File name: Pandora31s1_CharlesCityVA_20220703_L2Fit_fwvt1c2d20200727p1-8.txt File generation date: 20251126T114123.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20220703_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20220703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1829 Nominal wavelengths inside fitting window [nm]: 492.0595 492.1798 492.3001 492.4204 492.5406 492.6609 492.7811 492.9013 493.0215 493.1417 493.2618 493.3820 493.5021 493.6222 493.7423 493.8624 493.9824 494.1025 494.2225 494.3425 494.4625 494.5824 494.7024 494.8223 494.9423 495.0622 495.1821 495.3019 495.4218 495.5416 495.6614 495.7812 495.9010 496.0208 496.1405 496.2603 496.3800 496.4997 496.6194 496.7391 496.8587 496.9783 497.0980 497.2176 497.3371 497.4567 497.5762 497.6958 497.8153 497.9348 498.0543 498.1737 498.2932 498.4126 498.5320 498.6514 498.7708 498.8902 499.0095 499.1288 499.2481 499.3674 499.4867 499.6060 499.7252 499.8444 499.9637 500.0828 500.2020 500.3212 500.4403 500.5594 500.6786 500.7976 500.9167 501.0358 501.1548 501.2738 501.3928 501.5118 501.6308 501.7497 501.8687 501.9876 502.1065 502.2254 502.3443 502.4631 502.5819 502.7008 502.8195 502.9383 503.0571 503.1758 503.2946 503.4133 503.5320 503.6507 503.7693 503.8880 504.0066 504.1252 504.2438 504.3624 504.4809 504.5995 504.7180 504.8365 504.9550 505.0735 505.1919 505.3104 505.4288 505.5472 505.6656 505.7840 505.9023 506.0206 506.1390 506.2573 506.3756 506.4938 506.6121 506.7303 506.8485 506.9667 507.0849 507.2031 507.3212 507.4393 507.5574 507.6755 507.7936 507.9117 508.0297 508.1478 508.2658 508.3838 508.5017 508.6197 508.7376 508.8555 508.9734 509.0913 509.2092 509.3271 509.4449 509.5627 509.6805 509.7983 509.9161 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220703T103705.0Z 8219.442419 73 1 50.45 2 83.01 66.40 119.76 33.75 0.00 1 0.00 1 0 22 2.254e-03 2.232e-03 2.687e-04 2.683e-04 1.983272e+04 2.098301e+01 1.252743e+03 -6.000000e+00 1.331064e+02 290.36 -2.00 20.00 -2.00 505.33 0.00e+00 1.153961e-03 7.667700e-06 1.007289e-04 -6.000000e+00 6.515282e-05 290.36 -2.00 20.00 -2.00 500.58 0.00e+00 6.661020e-01 5.375194e-03 1.135687e-01 -6.000000e+00 4.541654e-02 232.69 -2.00 3.44 -2.00 502.15 0.00e+00 7.527 0.007 489.00 513.00 1 4.8794e+00 4.1305e-04 1.4712e-02 -6.0000e+00 3.4976e-03 -2.6847e-02 1.0319e-04 2.8662e-03 -6.0000e+00 8.9714e-04 4.6040e-03 1.4842e-04 2.6127e-05 1.0820e-04 -6.0000e+00 2.5823e-04 -5.7782e-04 7.5462e-05 10 0 0 10 0 0 99.10 23.66 1.30 -0.00058 0.00045 133 24 1 4 0 379.270 26.51 20.00 23.66 31.49 33.0 1037.08 83 145 205 239 151 459 449 353 331 191 267 132 -52 -71 55 7 -31 42 163 -83 15 123 