File name: Pandora31s1_CharlesCityVA_20220520_L2Fit_fwvt1c2d20200727p1-8.txt File generation date: 20251126T112710.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220520_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1829 Nominal wavelengths inside fitting window [nm]: 492.0595 492.1798 492.3001 492.4204 492.5406 492.6609 492.7811 492.9013 493.0215 493.1417 493.2618 493.3820 493.5021 493.6222 493.7423 493.8624 493.9824 494.1025 494.2225 494.3425 494.4625 494.5824 494.7024 494.8223 494.9423 495.0622 495.1821 495.3019 495.4218 495.5416 495.6614 495.7812 495.9010 496.0208 496.1405 496.2603 496.3800 496.4997 496.6194 496.7391 496.8587 496.9783 497.0980 497.2176 497.3371 497.4567 497.5762 497.6958 497.8153 497.9348 498.0543 498.1737 498.2932 498.4126 498.5320 498.6514 498.7708 498.8902 499.0095 499.1288 499.2481 499.3674 499.4867 499.6060 499.7252 499.8444 499.9637 500.0828 500.2020 500.3212 500.4403 500.5594 500.6786 500.7976 500.9167 501.0358 501.1548 501.2738 501.3928 501.5118 501.6308 501.7497 501.8687 501.9876 502.1065 502.2254 502.3443 502.4631 502.5819 502.7008 502.8195 502.9383 503.0571 503.1758 503.2946 503.4133 503.5320 503.6507 503.7693 503.8880 504.0066 504.1252 504.2438 504.3624 504.4809 504.5995 504.7180 504.8365 504.9550 505.0735 505.1919 505.3104 505.4288 505.5472 505.6656 505.7840 505.9023 506.0206 506.1390 506.2573 506.3756 506.4938 506.6121 506.7303 506.8485 506.9667 507.0849 507.2031 507.3212 507.4393 507.5574 507.6755 507.7936 507.9117 508.0297 508.1478 508.2658 508.3838 508.5017 508.6197 508.7376 508.8555 508.9734 509.0913 509.2092 509.3271 509.4449 509.5627 509.6805 509.7983 509.9161 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220520T104715.7Z 8175.449487 214 1 50.56 2 81.46 71.29 66.35 200.64 0.00 1 0.00 1 0 22 2.444e-03 2.431e-03 3.556e-04 3.553e-04 1.251526e+04 2.567084e+01 8.283018e+02 -6.000000e+00 1.421373e+02 286.28 -2.00 20.00 -2.00 505.33 0.00e+00 1.305648e-03 1.004201e-05 9.193033e-05 -6.000000e+00 6.995123e-05 286.28 -2.00 20.00 -2.00 500.67 0.00e+00 5.143357e-01 7.090343e-03 8.009685e-02 -6.000000e+00 4.933763e-02 231.52 -2.00 3.44 -2.00 502.23 0.00e+00 6.338 0.004 489.00 513.00 1 5.6387e+00 5.4419e-04 1.1577e-02 -6.0000e+00 3.7933e-03 -4.0314e-02 1.3669e-04 2.0187e-03 -6.0000e+00 9.7492e-04 2.6084e-03 3.1211e-04 3.7035e-05 8.8536e-05 -6.0000e+00 2.7989e-04 -1.7915e-02 1.2230e-04 10 0 0 10 0 0 86.65 24.38 1.43 -0.01791 -0.01575 63 11 1 4 0 802.360 27.26 20.00 24.38 30.62 32.4 1043.80 129 19 205 283 149 370 526 401 289 226 184 154 -40 -98 -26 0 -46 65 164 -57 23 229 168 275 293 108 -2 127 -139 -287 -23 