File name: Pandora31s1_CharlesCityVA_20220525_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T112808.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220525_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220525T171250.1Z 8180.717247 378 1 11.20 2 16.36 185.82 61.77 246.35 0.00 1 0.00 1 0 17 9.881e-03 7.618e-03 4.283e-03 3.302e-03 1.507043e-01 1.727441e-03 1.730243e-03 -6.000000e+00 5.729091e-03 231.79 -2.00 3.44 -2.00 314.30 0.00e+00 4.797753e-04 1.172280e-04 1.234814e-05 -6.000000e+00 2.273127e-04 286.78 -2.00 20.00 -2.00 314.05 0.00e+00 1.042 0.000 302.00 328.00 3 6.0737e+00 4.4619e-03 1.2937e-02 -6.0000e+00 1.4478e-02 5.2491e-02 4.9383e-03 7.5003e-03 -6.0000e+00 1.5749e-02 -1.5658e-04 2.8076e-03 3.6430e-03 -6.0000e+00 9.2291e-03 -1.9203e-03 1.1864e-03 1.0024e-03 -6.0000e+00 3.7992e-03 3.7350e-04 -5.5801e-05 9.3611e-05 1.3576e-05 -6.0000e+00 2.7139e-04 -1.3173e-02 2.6386e-05 12 9 1 12 33 1 999.00 23.56 0.44 -0.01317 -0.01359 2 3 1 5 0 3675.040 26.51 20.00 23.56 28.23 32.7 1032.71 -543 -267 -99 -2321 -1967 -2873 951 2549 2790 640 -3126 -475 -1108 -1032 1037 -267 -787 962 1209 1024 660 1650 530 613 -32 499 -1102 -390 -1061 2029 129 1647 879 -465 -2784 423 -2187 -312 -39 -292 -324 -511 596 -1626 -564 -821 -209 -1156 -266 234 1098 778 602 628 456 1246 -62 1125 -711 1424 135 1980 1477 754 -3 -72 -874 -545 -72 -104 451 523 768 1095 162 -890 -1162 -1171 -578 -1910 -1302 -1058 -1151 -453 -1187 -199 92 730 182 160 529 -459 -937 -687 -708 -225 475 807 1142 369 -293 -1152 -157 -819 -434 -1367 -367 301 316 406 11 848 223 -350 -304 -221 226 -346 1310 419 302 596 807 246 766 282 334 -86 289 -284 -435 389 -620 -308 -410 136 281 244 -367 300 -183 -378 -686 -231 -117 -43 -935 -728 -1061 361 1035 1197 280 -1371 -209 -526 -528 558 -150 -446 548 699 604 391 962 317 377 -20 318 -694 -232 -603 1120 74 968 538 -283 -1636 245 -1384 -216 -30 -243 -280 -449 526 -1452 -499 -722 -179 -971 -217 191 918 673 535 571 419 1148 -57 1036 -656 1301 127 1925 1498 782 -3 -69 -801 -492 -67 -105 473 559 815 1135 161 -836 -1029 -1005 -510 -1810 -1306 -1111 -1245 -502 -1375 -238 113 906 226 193 609 -502 -972 -699 -742 -248 550 979 1412 450 -346 -1309 -175 -940 -520 -1695 -464 387 416 548 15 1158 296 -446 -368 -258 264 -417 1633 544 399 781 1041 310 934 335 386 -100 344 -350 -547 492 -792 -400 -551 187 392 345 -522 421 -253 -515 -928 SS 20220525T194549.4Z 8180.823488 468 1 3.56 2 38.16 256.16 90.30 271.41 0.00 1 0.00 1 0 17 1.108e-02 7.430e-03 6.813e-03 4.847e-03 1.720035e-01 2.520534e-03 2.026466e-03 -6.000000e+00 6.428498e-03 231.80 -2.00 3.44 -2.00 314.78 0.00e+00 2.490715e-04 1.868899e-04 1.516519e-05 -6.000000e+00 2.550018e-04 286.79 -2.00 20.00 -2.00 314.50 0.00e+00 1.271 0.000 302.00 328.00 3 5.1495e+00 6.5306e-03 1.5490e-02 -6.0000e+00 1.6245e-02 1.9948e-02 7.2420e-03 8.7174e-03 -6.0000e+00 1.7670e-02 9.8035e-03 4.1187e-03 4.2418e-03 -6.0000e+00 1.0355e-02 -4.3171e-03 1.7651e-03 1.1698e-03 -6.0000e+00 4.2636e-03 7.2497e-04 1.7227e-04 1.3798e-04 1.5856e-05 -6.0000e+00 3.0436e-04 -1.4011e-02 7.9219e-05 12 9 1 12 1 1 999.00 23.63 0.19 -0.01401 -0.01272 1 5 1 5 0 1690.750 26.62 20.00 23.63 25.67 32.5 1019.10 853 271 -744 -5002 283 -1394 -1252 -4672 4387 -604 -1177 -1414 1137 1556 -843 706 -1147 2760 96 3868 -480 -816 -777 1347 554 -581 -563 -1695 -591 1057 873 846 615 283 -1444 -1089 -335 20 76 -689 -600 292 -501 -1061 -161 983 -1083 -2005 -167 1192 154 1141 670 1020 1448 151 694 367 1208 1707 664 740 1179 58 -776 -121 -744 -531 418 129 178 81 -126 243 38 -201 319 -840 151 -1175 -155 -1029 -1680 -790 -802 -630 -241 -413 -194 71 92 595 402 1255 -87 167 195 523 -806 195 -42 -336 -520 41 -453 -1307 -821 -107 21 -66 -81 -398 358 -53 -314 540 222 821 -534 557 -263 978 -77 396 934 1226 844 1301 656 472 1000 -366 -242 220 -16 -156 -243 -524 -217 -149 -307 -594 -755 303 100 -273 -1754 88 -436 -416 -1725 1613 -232 -446 -551 468 692 -408 351 -585 1397 50 2020 -258 -438 -426 751 318 -341 -325 -934 -309 543 463 466 352 161 -791 -600 -197 13 55 -541 -489 242 -422 -895 -135 812 -888 -1618 -131 930 125 949 575 894 1280 136 626 330 1071 1514 607 705 1166 59 -774 -114 -671 -473 388 128 184 86 -133 250 37 -186 278 -718 133 -1107 -154 -1079 -1822 -876 -926 -755 -296 -515 -242 86 106 650 417 1277 -92 186 229 643 -1019 242 -51 -386 -587 47 -551 -1639 -1053 -139 29 -91 -114 -558 486 -68 -390 646 267 1009 -689 740 -356 1309 -102 511 1167 1488 999 1542 805 597 1289 -479 -320 295 -23 -223 -351 -769 -318 -217 -439 -837 -1056 SS 20220525T212155.5Z 8180.890225 530 1 20.11 2 57.12 272.59 108.29 286.42 0.00 1 0.00 1 0 17 1.993e-02 8.382e-03 7.552e-03 3.264e-03 2.540780e-01 1.674944e-03 2.919788e-03 -6.000000e+00 1.154987e-02 231.80 -2.00 3.44 -2.00 316.49 0.00e+00 1.400601e-04 1.784017e-04 4.259743e-05 -6.000000e+00 4.583837e-04 286.80 -2.00 20.00 -2.00 316.16 0.00e+00 1.835 0.000 302.00 328.00 3 5.7550e+00 4.4075e-03 2.2506e-02 -6.0000e+00 2.9188e-02 5.2369e-02 4.9100e-03 1.2789e-02 -6.0000e+00 3.1756e-02 9.3310e-03 2.8645e-03 6.2323e-03 -6.0000e+00 1.8609e-02 -1.0699e-02 1.3385e-03 1.7308e-03 -6.0000e+00 7.6569e-03 1.9243e-04 -4.3543e-04 9.4080e-05 1.9988e-05 -6.0000e+00 5.4745e-04 -1.0571e-02 -4.7173e-06 12 9 1 12 9 1 84.87 23.54 0.59 -0.01057 -0.01384 4 2 1 5 0 3985.640 26.51 20.00 23.54 26.44 32.3 1022.77 2957 -3495 6787 -4866 -2959 -3382 6100 3834 11382 -200 -2558 -2534 -2731 -2760 1695 -2304 -7013 3177 -71 663 385 2623 698 -237 -468 3710 -3990 -379 -2460 1918 1319 857 -1691 36 -1623 3214 -2160 -518 3613 -1659 -611 -78 -1109 -1768 -417 773 -1415 -1362 257 2074 23 1743 910 -180 61 1232 -811 1295 732 1192 431 607 2319 666 -1060 126 -1298 388 449 829 127 502 -561 999 311 -594 -763 -1818 -339 -2143 100 -869 -371 -926 -645 -469 764 -253 1077 -332 674 84 -723 318 -424 -163 91 873 320 343 -760 -294 562 -1057 -949 -1990 -74 -59 118 -279 89 371 -32 -585 -268 431 445 -296 835 348 235 712 111 466 572 943 374 351 422 -427 412 -56 -882 -389 449 -165 456 197 -746 436 -292 -14 -829 467 -618 1087 -792 -434 -500 900 643 1938 -38 -497 -521 -629 -714 468 -698 -2274 981 -23 222 130 867 242 -87 -179 1401 -1571 -137 -863 656 479 333 -709 15 -641 1240 -952 -256 1982 -1041 -400 -53 -761 -1222 -286 522 -954 -903 167 1347 16 1241 677 -139 48 975 -656 1026 575 937 351 519 2066 618 -976 109 -1085 320 391 780 126 507 -566 970 288 -515 -624 -1466 -283 -1962 97 -898 -396 -1024 -745 -564 939 -317 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