97 204 293 112 14 37 -205 -293 14 -11 -186 83 28 -330 -264 -20 -27 -123 -29 -14 -38 24 43 -6 0 -74 -81 -187 -351 -275 -379 -269 -180 -157 -280 -250 -82 59 124 280 184 105 128 -11 4 -78 -93 -292 -268 -63 -180 -176 -110 -202 -430 -180 -81 -126 -195 -123 -234 -242 -70 -139 -259 -169 -48 97 124 86 208 80 57 162 116 74 -52 -238 -515 -491 -560 -422 -445 -537 -370 -201 -56 116 195 -82 -171 126 310 410 540 634 368 55 130 198 153 329 465 137 118 134 -178 16 125 -108 -126 302 47 52 367 185 22 237 285 109 128 109 148 72 76 -152 -256 -196 -165 79 137 200 236 150 465 454 360 338 193 267 133 -52 -70 54 7 -31 42 167 -84 15 126 100 212 304 117 15 38 -206 -294 13 -11 -188 84 29 -342 -273 -21 -28 -126 -30 -14 -39 25 45 -6 0 -76 -82 -190 -348 -272 -371 -264 -181 -158 -284 -256 -85 61 128 289 191 107 132 -11 4 -79 -93 -290 -264 -62 -178 -177 -111 -204 -430 -176 -80 -123 -190 -120 -226 -236 -69 -139 -254 -166 -48 96 123 84 204 79 56 157 110 67 -48 -214 -463 -448 -520 -402 -435 -533 -372 -201 -56 115 192 -82 -171 126 311 412 548 640 375 56 131 199 151 322 455 135 117 133 -178 16 124 -106 -122 294 46 50 361 182 22 238 290 113 131 112 152 74 78 -155 -259 -196 -165 SQ 20220703T104657.9Z 8219.449282 76 1 4.06 2 81.20 67.80 118.70 36.07 0.00 1 0.00 1 0 22 2.027e-03 2.012e-03 4.021e-04 4.015e-04 1.697933e+04 3.071545e+01 1.083912e+03 -6.000000e+00 1.197210e+02 290.36 -2.00 20.00 -2.00 505.32 0.00e+00 9.839573e-04 1.147620e-05 8.702471e-05 -6.000000e+00 5.860248e-05 290.36 -2.00 20.00 -2.00 500.55 0.00e+00 5.262603e-01 8.057575e-03 9.883355e-02 -6.000000e+00 4.085354e-02 232.69 -2.00 3.44 -2.00 502.12 0.00e+00 6.174 0.004 489.00 513.00 1 3.3135e+00 6.1965e-04 1.2390e-02 -6.0000e+00 3.1461e-03 -2.0296e-02 1.5503e-04 2.4777e-03 -6.0000e+00 8.0710e-04 2.7207e-02 4.0188e-04 4.0092e-05 9.3094e-05 -6.0000e+00 2.3225e-04 -5.3918e-03 9.5275e-05 12 1 1 12 1 1 95.82 23.66 1.25 -0.00539 -0.00260 39 90 1 4 0 96.980 26.51 20.00 23.66 31.74 32.9 1038.00 181 170 241 111 105 296 376 250 239 207 157 143 -163 -106 26 39 -101 35 131 -62 -71 63 114 227 256 105 -43 115 -154 -171 70 91 -184 41 43 -381 -234 7 30 -46 -36 39 26 36 54 87 8 -62 -78 -138 -284 -223 -290 -306 -145 -139 -290 -193 -153 105 180 175 216 81 88 -7 -53 -104 -75 -224 -162 -111 -193 -189 -100 -168 -332 -160 -97 -44 -152 -116 -289 -143 -85 -130 -284 -200 -32 85 109 117 222 -6 -67 61 192 22 -25 -240 -388 -339 -480 -323 -457 -519 -359 -89 -109 99 177 -60 -124 150 302 336 496 636 291 156 87 228 159 429 393 55 26 133 -178 32 132 -130 -72 291 38 39 357 136 -41 208 245 119 135 109 32 67 -20 -262 -147 -150 -168 173 165 236 110 105 299 387 256 244 213 160 144 -165 -105 