File name: Pandora31s1_CharlesCityVA_20220408_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T111847.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220408_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220408 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220408T121713.9Z 8133.511966 120 1 50.59 2 72.37 94.27 113.30 21.58 0.00 1 0.00 1 0 17 2.225e-01 6.514e-03 9.646e-02 2.104e-03 4.875650e-01 1.075014e-03 5.436092e-03 -6.000000e+00 1.278343e-01 228.46 -2.00 3.44 -2.00 319.54 0.00e+00 -4.874045e-05 2.701757e-04 2.362579e-04 -6.000000e+00 5.212555e-03 282.11 -2.00 20.00 -2.00 319.22 0.00e+00 3.256 0.001 302.00 328.00 3 4.1233e+00 2.9635e-03 4.0931e-02 -6.0000e+00 3.2113e-01 1.8371e-02 3.4494e-03 2.4526e-02 -6.0000e+00 3.5024e-01 2.8154e-02 3.0471e-03 1.2515e-02 -6.0000e+00 2.0516e-01 -2.2893e-02 1.6399e-03 3.7499e-03 -6.0000e+00 8.5018e-02 1.8030e-04 6.9533e-04 6.0813e-05 3.9716e-05 -6.0000e+00 6.1140e-03 -1.8080e-02 1.8192e-04 11 8 0 10 0 0 99.99 22.51 0.28 -0.01808 -0.01285 72 13 1 5 0 702.510 25.68 19.99 22.51 19.49 31.3 991.50 -29614 40576 221831 -15101 -32206 -21217 34150 4504 900000 95653 1038 -12418 731 -15632 17580 16529 -33842 86 5472 3796 -8639 13686 -4327 901 -4032 5063 -14588 -3778 -4145 -2992 -3883 5671 -2061 -2783 -6048 -1 -2734 4334 5647 -1674 -2820 1047 -213 -3767 2587 2396 -339 -780 2938 4177 -866 2787 -794 -1261 -204 -325 -449 1281 855 2426 -289 399 2421 844 -1031 509 -753 16 -41 1139 72 109 -681 1453 100 1012 114 -659 528 -1724 355 -1294 -548 -1179 -1197 -420 -166 18 397 -301 920 1237 -6 480 228 463 456 474 170 15 -785 -86 614 -91 -776 -1988 -492 95 26 -413 115 -159 -215 186 -14 331 830 -102 270 215 -602 388 -46 -445 389 349 666 877 555 -43 179 -186 -399 -52 -77 70 280 126 -528 100 -275 34 -127 -508 402 455 -244 -570 -349 376 75 900000 809 22 -337 21 -634 622 667 -2354 5 304 224 -583 764 -304 66 -330 399 -1375 -309 -334 -255 -379 575 -249 -346 -742 0 -376 663 1027 -376 -698 264 -56 -1038 680 638 -93 -218 812 1205 -285 963 -303 -515 -86 -141 -199 557 366 1022 -130 193 1263 478 -596 279 -408 9 -25 755 51 80 -495 994 64 594 64 -373 323 -1210 273 -1100 -491 -1105 -1185 -433 -177 19 427 -314 899 1140 -5 436 223 497 537 605 226 20 -988 -101 685 -104 -944 -2531 -643 128 38 -632 185 -260 -348 288 -22 476 1196 -152 421 345 -970 611 -71 -670 565 492 917 1236 839 -69 302 -325 -715 -96 -149 139 564 257 -1079 198 -531 64 -236 SS 20220408T122224.5Z 8133.515562 123 1 13.49 2 71.34 95.08 112.93 22.72 0.00 1 0.00 1 0 17 1.535e-01 6.016e-03 6.767e-02 3.135e-03 4.635091e-01 1.589111e-03 5.240482e-03 -6.000000e+00 8.800307e-02 228.46 -2.00 3.44 -2.00 319.06 0.00e+00 4.361494e-04 3.489998e-04 1.914751e-04 -6.000000e+00 3.532113e-03 282.11 -2.00 20.00 -2.00 318.75 0.00e+00 3.087 0.000 302.00 328.00 3 3.8812e+00 4.3288e-03 3.8859e-02 -6.0000e+00 2.2063e-01 2.3705e-02 4.9453e-03 2.3289e-02 -6.0000e+00 2.4055e-01 1.7537e-02 3.9895e-03 1.1739e-02 -6.0000e+00 1.4133e-01 -1.6177e-02 2.1599e-03 3.4497e-03 -6.0000e+00 5.8633e-02 2.7732e-04 3.5118e-04 8.9367e-05 3.6491e-05 -6.0000e+00 4.2120e-03 -1.7279e-02 9.4633e-05 12 1 1 12 1 1 99.94 22.52 0.30 -0.01728 -0.01464 14 10 1 5 0 888.010 25.68 20.00 22.52 19.62 31.4 992.76 130511 -19807 66266 41950 10226 -13449 