File name: Pandora31s1_CharlesCityVA_20220420_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T112028.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220420_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220420T110554.1Z 8145.462432 229 1 51.23 2 83.37 80.45 73.66 216.50 0.00 1 0.00 1 0 25 5.410e-01 2.424e-02 1.897e-01 7.391e-03 1.024307e+00 5.059930e-03 9.913484e-03 -6.000000e+00 3.505611e-01 229.38 -2.00 3.44 -2.00 322.40 0.00e+00 6.196552e-03 2.422552e-03 1.673920e-03 -6.000000e+00 3.361249e-02 283.28 -2.00 20.00 -2.00 322.03 0.00e+00 7.871 0.008 302.00 328.00 3 1.2631e+00 1.7478e-02 9.6095e-02 -6.0000e+00 8.9939e-01 6.9617e-01 3.4755e-02 5.6494e-02 -6.0000e+00 1.0013e+00 -9.2085e-01 4.3573e-02 3.4053e-02 -6.0000e+00 5.6254e-01 3.5887e-01 1.9147e-02 1.2260e-02 -6.0000e+00 2.6099e-01 2.1495e-05 5.8478e-04 2.3788e-04 1.5285e-04 -6.0000e+00 1.8653e-02 -8.6547e-03 4.1940e-05 12 8 8 10 0 0 26.24 21.68 0.63 -0.00865 -0.00426 57 10 1 5 0 898.610 24.96 20.00 21.68 11.40 30.9 953.85 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -177198 900000 900000 -245959 900000 900000 900000 900000 900000 158484 900000 900000 900000 -191322 900000 900000 900000 -90709 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -38324 900000 900000 900000 900000 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9 -524 2287 -692 3046 2992 1496 1944 -1341 167 -398 -822 1558 -4387 3407 1295 -1829 -246 -86 -2220 -794 2441 -1260 -91 -3857 2814 741 -1259 -2389 -6486 -292 3911 -2232 -2688 -2247 -1170 -2486 -1368 -1540 1276 3186 -2361 2357 2560 2112 3671 1593 -1260 1737 647 -749 2905 2521 213 -1037 -22 -1340 -1091 1054 -811 2600 1805 -2812 2104 -2890 -963 -681 SS 20220420T111628.3Z 8145.469771 232 1 50.91 2 81.29 82.01 74.90 218.51 0.00 1 0.00 1 0 17 3.453e-01 6.437e-03 2.549e-01 2.453e-03 8.739033e-01 1.417598e-03 8.883342e-03 -6.000000e+00 2.050255e-01 229.38 -2.00 3.44 -2.00 321.70 0.00e+00 3.946388e-03 6.026056e-04 1.044218e-03 -6.000000e+00 1.074246e-02 283.28 -2.00 20.00 -2.00 321.36 0.00e+00 6.234 0.004 302.00 328.00 3 1.0927e+00 4.4236e-03 7.7483e-02 -6.0000e+00 5.1887e-01 4.9210e-02 7.8247e-03 4.7429e-02 -6.0000e+00 5.6976e-01 -2.8275e-02 1.0223e-02 2.7909e-02 -6.0000e+00 3.2656e-01 7.6267e-05 4.7629e-03 9.6190e-03 -6.0000e+00 1.4275e-01 1.5082e-04 6.3445e-05 6.9528e-05 1.0650e-04 -6.0000e+00 1.0175e-02 -8.8041e-03 3.9524e-05 11 8 0 10 0 0 34.86 21.68 0.38 -0.00880 -0.00833 178 32 1 5 0 285.960 24.96 20.00 21.68 13.41 31.0 963.44 900000 900000 900000 900000 900000 -138737 900000 900000 900000 900000 -111725 900000 900000 -78352 900000 900000 -193486 104174 -41518 900000 -26492 900000 -45193 109234 41176 900000 -93928 -48328 120100 -25754 -49229 47632 2307 39811 -18017 28543 -39006 28427 23048 3240 -10159 15088 5305 -15208 24952 15081 7292 4331 14991 13498 113 5874 -86 -1028 -831 -1485 -4185 3195 2242 7605 -4297 3612 5382 4897 -4505 5205 -1589 1551 757 1 658 -631 -766 2429 436 1694 366 -2215 2080 -2189 2305 -518 -1339 -1146 -2189 129 -656 44 229 -1536 1109 741 -854 1393 466 99 899 963 625 176 -511 17 349 -473 -1414 -2199 -265 151 -1 -610 -380 -301 66 -12 37 572 827 124 595 133 -114 348 -159 -428 363 -276 458 1006 595 164 -70 -486 -546 -380 -221 123 176 21 -359 295 -111 366 2 900000 900000 900000 900000 900000 -331 900000 900000 900000 900000 -266 900000 900000 -206 900000 900000 -2852 248 -188 900000 -114 900000 -269 260 128 900000 -1232 -403 286 -227 -716 329 30 370 -292 306 -871 441 473 88 -359 451 186 -679 773 543 302 201 689 714 8 446 -8 -104 -90 -171 -508 356 245 786 -535 476 752 787 -840 889 -302 311 176 0 193 -192 -226 642 106 369 79 -536 576 -771 922 -226 -648 -590 -1219 75 -398 27 138 -900 593 380 -448 784 310 73 775 955 669 186 -504 14 278 -386 -1244 -2054 -259 160 -1 -791 -552 -437 97 -17 55 812 1197 177 892 203 -169 519 -230 -597 486 -359 587 1399 905 287 -129 -972 -1168 -823 -511 296 433 53 -882 680 -239 776 4 SS 20220420T112844.7Z 8145.478295 237 1 50.83 2 78.87 83.82 76.42 220.77 0.00 1 0.00 1 0 25 2.731e-01 4.222e-03 1.446e-01 1.075e-03 7.218774e-01 5.765676e-04 7.689047e-03 -6.000000e+00 1.588925e-01 229.38 -2.00 3.44 -2.00 320.90 0.00e+00 1.419117e-03 2.097662e-04 6.142424e-04 -6.000000e+00 6.755217e-03 283.28 -2.00 20.00 -2.00 320.58 0.00e+00 4.996 0.002 302.00 328.00 3 9.2132e-01 1.6849e-03 6.2449e-02 -6.0000e+00 4.0020e-01 3.1002e-02 2.3354e-03 3.7654e-02 -6.0000e+00 4.3688e-01 -4.8294e-04 2.7982e-03 2.0543e-02 -6.0000e+00 2.5406e-01 -1.2958e-02 1.4046e-03 6.6376e-03 -6.0000e+00 1.0476e-01 6.6145e-04 -1.0606e-04 2.9868e-05 7.3253e-05 -6.0000e+00 7.7627e-03 -9.3751e-03 3.6804e-05 10 0 0 10 0 0 11.98 21.69 0.30 -0.00938 -0.01017 403 72 1 5 0 126.080 24.96 20.00 21.69 14.96 31.4 970.26 101519 -22434 150747 900000 -160955 900000 -123855 900000 -75464 900000 -81176 -35180 -24188 -45582 16051 -30631 -23421 -36597 -2046 -20492 9164 -9241 -23403 -14388 -19893 3475 -29923 -9899 -21115 3993 -21307 11215 -8247 1047 -15767 -1413 -10893 -2518 3108 -4031 -385 -2436 2648 -4825 4810 -825 3040 -1387 1505 2623 161 2256 292 2395 -994 1907 -602 1866 -441 2437 -129 1463 2282 1099 916 231 701 -538 1245 393 312 -137 -135 295 -743 398 -551 27 -439 -224 -636 -486 -1275 -1053 -1432 -633 -465 197 376 57 947 641 816 739 952 291 654 369 114 43 -411 133 271 -132 -908 -832 -531 -209 -191 -164 -248 -96 -83 -36 381 524 592 76 98 -377 -188 -29 5 -186 49 302 629 823 180 121 -69 -144 -137 -117 -270 -79 164 -45 -202 26 28 61 105 106 -38 158 900000 -1046 900000 -675 900000 -340 900000 -468 -159 -129 -396 96 -350 -285 -519 -25 -287 108 -135 -392 -247 -394 64 -704 -187 -461 79 -670 308 -318 38 -659 -54 -525 -137 199 -331 -34 -217 236 -475 440 -83 304 -153 173 330 24 365 53 469 -214 419 -139 417 -98 524 -30 379 623 340 294 73 225 -186 482 176 141 -64 -61 134 -309 148 -199 10 -194 -110 -367 -318 -916 -749 -1095 -510 -390 167 316 46 702 450 604 545 801 270 701 424 140 53 -463 142 268 -134 -997 -962 -610 -258 -263 -240 -379 -154 -132 -55 586 780 896 115 156 -619 -301 -44 9 -280 71 418 853 1192 283 215 -129 -285 -273 -249 -586 -178 379 -105 -467 56 60 125 209 SS 20220420T113414.5Z 8145.482112 240 1 50.83 2 77.78 84.63 77.12 221.77 0.00 1 0.00 1 0 25 1.378e-01 4.075e-03 6.446e-02 8.142e-04 6.668474e-01 4.252339e-04 7.210584e-03 -6.000000e+00 7.913806e-02 229.38 -2.00 3.44 -2.00 320.56 0.00e+00 1.061095e-03 1.427055e-04 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