33 -271 76 44 -360 -219 -8 -53 -135 -8 -27 -31 4 114 100 -2 -62 9 -213 -406 -293 -399 -406 -208 -171 -201 -205 -73 17 209 322 140 109 213 38 1 -33 -41 -280 -264 -181 -244 -287 -194 -240 -365 -284 -150 -227 -233 -176 -319 -255 -202 -167 -393 -242 -85 117 48 143 229 174 42 174 152 -1 -104 -238 -512 -514 -598 -506 -325 -584 -412 -245 -72 78 117 17 -95 138 361 450 517 717 421 219 338 276 246 355 410 156 99 129 -107 156 180 -49 -72 276 87 28 240 196 -53 243 264 165 131 157 85 7 -13 -164 -308 -249 -226 122 18 197 274 145 370 534 404 291 226 185 153 -40 -96 -25 0 -45 64 165 -59 24 232 171 280 300 111 -2 129 -141 -285 -23 33 -269 76 45 -367 -223 -8 -55 -138 -8 -28 -31 4 117 104 -2 -64 9 -215 -400 -287 -388 -396 -207 -171 -202 -208 -75 17 214 330 144 111 219 39 1 -32 -40 -277 -260 -178 -242 -287 -192 -237 -365 -279 -146 -218 -224 -170 -310 -251 -201 -165 -390 -240 -84 115 48 143 231 175 42 169 146 -1 -96 -222 -477 -483 -568 -491 -321 -583 -415 -245 -72 78 117 17 -95 139 366 458 530 728 431 224 347 279 245 351 406 155 99 129 -107 156 180 -49 -72 272 86 28 237 198 -54 249 269 170 136 164 87 8 -14 -168 -310 -253 -229 SQ 20220520T105512.8Z 8175.455009 216 1 9.78 2 79.95 72.41 66.90 202.44 0.00 1 0.00 1 0 22 2.261e-03 2.253e-03 3.109e-04 3.106e-04 1.105909e+04 2.210910e+01 7.370019e+02 -6.000000e+00 1.314761e+02 286.28 -2.00 20.00 -2.00 505.33 0.00e+00 1.097965e-03 8.778259e-06 7.947435e-05 -6.000000e+00 6.470567e-05 286.28 -2.00 20.00 -2.00 500.64 0.00e+00 4.195160e-01 6.205097e-03 7.147968e-02 -6.000000e+00 4.563932e-02 231.53 -2.00 3.44 -2.00 502.21 0.00e+00 5.485 0.003 489.00 513.00 1 3.8406e+00 4.7645e-04 1.0122e-02 -6.0000e+00 3.5089e-03 -3.7238e-02 1.1990e-04 1.7929e-03 -6.0000e+00 9.0189e-04 1.8015e-02 3.6161e-04 3.2741e-05 8.0637e-05 -6.0000e+00 2.5889e-04 -1.7979e-02 1.1902e-04 12 1 1 12 1 1 77.51 24.38 1.35 -0.01798 -0.01547 68 65 1 4 0 139.120 27.15 20.00 24.38 30.56 32.3 1043.54 74 43 235 224 61 304 455 351 306 224 233 174 -67 -77 9 -40 -95 51 141 -43 0 200 126 197 332 162 16 117 -121 -358 4 18 -281 63 58 -297 -212 6 21 -89 -26 29 1 73 37 109 -15 -39 -58 -228 -371 -235 -369 -334 -244 -149 -277 -189 -78 72 167 317 190 142 90 29 -3 -79 -31 -186 -266 -138 -251 -232 -134 -212 -424 -284 -76 -159 -155 -163 -322 -310 -141 -136 -246 -172 -66 63 61 107 142 74 50 80 169 46 -22 -294 -380 -384 -567 -477 -379 -602 -429 -190 -35 83 127 36 -40 146 323 407 500 639 367 225 233 314 183 410 346 101 40 83 -38 98 181 -21 -68 218 19 47 287 226 -55 170 270 167 184 194 113 -47 -73 -262 -289 -203 -196 71 41 225 217 61 305 456 355 310 225 235 173 -66 -77 9 -40 -94 51 143 -43 