File name: Pandora31s1_CharlesCityVA_20230211_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T122929.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230211_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230211T131442.7Z 8442.551884 290 1 34.48 2 77.61 118.62 72.11 241.20 0.00 1 0.00 1 0 17 7.229e-01 1.164e-02 2.709e-01 8.456e-03 5.235663e-01 4.344923e-03 5.770210e-03 -6.000000e+00 4.077153e-01 224.98 -2.00 3.44 -2.00 320.62 0.00e+00 1.000266e-03 1.423872e-03 3.519787e-04 -6.000000e+00 1.661177e-02 278.30 -2.00 20.00 -2.00 320.27 0.00e+00 4.529 0.001 302.00 328.00 3 4.2219e+00 1.2446e-02 5.2094e-02 -6.0000e+00 1.0140e+00 1.0160e-01 1.5438e-02 2.6451e-02 -6.0000e+00 1.1096e+00 -6.8003e-02 1.5929e-02 1.3873e-02 -6.0000e+00 6.5371e-01 2.1105e-02 8.3062e-03 4.3471e-03 -6.0000e+00 2.7223e-01 4.7877e-05 -3.5851e-04 2.5549e-04 5.2383e-05 -6.0000e+00 1.9832e-02 6.4174e-03 6.8660e-05 12 9 9 12 25 1 81.50 24.17 0.31 0.00642 0.00372 10 3 1 5 0 3116.450 26.94 20.00 24.17 16.37 33.8 962.41 -80076 -37341 -140685 32807 -55636 -7758 37455 342712 61991 -2660 -76799 34469 -48470 -8358 24038 -5698 735831 249 -29808 14919 24925 -21826 -22048 -2231 483 -18264 -15284 8155 -10464 -17068 -7021 -4153 -5830 -4027 9484 9686 -268 5930 11036 898 -1293 1539 5063 -3850 3715 -681 10599 -1074 4079 5854 -4567 1560 3630 3178 3404 527 -7361 1592 -1931 1821 3292 -2628 5521 1474 99 -21 -2342 -620 4933 2754 471 -1232 3404 82 -916 1078 -229 -88 -3050 -25 -2457 581 -1657 181 -1012 -2007 -1468 390 -290 -349 1158 2138 1608 142 1956 -209 998 -120 -1191 1652 -1298 -1123 1366 503 -1321 -1440 -1611 -579 164 512 202 741 -45 -1211 806 583 864 -219 -1394 -482 74 192 845 -288 219 1572 -76 450 606 390 296 -209 -478 59 22 366 141 -323 -258 -132 218 59 -498 -1246 -426 -4324 271 -669 -64 309 2826 511 -30 -1820 331 -1254 -181 456 -162 6068 8 -1323 452 694 -960 -1042 -95 21 -1002 -806 330 -505 -963 -417 -274 -434 -296 587 624 -22 542 1161 120 -192 235 775 -650 591 -114 1617 -187 700 1060 -1009 355 876 824 920 151 -2318 454 -557 508 957 -894 1941 581 40 -8 -907 -246 2078 1338 251 -683 1761 41 -425 445 -91 -36 -1447 -13 -1530 390 -1213 138 -831 -1762 -1337 355 -263 -302 921 1583 1157 108 1623 -200 1066 -144 -1502 1984 -1491 -1180 1341 518 -1478 -1689 -1992 -753 229 776 328 1225 -73 -1905 1179 828 1244 -334 -2264 -799 121 306 1305 -434 317 2165 -104 644 951 668 541 -400 -949 123 48 829 326 -761 -602 -297 469 122 -1025 SS 20230211T132017.2Z 8442.555755 293 1 50.89 2 76.64 119.58 73.08 242.17 0.00 1 0.00 1 0 25 1.111e-01 5.637e-03 4.986e-02 1.661e-03 4.955470e-01 8.356845e-04 5.535562e-03 -6.000000e+00 6.262868e-02 224.98 -2.00 3.44 -2.00 319.79 0.00e+00 6.118496e-04 2.281260e-04 2.603132e-04 -6.000000e+00 2.551936e-03 278.30 -2.00 20.00 -2.00 319.47 0.00e+00 4.222 0.001 302.00 328.00 3 2.8889e+00 2.3131e-03 4.8670e-02 -6.0000e+00 1.5576e-01 -1.8905e-04 2.7358e-03 2.4755e-02 -6.0000e+00 1.7046e-01 2.2349e-02 2.5551e-03 1.2721e-02 -6.0000e+00 1.0042e-01 -1.9747e-02 1.3698e-03 3.8666e-03 -6.0000e+00 4.1813e-02 2.5984e-04 -1.2863e-04 4.8069e-05 4.2217e-05 -6.0000e+00 3.0468e-03 7.1520e-03 6.6577e-05 10 0 0 10 0 0 99.71 24.16 0.29 0.00715 0.00619 95 17 1 5 0 535.550 26.94 19.99 24.16 16.42 