File name: Pandora31s1_CharlesCityVA_20220316_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T110722.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220316_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220316 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220316T124031.6Z 8110.528143 275 1 51.38 2 74.66 104.25 110.29 307.27 0.00 1 0.00 1 0 17 1.723e-01 9.017e-03 1.152e-01 2.766e-03 5.157582e-01 1.435118e-03 5.725509e-03 -6.000000e+00 9.983794e-02 226.66 -2.00 3.44 -2.00 319.84 0.00e+00 -1.711265e-04 3.985498e-04 2.851636e-04 -6.000000e+00 4.280985e-03 279.91 -2.00 20.00 -2.00 319.52 0.00e+00 3.710 0.001 302.00 328.00 3 4.2953e+00 3.9840e-03 4.5207e-02 -6.0000e+00 2.5051e-01 3.2842e-03 4.7462e-03 2.5916e-02 -6.0000e+00 2.7427e-01 4.1733e-02 4.5681e-03 1.3429e-02 -6.0000e+00 1.5923e-01 -3.0917e-02 2.4435e-03 4.1120e-03 -6.0000e+00 6.6939e-02 9.7581e-05 2.5422e-05 8.1240e-05 4.4210e-05 -6.0000e+00 4.9873e-03 -1.6239e-02 1.1598e-05 11 8 0 10 0 0 99.66 22.24 0.44 -0.01624 -0.01605 32 6 1 5 0 1604.790 25.47 20.00 22.24 17.71 31.1 981.82 124393 900000 900000 900000 33869 25520 900000 900000 900000 89357 -36395 -23699 46178 -33727 33087 9571 -39821 2705 17353 10646 -3686 25433 -10603 9163 -11655 42761 -20438 12991 -13552 7661 -20956 11760 -2393 3496 2241 5206 -8297 2648 15588 -2084 -110 3092 2997 -9367 6968 2497 169 -1054 3140 7477 -2136 6358 -2378 -2312 -1862 -682 -281 1678 -720 56 -3167 349 4307 1014 -3106 1407 -1927 -6 -219 19 -201 856 -1397 2964 342 2075 277 -1256 1808 -1971 1262 -612 -451 -1138 -1203 -502 38 -247 577 -868 1337 887 -209 714 244 874 476 631 234 96 -1379 703 384 43 -1376 -2048 -268 589 257 -545 109 -589 -358 45 1 674 852 -47 739 367 -516 787 -13 -546 -212 242 116 855 725 -303 -242 -348 -140 -250 -236 -101 89 359 -510 421 -81 446 -409 335 900000 900000 900000 205 174 900000 900000 900000 521 -745 -493 606 -1153 722 297 -2146 106 635 436 -176 943 -592 467 -777 1802 -1554 694 -918 461 -1892 896 -232 329 205 477 -975 336 2128 -388 -22 636 640 -2268 1473 558 39 -250 739 1800 -614 1848 -804 -835 -700 -263 -110 641 -276 21 -1290 150 1978 515 -1646 692 -959 -3 -121 12 -133 575 -941 1840 201 1106 142 -661 1019 -1300 906 -489 -381 -1010 -1128 -491 38 -254 586 -861 1233 778 -178 620 230 903 544 782 303 122 -1691 793 416 48 -1629 -2528 -340 776 359 -817 172 -950 -571 69 2 957 1217 -70 1138 582 -822 1218 -20 -812 -305 339 159 1199 1091 -491 -412 -611 -253 -467 -460 -202 181 737 -1050 842 -157 837 -764 SS 20220316T125042.1Z 8110.535210 278 1 52.01 2 72.70 105.95 111.85 309.19 0.00 1 0.00 1 0 17 2.735e-01 1.023e-02 1.015e-01 2.736e-03 4.599008e-01 1.399215e-03 5.180036e-03 -6.000000e+00 1.569543e-01 226.66 -2.00 3.44 -2.00 319.31 0.00e+00 -1.000082e-04 3.333002e-04 