0 205 130 202 342 168 17 119 -121 -356 4 18 -280 63 59 -305 -218 6 21 -90 -27 29 1 75 38 112 -16 -40 -59 -230 -367 -231 -358 -325 -241 -148 -279 -193 -78 73 169 321 194 145 91 29 -3 -79 -31 -184 -261 -135 -249 -232 -133 -210 -417 -279 -74 -155 -151 -158 -314 -305 -138 -135 -245 -171 -65 62 61 106 142 74 50 78 164 44 -20 -275 -355 -362 -542 -465 -371 -607 -428 -188 -35 83 126 36 -41 146 326 412 510 657 374 228 237 314 184 408 345 101 40 82 -38 97 182 -21 -67 215 18 46 284 225 -55 172 277 170 190 201 117 -48 -75 -266 -293 -204 -196 SQ 20220520T105917.6Z 8175.457842 219 1 50.32 2 79.18 72.98 67.20 203.35 0.00 1 0.00 1 0 15 2.137e-03 2.129e-03 5.790e-04 5.783e-04 1.040418e+04 4.108882e+01 6.973446e+02 -6.000000e+00 1.243137e+02 286.28 -2.00 20.00 -2.00 505.31 0.00e+00 9.896373e-04 1.633997e-05 7.252865e-05 -6.000000e+00 6.118231e-05 286.28 -2.00 20.00 -2.00 500.57 0.00e+00 4.147752e-01 1.159308e-02 6.640835e-02 -6.000000e+00 4.315591e-02 231.53 -2.00 3.44 -2.00 502.14 0.00e+00 5.127 0.002 489.00 513.00 1 6.7748e+00 8.9066e-04 9.4360e-03 -6.0000e+00 3.3179e-03 -1.9251e-02 2.2436e-04 1.6713e-03 -6.0000e+00 8.5287e-04 1.0109e-03 5.3421e-04 6.1190e-05 7.3080e-05 -6.0000e+00 2.4478e-04 -1.7600e-02 1.1227e-04 10 0 0 10 0 0 98.86 24.38 1.29 -0.01760 -0.01389 32 6 1 4 0 1572.350 27.26 20.00 24.38 30.53 32.5 1044.15 217 47 96 67 0 361 490 107 214 176 353 -18 -127 -102 99 35 -13 -72 148 -33 21 262 56 337 223 -37 -94 139 -178 -227 103 70 -129 142 127 -383 -228 -11 46 -56 -1 -14 -80 27 101 -50 52 -23 158 -128 -425 -142 -352 -255 -108 -201 -293 -251 -159 -91 176 348 52 52 138 3 0 -25 -7 -243 -264 14 -263 -144 -40 -316 -463 -149 -2 -92 -98 -91 -203 -45 -156 70 -393 -231 79 179 57 95 99 -54 58 117 -39 132 -48 -112 -393 -405 -434 -454 -303 -604 -325 -167 53 72 74 9 -161 107 162 201 421 646 274 126 222 232 49 518 344 175 110 -49 -47 50 147 54 -11 436 89 60 366 177 -175 330 142 -14 182 40 110 -150 -29 -237 -309 -88 -134 208 45 94 65 0 362 499 110 221 180 356 -18 -128 -102 98 35 -13 -73 153 -34 21 269 58 348 232 -38 -98 142 -183 -228 102 69 -129 146 131 -401 -239 -11 47 -57 -1 -14 -83 28 103 -52 53 -24 162 -129 -427 -139 -341 -248 -107 -199 -297 -259 -161 -92 178 353 53 53 139 4 0 -25 -7 -238 -262 14 -257 -142 -40 -314 -456 -147 -2 -89 -95 -89 -199 -43 -152 69 -392 -230 78 177 56 95 98 -54 58 114 -37 125 -45 -105 -365 -380 -409 -434 -300 -600 -324 -166 53 71 73 9 -163 107 162 202 427 657 281 128 224 230 49 513 341 175 111 -49 -46 49 146 53 -10 419 85 59 359 174 -175 333 142 -14 186 41 113 -154 -30 -238 -312 -88 -134 SQ 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