File name: Pandora31s1_CharlesCityVA_20230326_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T124642.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230326_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230326T114507.5Z 8485.489670 59 1 50.56 2 82.59 92.88 109.27 37.55 0.00 1 0.00 1 0 25 5.758e-01 2.505e-02 2.481e-01 5.416e-03 8.200607e-01 3.357350e-03 8.235719e-03 -6.000000e+00 3.556765e-01 227.44 -2.00 3.44 -2.00 321.91 0.00e+00 2.790619e-03 1.494845e-03 1.103201e-03 -6.000000e+00 2.243223e-02 280.87 -2.00 20.00 -2.00 321.55 0.00e+00 7.179 0.006 302.00 328.00 3 1.7335e+00 1.0785e-02 8.3507e-02 -6.0000e+00 8.9911e-01 2.9799e-01 1.8361e-02 4.4254e-02 -6.0000e+00 9.9558e-01 -4.5227e-01 2.2998e-02 2.5935e-02 -6.0000e+00 5.6738e-01 1.8043e-01 1.0629e-02 9.0925e-03 -6.0000e+00 2.6503e-01 3.5387e-05 5.2526e-04 1.7391e-04 1.0907e-04 -6.0000e+00 1.8082e-02 -1.2970e-02 2.0866e-04 12 8 8 10 0 0 21.04 25.47 0.62 -0.01297 -0.00902 57 10 1 5 0 886.780 27.99 19.99 25.47 21.75 33.9 994.45 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -135848 900000 900000 900000 900000 900000 -220205 900000 900000 900000 -125317 900000 900000 900000 87506 900000 -182455 900000 -591 900000 900000 900000 53363 181920 900000 900000 34153 56288 900000 242866 201203 900000 900000 28984 900000 38426 -31195 32103 69708 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-5242 -2 524 -1178 -690 -1771 -474 -2857 162 -1598 693 -4475 3595 141 240 -1149 -4124 729 1948 -677 -1284 -3028 -1161 -2148 487 -1389 196 3482 -914 512 872 699 4753 2467 -2845 2004 -883 963 2049 3161 -158 570 761 -2356 -1031 2038 -2223 3661 822 -2002 1277 -2135 1826 -4095 SS 20230326T115546.3Z 8485.497063 62 1 50.77 2 80.48 94.51 107.98 39.60 0.00 1 0.00 1 0 17 3.438e-01 6.150e-03 1.725e-01 2.022e-03 7.023360e-01 1.115316e-03 7.406978e-03 -6.000000e+00 2.057709e-01 227.44 -2.00 3.44 -2.00 321.15 0.00e+00 1.511179e-03 4.329481e-04 6.770357e-04 -6.000000e+00 1.000890e-02 280.87 -2.00 20.00 -2.00 320.82 0.00e+00 5.761 0.003 302.00 328.00 3 1.4802e+00 3.3283e-03 6.7868e-02 -6.0000e+00 5.1712e-01 -2.6968e-02 4.8589e-03 3.6866e-02 -6.0000e+00 5.7014e-01 5.2808e-02 6.0178e-03 2.0596e-02 -6.0000e+00 3.2239e-01 -3.3614e-02 2.9621e-03 6.8491e-03 -6.0000e+00 1.4090e-01 1.9878e-04 2.5900e-04 5.9245e-05 7.9426e-05 -6.0000e+00 1.0080e-02 -1.3603e-02 2.0080e-04 10 0 0 10 0 0 29.75 25.46 0.35 -0.01360 -0.01166 160 29 1 5 0 317.280 27.99 20.00 25.46 23.59 33.8 1002.78 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -77804 44194 -116716 -41736 900000 87340 -91357 -7645 900000 -25816 -45680 260809 65459 3026 -14379 127456 -80424 27078 -33234 33433 -10039 41133 -13481 -1031 -6819 7473 -7573 -5104 55717 1395 4992 7621 8004 -6365 18375 -1922 -6422 -6952 2940 9500 -6512 8759 312 -983 -246 2227 -2137 2235 1582 3473 -5183 856 2223 2174 761 2258 -1757 -863 164 1170 -424 -180 -1152 1613 -370 270 -1554 -1445 156 -884 1722 -624 -914 -267 -1542 -43 125 -11 1008 -557 663 1062 487 166 590 198 378 -33 157 254 -731 861 385 -105 -1065 -1448 -549 129 -387 122 -231 -12 -177 -10 243 419 695 101 -182 -75 48 280 94 -610 169 -413 668 866 694 4 -80 -125 -489 -140 -77 -184 370 25 -396 269 -271 289 -20 