2.092229e-04 -6.000000e+00 6.666956e-03 279.91 -2.00 20.00 -2.00 318.99 0.00e+00 3.315 0.001 302.00 328.00 3 4.7823e+00 3.8219e-03 4.0338e-02 -6.0000e+00 3.9344e-01 9.3484e-03 4.4164e-03 2.2994e-02 -6.0000e+00 4.3013e-01 4.3950e-02 3.7794e-03 1.1725e-02 -6.0000e+00 2.5133e-01 -3.1889e-02 2.0467e-03 3.5122e-03 -6.0000e+00 1.0504e-01 9.2875e-05 2.6686e-04 8.0002e-05 3.7359e-05 -6.0000e+00 7.8022e-03 -1.6765e-02 3.2340e-05 12 9 8 11 32 0 99.90 22.25 0.25 -0.01677 -0.01476 19 3 1 5 0 2737.110 25.47 20.00 22.25 18.28 31.2 985.31 47761 276907 900000 900000 -2318 36610 89785 900000 900000 49638 -42938 3769 15755 -24005 34051 -10130 -34335 5363 18257 632 -1470 17729 6092 7160 -5403 25822 -14247 5932 -6798 6304 -16483 7700 -3862 6927 -6069 -2260 -5582 4125 11363 1 -1236 368 2730 -8386 6534 3494 2425 -3505 2867 6503 -2519 5832 -2442 -2135 -1595 -476 -1173 3010 -227 102 -5236 1424 4161 1315 -2190 2042 -2369 -648 1359 -534 1035 -340 -954 2436 383 2439 243 -1328 879 -1980 -1582 14 -503 -975 -1327 158 -442 30 946 -1144 1427 214 304 354 604 93 640 305 629 171 -1160 541 883 10 -708 -1806 -870 729 342 -151 -262 -372 -246 -43 -201 589 1316 19 637 -780 -254 498 61 -941 -19 606 190 535 853 73 -146 -201 -386 16 -235 -63 483 94 -669 441 -318 190 -98 476 738 900000 900000 -37 416 693 900000 900000 760 -1622 104 466 -1239 1206 -609 -2797 325 1041 44 -107 1100 450 570 -517 1935 -1542 508 -643 563 -2057 868 -536 885 -835 -309 -887 712 2206 0 -336 104 779 -2667 1839 1020 717 -1103 870 2013 -915 2131 -1024 -947 -731 -223 -562 1383 -105 47 -2632 732 2286 787 -1349 1166 -1370 -378 847 -374 763 -259 -722 1722 257 1481 142 -790 558 -1441 -1271 12 -459 -929 -1336 165 -479 33 1025 -1217 1412 202 276 326 596 101 754 389 830 223 -1453 628 984 11 -862 -2293 -1138 982 486 -228 -415 -598 -390 -65 -293 829 1855 28 971 -1234 -400 769 93 -1401 -28 843 259 746 1263 116 -241 -342 -671 28 -440 -120 940 185 -1324 850 -597 345 -176 SS 20220316T125735.6Z 8110.539996 282 1 50.66 2 71.39 107.12 112.88 310.52 0.00 1 0.00 1 0 17 1.810e-01 8.246e-03 4.729e-02 2.417e-03 4.326133e-01 1.216392e-03 4.895774e-03 -6.000000e+00 1.030583e-01 226.66 -2.00 3.44 -2.00 319.01 0.00e+00 -2.498548e-04 2.645037e-04 1.765619e-04 -6.000000e+00 4.164180e-03 279.91 -2.00 20.00 -2.00 318.70 0.00e+00 3.094 0.000 302.00 328.00 3 4.7633e+00 3.3022e-03 3.7732e-02 -6.0000e+00 2.5729e-01 9.5447e-03 3.7721e-03 2.1555e-02 -6.0000e+00 2.8090e-01 3.1964e-02 3.0053e-03 1.0913e-02 -6.0000e+00 1.6527e-01 -2.4439e-02 1.6274e-03 3.2362e-03 -6.0000e+00 6.8823e-02 1.2129e-04 3.4679e-04 6.9791e-05 3.4195e-05 -6.0000e+00 4.9637e-03 -1.7509e-02 7.4773e-05 11 8 0 10 0 0 99.79 22.26 0.31 -0.01751 -0.01490 23 4 1 5 0 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