File name: Pandora31s1_CharlesCityVA_20220520_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T112803.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220520_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220520T113651.1Z 8175.483925 240 1 51.07 2 71.95 78.20 70.45 211.43 0.00 1 0.00 1 0 17 8.970e-02 5.828e-03 3.029e-02 1.607e-03 4.542046e-01 8.235710e-04 5.093170e-03 -6.000000e+00 5.201335e-02 231.53 -2.00 3.44 -2.00 319.43 0.00e+00 4.849586e-04 1.964897e-04 2.040258e-04 -6.000000e+00 2.063586e-03 286.28 -2.00 20.00 -2.00 319.10 0.00e+00 3.183 0.000 302.00 328.00 3 3.7827e+00 2.2737e-03 3.9620e-02 -6.0000e+00 1.3136e-01 -3.6929e-02 2.6153e-03 2.3238e-02 -6.0000e+00 1.4287e-01 1.1830e-02 2.2080e-03 1.1686e-02 -6.0000e+00 8.3740e-02 -1.1999e-02 1.1872e-03 3.4278e-03 -6.0000e+00 3.4532e-02 2.9485e-04 2.5765e-05 4.6874e-05 3.6380e-05 -6.0000e+00 2.4624e-03 -1.9463e-02 1.1472e-04 10 0 0 10 0 0 99.92 24.42 0.31 -0.01946 -0.01927 104 19 1 5 0 490.920 27.26 20.00 24.42 32.19 32.6 1053.49 30176 -7976 48584 -569 14609 31179 9911 42605 38162 22084 -32307 2030 -18592 -8429 5627 4739 -18393 2927 4412 -6305 -9027 4170 8018 -3295 1565 6399 -10041 -4647 -4539 3649 262 7752 -3844 725 -4343 1804 -7585 13 6290 -222 -1611 131 1042 -2422 736 -923 -1125 -3038 2393 1575 -43 1916 386 -1365 -234 463 -1303 1224 131 1622 -548 962 2197 1350 -218 802 -706 -50 1186 632 522 -447 -142 736 -466 -339 -299 -1057 517 -695 -18 -905 -1095 -890 -850 -119 -97 232 676 525 704 1037 443 520 684 175 480 114 -104 -122 -652 -52 383 -603 -917 -1556 -497 -221 -340 -95 -308 -102 -80 69 110 547 703 157 217 -229 -119 149 77 -469 483 159 794 851 746 257 14 -15 -368 48 -110 -234 245 13 -348 65 -222 -31 -102 379 -159 586 -10 212 396 170 615 642 455 -1140 58 -772 -382 264 252 -1308 184 290 -479 -717 297 584 -288 140 571 -1040 -438 -419 331 28 860 -525 97 -581 233 -1198 2 1242 -54 -428 36 294 -715 213 -274 -336 -931 712 495 -15 704 153 -585 -103 209 -609 557 59 724 -259 485 1197 791 -130 454 -394 -28 720 429 378 -336 -105 521 -312 -208 -174 -617 323 -492 -14 -774 -992 -839 -845 -123 -104 254 734 553 702 976 402 476 671 188 564 145 -138 -160 -820 -61 432 -700 -1127 -1993 -655 -303 -490 -145 -492 -165 -129 106 162 782 1009 233 337 -368 -192 237 120 -713 708 228 1105 1209 1128 413 24 -27 -656 88 -211 -463 490 27 -708 130 -431 -58 -189 SS 20220520T120258.8Z 8175.502069 252 1 11.10 2 66.83 81.82 73.22 216.69 0.00 1 0.00 1 0 17 3.631e-02 7.090e-03 1.773e-02 3.031e-03 3.654388e-01 1.544558e-03 4.175646e-03 -6.000000e+00 2.105576e-02 231.53 -2.00 3.44 -2.00 318.15 0.00e+00 4.016541e-04 2.531228e-04 1.055518e-04 -6.000000e+00 8.354636e-04 286.29 -2.00 20.00 -2.00 317.81 0.00e+00 2.522 0.000 302.00 328.00 3 4.3206e+00 4.1525e-03 3.1507e-02 -6.0000e+00 5.3177e-02 -1.1106e-02 4.6512e-03 1.8530e-02 -6.0000e+00 5.7838e-02 2.9687e-03 3.1092e-03 9.1260e-03 -6.0000e+00 3.3900e-02 -4.6024e-03 1.6224e-03 2.5852e-03 -6.0000e+00 1.3979e-02 3.5924e-04 -3.2429e-05 8.7647e-05 2.7534e-05 -6.0000e+00 9.9696e-04 -1.9833e-02 7.8148e-05 12 9 1 12 1 1 98.28 24.47 0.24 -0.01983 -0.02008 9 8 1 5 0 1089.150 27.26 20.00 24.47 33.70 32.5 1060.23 541 1758 4798 7726 -3946 14647 8602 11313 12280 17150 -11890 -8570 