6913 26812 69529 35549 -16229 12938 -6236 15829 681 9719 -12828 1079 -3792 1841 -4957 6245 -71 2494 -322 2153 -3097 -4085 1692 -6102 -5250 799 -2397 -3925 -3243 480 -5652 3398 1599 -500 -2331 -480 -377 -3889 2746 334 -1743 -1512 867 892 1151 1660 1628 -880 98 -4 -387 314 1130 1384 454 1214 1839 1445 -948 928 -2144 883 465 531 -7 537 145 896 -441 596 25 -1016 -359 -1345 551 -1060 -830 -1380 -874 189 -391 555 53 35 259 409 198 573 1179 -127 362 -73 593 162 -339 41 216 -242 -693 -1660 -709 -184 -127 60 -118 189 -113 127 -29 60 225 -149 192 -94 -402 498 -78 -208 907 -47 812 776 567 -37 -194 -80 -8 45 151 -81 158 135 -598 136 -499 -153 171 746 -517 792 591 181 -304 144 528 1023 757 -581 397 -275 683 40 588 -1032 82 -319 154 -449 516 -7 245 -35 236 -355 -451 174 -717 -691 112 -382 -645 -506 74 -1035 677 386 -141 -720 -153 -124 -1333 898 112 -599 -524 300 323 450 695 726 -423 48 -2 -201 161 565 690 236 677 1109 928 -621 576 -1332 546 312 392 -5 430 115 680 -317 393 15 -645 -245 -1030 458 -963 -791 -1372 -909 204 -437 625 60 38 268 401 188 549 1199 -142 438 -96 797 215 -432 49 248 -286 -862 -2147 -942 -254 -183 91 -188 305 -180 194 -43 85 323 -220 295 -149 -639 774 -120 -311 1307 -66 1115 1090 846 -58 -321 -135 -14 81 280 -155 306 263 -1171 260 -929 -278 305 SS 20220408T122717.7Z 8133.518955 126 1 50.69 2 70.37 95.85 112.56 23.78 0.00 1 0.00 1 0 17 2.476e-02 4.679e-03 3.905e-03 4.237e-04 4.434436e-01 2.144496e-04 5.087229e-03 -6.000000e+00 1.418686e-02 228.46 -2.00 3.44 -2.00 318.75 0.00e+00 3.461072e-04 4.248122e-05 1.597069e-04 -6.000000e+00 5.695941e-04 282.11 -2.00 20.00 -2.00 318.43 0.00e+00 2.944 0.000 302.00 328.00 3 1.5398e+00 5.7963e-04 3.7137e-02 -6.0000e+00 3.5566e-02 1.5330e-02 6.5679e-04 2.2322e-02 -6.0000e+00 3.8782e-02 -5.8127e-03 4.9180e-04 1.1175e-02 -6.0000e+00 2.2786e-02 -3.8131e-03 2.6431e-04 3.2443e-03 -6.0000e+00 9.4506e-03 3.4378e-03 -3.7483e-04 1.2102e-05 3.5011e-05 -6.0000e+00 6.7929e-04 -1.7076e-02 7.5530e-06 10 0 0 10 0 0 99.92 22.52 0.26 -0.01708 -0.01989 713 128 1 5 0 71.070 25.68 20.01 22.52 19.92 31.6 995.24 -7955 -4831 -6782 -6654 -14654 -10075 -7854 -7608 -3374 -4739 -5943 -7556 -3628 -2852 481 -1123 -2381 -1425 -569 177 -690 447 -581 577 -935 -690 -2205 -1972 -1321 -60 494 1407 105 -1179 -1958 -1992 -1287 -729 120 -1079 -824 -1363 -924 -559 -440 -311 -644 -287 -281 586 542 988 983 933 861 995 604 511 645 930 1100 1287 1618 754 456 218 -131 398 599 357 226 173 -170 98 -81 278 -107 42 -120 -618 -599 -1359 -1469 -1396 -971 -796 -276 -73 57 115 525 592 600 905 649 520 635 197 -210 -65 -384 -282 34 -176 -634 -778 -652 -561 -106 -125 -76 -120 -51 -24 289 497 482 242 -20 -250 -356 -9 -53 202 359 505 804 962 554 341 191 20 -26 54 -133 -141 81 -110 -244 -107 -226 -189 -185 -239 -155 -226 -206 -452 -303 -257 -284 -135 -202 -264 -383 -213 -201 39 -95 -220 -140 -59 19 -75 49 -68 72 -127 -98 -314 -265 -171 -8 76 242 20 -234 -371 -387 -280 -175 35 -342 -285 -499 -349 -213 -168 -120 -249 -111 -111 240 243 450 481 488 470 560 348 291 359 515 636 763 1060 506 307 148 -86 265 414 281 183 145 -140 76 -61 200 -72 28 -83 -498 -520 -1255 -1457 -1388 -1031 -856 -310 -83 64 125 551 604 578 881 660 569 786 262 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