26 39 -101 36 133 -64 -73 65 118 235 266 109 -45 117 -157 -173 70 91 -187 42 45 -394 -242 8 31 -47 -37 40 26 38 56 91 9 -64 -80 -139 -283 -221 -285 -301 -144 -141 -297 -196 -157 107 184 180 222 84 91 -7 -54 -105 -75 -223 -160 -110 -192 -186 -99 -167 -327 -157 -94 -43 -148 -113 -281 -140 -84 -128 -282 -198 -31 83 107 116 220 -6 -65 58 181 20 -23 -221 -357 -312 -448 -310 -445 -513 -358 -88 -108 98 175 -60 -124 150 302 337 502 640 296 158 87 227 159 422 388 55 26 131 -176 31 128 -128 -70 280 36 38 351 135 -41 210 246 122 137 111 33 68 -20 -265 -146 -150 -168 SQ 20220703T105708.3Z 8219.456346 81 1 50.33 2 79.32 69.21 117.55 38.39 0.00 1 0.00 1 0 22 2.064e-03 2.052e-03 4.061e-04 4.055e-04 1.417465e+04 3.034968e+01 9.161301e+02 -6.000000e+00 1.219200e+02 290.36 -2.00 20.00 -2.00 505.31 0.00e+00 8.372015e-04 1.159299e-05 7.467773e-05 -6.000000e+00 5.968242e-05 290.36 -2.00 20.00 -2.00 500.54 0.00e+00 4.076853e-01 8.145538e-03 8.375678e-02 -6.000000e+00 4.161274e-02 232.69 -2.00 3.44 -2.00 502.12 0.00e+00 5.188 0.002 489.00 513.00 1 6.0580e+00 6.2686e-04 1.0453e-02 -6.0000e+00 3.2045e-03 -1.7942e-02 1.5706e-04 2.0911e-03 -6.0000e+00 8.2230e-04 2.0453e-03 4.0894e-04 4.1466e-05 8.2178e-05 -6.0000e+00 2.3652e-04 -1.2210e-03 5.2973e-05 10 0 0 10 0 0 99.91 23.66 1.32 -0.00122 0.00162 65 12 1 4 0 774.090 26.51 20.00 23.66 31.98 33.0 1039.42 71 83 318 203 63 295 483 219 239 159 298 158 23 -24 70 38 -108 93 87 -118 -43 117 34 229 262 114 -43 38 -253 -193 99 1 -215 157 35 -373 -213 67 6 -101 21 15 -45 -26 64 -26 -33 -57 45 -210 -321 -237 -235 -266 -130 -92 -228 -276 -221 6 53 347 138 38 98 1 16 -102 -65 -250 -220 -68 -204 -161 -108 -234 -342 -131 1 -164 -153 -75 -225 -214 -22 -112 -287 -170 -40 123 75 58 173 15 -56 86 75 20 -1 -138 -285 -431 -457 -464 -387 -622 -388 -126 -51 80 156 11 -85 77 325 284 498 617 324 91 284 215 151 282 403 76 49 39 -68 105 78 -88 -123 379 31 39 349 215 -46 228 229 120 123 141 23 -3 3 -80 -233 -180 -153 68 81 309 203 63 297 494 227 247 163 301 161 24 -24 70 38 -110 94 90 -121 -45 121 36 238 273 119 -45 39 -261 -194 98 1 -217 159 36 -385 -224 70 6 -103 22 15 -46 -27 66 -27 -34 -59 46 -212 -322 -232 -233 -259 -129 -92 -233 -286 -225 6 54 352 141 38 100 1 16 -102 -65 -250 -219 -68 -204 -159 -108 -232 -337 -130 1 -159 -148 -73 -220 -211 -22 -111 -285 -169 -40 122 74 58 174 15 -56 84 71 19 0 -127 -263 -394 -430 -446 -379 -614 -385 -124 -50 78 154 11 -85 78 322 283 500 624 330 93 284 216 149 277 396 75 48 39 -67 104 77 -86 -119 369 30 37 340 210 -45 230 229 122 125 145 24 -3 3 -80 -234 -179 -152 SQ 20220703T110150.3Z 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