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -306 87 -1106 -246 900000 219 -1438 -64 900000 -305 -678 513 363 35 -219 502 -2360 291 -672 401 -230 684 -413 -29 -199 215 -268 -217 1754 83 322 519 574 -542 1253 -166 -604 -695 285 953 -806 1051 45 -158 -42 390 -403 401 279 599 -1031 180 533 586 216 623 -511 -264 52 426 -171 -75 -474 605 -129 91 -511 -499 57 -390 867 -367 -549 -170 -1066 -31 95 -8 769 -413 452 682 309 112 453 167 370 -34 178 282 -811 845 351 -98 -1084 -1562 -622 147 -493 165 -347 -20 -278 -15 350 583 979 151 -287 -122 76 428 139 -875 232 -581 912 1256 1082 6 -148 -234 -972 -295 -166 -416 850 58 -925 597 -567 596 -41 SS 20230326T120426.9Z 8485.503089 67 1 50.73 2 78.76 95.85 106.89 41.24 0.00 1 0.00 1 0 25 2.930e-01 4.612e-03 1.532e-01 1.207e-03 6.173584e-01 6.271225e-04 6.717952e-03 -6.000000e+00 1.676227e-01 227.44 -2.00 3.44 -2.00 320.55 0.00e+00 8.414715e-04 2.104026e-04 4.442533e-04 -6.000000e+00 6.870319e-03 280.87 -2.00 20.00 -2.00 320.24 0.00e+00 4.954 0.002 302.00 328.00 3 1.3554e+00 1.7933e-03 5.8558e-02 -6.0000e+00 4.2007e-01 -9.7968e-03 2.3086e-03 3.1626e-02 -6.0000e+00 4.5859e-01 2.6525e-02 2.5785e-03 1.6755e-02 -6.0000e+00 2.6885e-01 -2.0585e-02 1.3305e-03 5.2763e-03 -6.0000e+00 1.1158e-01 5.1985e-04 2.3661e-05 3.4277e-05 6.0968e-05 -6.0000e+00 8.0502e-03 -1.3307e-02 1.8476e-04 11 1 0 11 8 0 55.32 25.45 0.33 -0.01331 -0.01313 277 50 1 5 0 183.090 27.99 20.00 25.45 25.00 34.1 1009.35 58800 11118 154988 -26315 -34753 -45784 271500 -46149 900000 -19307 -22657 -29091 -25786 -23297 12514 8448 -43768 372 -7582 367 -24989 22209 -10216 5848 -14818 20402 -25960 -9236 -13474 -5469 -4572 -417 -4805 -6915 -499 -9506 -1368 -4071 11067 -249 -718 2349 -591 -1262 1840 -785 -4787 -650 -1095 4757 -1035 3057 950 89 1550 570 170 -43 531 236 -375 222 2524 1046 1096 1087 -786 767 -273 728 -96 227 -1263 772 -643 409 -522 -253 -204 -735 298 -1342 -897 -1210 -735 -530 280 162 809 235 768 591 692 719 476 716 436 341 -176 237 -671 143 257 -384 -849 -1263 -504 -426 -207 -167 62 -43 80 -48 236 306 474 213 -80 -285 -389 181 -141 -54 56 245 589 889 416 191 60 -66 -231 -200 -108 -268 341 -151 -158 119 -107 108 -88 90 31 182 -108 -147 -226 320 -304 900000 -120 -157 -257 -282 -289 149 112 -1101 7 -160 8 -682 387 -268 145 -493 507 -1034 -302 -463 -194 -193 -20 -277 -422 -28 -594 -90 -337 975 -27 -86 294 -80 -176 253 -114 -740 -100 -179 795 -206 653 227 22 393 153 47 -12 141 63 -106 70 879 410 441 425 -312 314 -127 358 -52 126 -700 394 -303 186 -227 -113 -97 -414 193 -933 -674 -969 -629 -452 248 147 725 202 653 472 535 581 434 706 468 415 -229 303 -806 153 273 -422 -950 -1497 -627 -537 -285 -243 99 -72 132 -76 351 462 724 324 -130 -479 -647 289 -219 -81 85 355 830 1314 658 320 111 -123 -450 -414 -228 -592 768 -332 -345 261 -223 222 -178 SS 20230326T121008.5Z 8485.507043 70 1 50.65 2 77.63 96.74 106.16 42.29 0.00 1 0.00 1 0 25 8.328e-02 4.119e-03 3.683e-02 9.002e-04 5.715444e-01 4.630756e-04 6.329942e-03 -6.000000e+00 4.754901e-02 227.44 -2.00 3.44 -2.00 320.16 0.00e+00 9.316952e-04 1.404094e-04 3.535509e-04 -6.000000e+00 1.915955e-03 280.87 -2.00 20.00 -2.00 319.84 0.00e+00 4.536 0.001 302.00 328.00 3 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