File name: Pandora31s1_CharlesCityVA_20230329_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T124742.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230329_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230329 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230329T114248.6Z 8488.488063 123 1 51.06 2 82.16 91.72 115.81 0.78 0.00 1 0.00 1 0 45 5.131e-01 3.850e-02 2.073e-01 7.979e-03 8.999589e-01 5.189851e-03 8.797800e-03 -6.000000e+00 3.230923e-01 227.67 -2.00 3.44 -2.00 322.11 0.00e+00 3.166745e-03 2.342526e-03 1.275488e-03 -6.000000e+00 2.715605e-02 281.15 -2.00 20.00 -2.00 321.74 0.00e+00 6.839 0.005 302.00 328.00 3 2.5725e+00 1.6756e-02 8.2777e-02 -6.0000e+00 8.3871e-01 7.7555e-01 2.6954e-02 4.7339e-02 -6.0000e+00 9.3437e-01 -1.0716e+00 3.1988e-02 2.7375e-02 -6.0000e+00 5.2410e-01 4.1261e-01 1.4871e-02 9.6302e-03 -6.0000e+00 2.3172e-01 1.7283e-05 1.2522e-03 2.5526e-04 1.1829e-04 -6.0000e+00 1.7265e-02 -1.5340e-04 1.4094e-04 12 8 8 10 0 0 51.78 23.88 0.76 -0.00015 0.00926 30 5 1 5 0 1701.710 26.73 20.00 23.88 15.61 33.5 965.29 900000 900000 900000 900000 -108124 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -169509 900000 900000 900000 -62013 900000 900000 900000 900000 900000 -151898 900000 49093 900000 81819 900000 900000 900000 900000 900000 224763 900000 900000 900000 900000 900000 900000 5329 900000 900000 128755 109026 900000 900000 19949 900000 72367 67641 49805 53072 28966 178692 60727 102515 -21766 48994 114457 44221 6413 54820 7702 25100 10796 22625 23205 24873 -839 67854 -376 33800 10098 -13314 13273 -4722 32587 9537 13803 4348 -2270 5195 2460 -1455 10498 -20172 -159 3221 -3325 14 -2016 -2570 -3615 359 -3264 2929 -10820 8367 845 -1691 -3386 -10078 759 3383 -2786 -3063 -3321 -2473 -2417 -54 -1923 -360 3756 -1909 1308 2608 2310 6003 2633 -3217 2363 834 2615 4506 3091 22 264 217 -1673 -801 1042 -228 1633 1058 -2125 1336 -734 1013 -3980 900000 900000 900000 900000 -986 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -11234 900000 900000 900000 -1526 900000 900000 900000 900000 900000 -9689 900000 434 900000 764 900000 900000 900000 900000 900000 1731 900000 900000 900000 900000 900000 900000 273 900000 900000 2087 2268 900000 900000 1310 900000 3465 3644 3325 3534 2429 3399 3446 3816 -2794 3611 5194 4384 938 5060 1147 3417 1905 4027 4372 4655 -190 7376 -70 4123 1527 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7.1521e-03 1.1485e-04 1.0613e-04 10 0 0 10 0 0 53.90 23.90 0.34 0.00011 -0.00082 149 27 1 5 0 340.930 26.73 20.00 23.90 17.85 33.8 975.17 900000 900000 900000 52590 -127613 900000 900000 900000 900000 900000 -113841 -38690 -32216 -67686 129960 83037 -64309 -12554 23068 -30243 -37587 16911 -941 -12445 -17808 32205 -61385 -18392 -19689 -13660 -9179 28621 -4296 -1280 -6174 -419 -13020 780 13299 79 1746 5547 7718 -9271 12365 -3191 -3934 110 3679 7189 -452 6529 1500 208 -815 242 -1923 2624 -1200 1832 -3409 2444 2887 1596 -1616 824 -1440 295 355 743 835 234 -794 1123 -599 -197 -555 -1760 628 -812 861 -1222 -1147 -819 -1289 36 -13 105 612 -651 674 888 405 938 548 304 579 300 119 80 -696 546 577 -298 -862 -1342 -321 127 -119 -201 -335 -156 -322 202 210 702 731 153 -21 -462 -217 211 80 -390 373 -5 783 644 156 98 -102 -159 -284 -207 6 -133 218 -81 -330 154 -83 400 -110 900000 900000 900000 93 -539 900000 900000 900000 900000 900000 -832 -168 -173 -671 235 285 -1051 -140 198 -461 -630 174 -13 -208 -341 407 -1902 -374 -420 -319 -251 654 -153 -46 -225 -15 -612 39 729 6 139 456 653 -939 1051 -323 -416 12 408 849 -65 974 258 39 -164 50 -418 543 -251 373 -770 584 781 483 -516 254 -460 99 133 313 376 109 -363 475 -236 -71 -195 -657 263 -401 478 -768 -772 -578 -967 28 -11 86 494 -511 495 623 282 688 450 282 601 344 144 95 -781 560 561 -298 -914 -1487 -370 154 -157 -289 -515 -248 -509 310 312 1016 1072 233 -34 -747 -344 325 120 -574 532 -7 1072 930 248 168 -188 -305 -565 -429 13 -297 491 -185 -748 337 -175 810 -221 SS 20230329T120608.4Z 8488.504263 131 1 50.73 2 77.53 95.31 115.55 6.27 0.00 1 0.00 1 0 25 1.116e-01 4.561e-03 1.192e-01 1.321e-03 6.527258e-01 6.927660e-04 7.067161e-03 -6.000000e+00 6.421936e-02 227.67 -2.00 3.44 -2.00 320.59 0.00e+00 1.134133e-03 2.340779e-04 4.703874e-04 -6.000000e+00 2.657614e-03 281.15 -2.00 20.00 -2.00 320.25 0.00e+00 4.501 0.001 302.00 328.00 3 1.9343e+00 1.9753e-03 5.5926e-02 -6.0000e+00 1.6118e-01 -6.0564e-04 2.5782e-03 3.3336e-02 -6.0000e+00 1.7618e-01 1.6544e-02 2.9213e-03 1.7768e-02 -6.0000e+00 1.0285e-01 -1.9028e-02 1.5012e-03 5.5953e-03 -6.0000e+00 4.2603e-02 4.2185e-04 -1.8432e-04 3.6782e-05 6.1182e-05 -6.0000e+00 3.1291e-03 4.3671e-05 1.1047e-04 10 0 0 10 0 0 56.35 23.91 0.30 0.00004 -0.00134 208 37 1 5 0 243.850 26.73 20.00 23.91 18.49 33.7 978.27 23513 7983 900000 17519 -56477 -58896 900000 22790 900000 -4046 -12656 -55146 -25405 -21594 17293 1129 -38092 -5291 -6101 -7885 -18252 14639 -8709 7269 -12927 19771 -25550 -10559 -5883 -3389 -5833 2000 1780 -4229 -1934 -4055 -2473 -2669 5812 -773 -648 2581 1329 -853 1372 564 -2048 -578 -329 4389 -1723 2628 611 -731 465 163 -152 -437 771 682 -940 726 2151 918 -615 1292 -486 398 222 665 -97 651 -827 832 -683 534 -466 -980 168 -739 377 -1351 -943 -1355 -1044 -237 -190 353 630 -182 869 995 645 1025 609 563 502 496 -291 335 -511 265 396 -282 -951 -1043 -439 -421 -46 -385 14 -99 -26 -4 235 502 723 304 -212 -476 -433 229 -272 -207 296 262 649 876 333 36 -14 -146 -136 -274 -77 -208 192 34 -332 202 -174 206 9 41 19 900000 37 -238 -269 900000 61 900000 -18 -65 -529 -235 -248 168 15 -856 -95 -120 -167 -438 260 -214 169 -401 467 -954 -330 -180 -115 -227 85 87 -226 -97 -218 -152 -201 497 -83 -78 320 175 -117 188 80 -284 -83 -50 693 -327 533 139 -183 122 45 -43 -122 207 184 -272 232 719 344 -239 481 -185 159 101 344 -51 349 -438 434 -327 229 -193 -429 83 -411 241 -993 -700 -1073 -883 -211 -166 313 551 -162 711 767 488 818 554 559 544 607 -360 426 -605 296 414 -306 -1055 -1220 -540 -529 -64 -565 23 -157 -41 -7 351 721 1055 468 -346 -764 -717 362 -417 -305 439 374 905 1299 533 62 -26 -275 -270 -553 -167 -448 421 75 -734 442 -360 421 19 SS 20230329T121127.9Z 8488.507961 134 1 50.93 2 76.48 96.14 115.43 7.52 0.00 1 0.00 1 0 25 1.549e-01 4.860e-03 6.852e-02 1.045e-03 6.090882e-01 5.367259e-04 6.687219e-03 -6.000000e+00 8.834956e-02 227.67 -2.00 3.44 -2.00 320.26 0.00e+00 1.097496e-03 1.673514e-04 3.883219e-04 -6.000000e+00 3.561744e-03 281.15 -2.00 20.00 -2.00 319.94 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