367 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