143 -5773 9843 -3931 -6834 -1403 3789 -2953 -2233 1612 1965 4973 -3642 6206 -9388 1710 -3306 6641 -1778 5903 -3199 -119 -2392 -1667 -3346 -1971 4279 -1754 1006 -1587 -345 -2200 147 -1806 -871 -3256 1062 2646 -207 1480 155 492 213 958 -466 672 658 1678 534 1969 2357 977 342 87 -484 176 786 14 654 -375 -685 667 -153 413 -870 -596 275 -290 -207 -679 -1992 -981 -1640 -307 485 562 277 365 749 165 138 10 249 -15 276 -70 -83 -268 -657 340 100 263 -292 -884 -954 -589 -552 59 -194 -5 165 97 422 473 904 255 400 -77 -395 357 -239 -154 201 362 295 1271 198 265 -30 147 -334 140 -144 -182 342 107 -538 -402 -114 -21 11 28 99 267 389 -204 644 438 635 754 1047 -960 -730 13 -650 1106 -549 -1036 -214 578 -497 -379 265 337 887 -738 1195 -2050 322 -629 1197 -377 1286 -816 -30 -583 -410 -923 -622 1502 -727 436 -730 -161 -1051 69 -867 -412 -1565 495 1255 -106 799 89 294 131 599 -298 425 410 1039 344 1336 1705 748 262 64 -343 125 594 11 571 -337 -612 572 -125 312 -628 -424 206 -240 -186 -655 -2023 -1024 -1800 -349 566 666 328 421 820 172 138 10 261 -16 335 -91 -111 -355 -837 408 117 314 -368 -1151 -1281 -816 -794 89 -301 -8 255 143 598 650 1244 362 592 -118 -610 543 -359 -226 286 500 399 1729 284 399 -46 235 -543 233 -249 -324 615 196 -986 -724 -201 -36 19 SS 20220520T120833.5Z 8175.505943 256 1 50.80 2 65.73 82.60 73.86 217.77 0.00 1 0.00 1 0 17 8.858e-03 4.729e-03 2.034e-03 4.171e-04 3.509366e-01 2.123714e-04 4.059109e-03 -6.000000e+00 5.135893e-03 231.53 -2.00 3.44 -2.00 317.98 0.00e+00 1.992542e-04 3.321268e-05 9.416508e-05 -6.000000e+00 2.038091e-04 286.29 -2.00 20.00 -2.00 317.65 0.00e+00 2.416 0.000 302.00 328.00 3 2.1708e+00 5.6949e-04 3.0259e-02 -6.0000e+00 1.2971e-02 -3.2427e-02 6.3684e-04 1.7886e-02 -6.0000e+00 1.4108e-02 -1.8690e-04 4.1509e-04 8.7972e-03 -6.0000e+00 8.2691e-03 -3.7036e-03 2.1427e-04 2.4778e-03 -6.0000e+00 3.4094e-03 3.5393e-03 -2.3315e-04 1.2092e-05 2.7259e-05 -6.0000e+00 2.4321e-04 -1.9500e-02 5.9722e-05 10 0 0 10 0 0 98.00 24.47 0.22 -0.01950 -0.02125 600 108 1 5 0 84.650 27.26 20.00 24.47 33.78 32.6 1061.56 -1370 -1945 -2410 -3743 -1729 -4118 -840 347 1029 -829 -652 -750 -584 671 1729 462 -1304 224 379 805 -113 751 25 470 -490 356 -1457 -709 -535 1147 1175 1202 608 -1015 -1573 -1687 -1524 -774 -159 -901 -904 -790 -1073 -652 -566 -607 -910 -761 -518 452 494 772 708 605 687 650 493 440 597 721 1009 1262 1488 912 419 265 11 457 649 594 284 181 -20 235 -157 79 -229 -60 -212 -601 -669 -1319 -1401 -1280 -750 -487 -87 -12 163 277 474 482 548 776 658 535 474 118 -226 -146 -499 -474 -87 -272 -761 -837 -661 -560 -45 -57 18 -83 -20 18 221 513 428 387 71 -173 -391 -27 -82 200 310 510 759 1018 629 418 135 58 0 57 -77 -136 82 -155 -317 -99 -276 -220 -178 -83 -129 -162 -256 -106 -259 -56 24 79 -67 -53 -67 -60 81 239 71 -217 39 64 140 -20 133 5 94 -105 78 -323 -147 -106 230 259 293 164 -280 -411 -448 -454 -253 -63 -386 -421 -385 -541 -330 -287 -309 -459 -380 -258 231 255 430 421 382 422 411 318 282 374 451 658 893 1087 715 327 193 8 336 493 485 252 167 -18 204 -133 60 -170 -44 -158 -513 -613 -1279 -1453 -1331 -834 -551 -103 -14 197 320 530 494 550 774 676 588 559 155 -301 -190 -637 -580 -101 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