33.7 962.83 33345 10660 23002 8417 3333 25311 13692 36178 31189 81415 -32304 -9943 -26160 -32425 26819 -451 -19312 -2925 11485 -3573 -7888 6911 318 -3650 -1178 8741 -19592 576 -10232 8600 -814 10669 -5416 -540 -3974 498 -6039 -179 3321 -1543 -809 -966 1566 -3049 3176 -2607 -1065 -3360 1475 2912 -1163 2864 407 846 -407 1604 -802 1388 206 2100 -1207 1673 1937 1091 -318 730 -196 428 365 236 213 317 -153 1002 -135 210 -575 -304 36 -771 492 -829 -1390 -1094 -1304 -99 -76 -386 536 -706 624 904 1045 634 611 294 398 -3 48 149 -542 221 255 -304 -867 -946 -572 35 -164 -237 -164 -91 -185 -130 281 281 801 -5 425 -336 -43 58 48 -159 349 86 686 830 493 258 -182 -126 -440 -93 14 -143 302 -47 -471 231 -102 174 -265 252 110 215 84 33 215 146 358 361 615 -754 -218 -816 -1304 737 -18 -997 -140 512 -192 -446 349 18 -238 -80 565 -1631 38 -751 579 -69 921 -598 -57 -419 53 -774 -26 560 -312 -176 -221 363 -746 746 -653 -266 -872 378 785 -356 916 143 314 -159 636 -329 554 82 824 -512 756 960 580 -171 373 -100 225 211 151 145 220 -105 647 -82 117 -308 -166 22 -528 371 -686 -1216 -998 -1258 -99 -78 -405 555 -711 589 809 908 570 596 316 469 -4 63 192 -665 253 282 -349 -1053 -1190 -747 47 -236 -363 -264 -148 -296 -201 416 406 1168 -8 670 -546 -70 92 75 -240 513 123 962 1206 769 429 -318 -225 -811 -177 27 -291 624 -98 -982 469 -202 333 -505 SS 20230211T133027.0Z 8442.562812 296 1 50.98 2 74.90 121.38 74.86 243.91 0.00 1 0.00 1 0 25 4.407e-02 4.686e-03 2.042e-02 1.281e-03 4.461986e-01 6.408766e-04 5.038592e-03 -6.000000e+00 2.485488e-02 224.99 -2.00 3.44 -2.00 319.38 0.00e+00 3.142489e-04 1.544710e-04 1.993866e-04 -6.000000e+00 1.012579e-03 278.30 -2.00 20.00 -2.00 319.05 0.00e+00 3.765 0.001 302.00 328.00 3 2.8679e+00 1.7523e-03 4.3484e-02 -6.0000e+00 6.1815e-02 -1.2440e-03 2.0269e-03 2.2186e-02 -6.0000e+00 6.7643e-02 2.2248e-02 1.7158e-03 1.1272e-02 -6.0000e+00 3.9849e-02 -1.9130e-02 9.2608e-04 3.3713e-03 -6.0000e+00 1.6596e-02 4.3356e-04 4.5186e-05 3.7395e-05 3.6619e-05 -6.0000e+00 1.2088e-03 6.5642e-03 1.0797e-04 10 0 0 10 0 0 99.99 24.14 0.33 0.00656 0.00690 164 29 1 5 0 310.800 26.94 20.00 24.14 16.76 33.7 963.86 6818 -1824 29498 6794 -16580 5577 14499 8912 15681 12060 -12231 -1350 -5958 -10093 6936 -206 -10776 -122 3513 -2167 -3818 2274 1661 616 -118 5540 -7577 -1169 -2853 925 -644 4702 -2760 -1523 -2276 107 -3323 -1273 567 -1238 -1102 -853 -746 -1973 587 -746 -1381 -2102 559 1192 -263 1021 588 -4 69 620 194 837 352 1041 -2 1113 2053 1134 260 678 -402 1063 345 320 3 114 32 346 -133 531 -56 46 68 -481 -116 -1191 -1412 -1253 -1022 -209 -209 -66 279 -278 583 999 685 881 624 529 432 98 -159 68 -523 -48 476 -275 -711 -1009 -504 -314 -96 -172 -301 -107 -174 8 240 689 562 197 180 -362 -131 38 -111 -219 311 135 872 756 457 241 143 -19 -179 -79 -176 -121 197 -128 -410 -2 -86 196 -154 114 -36 433 115 -333 93 251 187 343 286 -386 -44 -227 -487 334 -12 -750 -8 242 -165 -299 170 134 55 -11 522 -802 -110 -270 91 -74 577 -374 -219 -315 15 -517 -235 125 -321 -311 -236 -213 -577 169 -219 -410 -635 169 379 -93 390 244 -2 32 295 88 399 165 487 -1 569 1156 691 158 388 -227 611 224 222 2 87 24 244 -86 326 -32 27 45 -348 -95 -1037 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