File name: Pandora31s1_CharlesCityVA_20231117_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20251126T142439.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20231117_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20231117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231117T122310.2Z 8721.516090 53 1 51.52 2 84.91 118.60 132.99 95.26 0.00 1 0.00 1 0 33 6.410e-01 6.989e-02 3.350e-01 1.875e-02 9.689284e-01 1.275147e-02 8.361785e-03 -6.000000e+00 4.122176e-01 223.96 -2.00 3.44 -2.00 322.59 0.00e+00 -1.325800e-02 5.909877e-03 1.597915e-03 -6.000000e+00 2.770112e-02 283.10 -2.00 20.00 -2.00 322.19 0.00e+00 9.696 0.015 302.00 328.00 3 7.6484e-01 4.2974e-02 1.0815e-01 -6.0000e+00 1.0263e+00 1.8642e+00 5.8170e-02 4.7969e-02 -6.0000e+00 1.1435e+00 -2.0553e+00 5.8626e-02 2.8615e-02 -6.0000e+00 6.5622e-01 6.5386e-01 2.9336e-02 1.0791e-02 -6.0000e+00 3.0336e-01 5.5173e-06 6.7636e-03 6.0058e-04 1.1012e-04 -6.0000e+00 2.2038e-02 1.2807e-03 1.7941e-04 12 8 8 10 0 0 -20.99 23.33 1.23 0.00128 0.05211 27 5 1 5 0 1907.660 26.11 19.99 23.33 17.22 34.6 951.36 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 112509 900000 94378 900000 900000 900000 -27075 900000 900000 128695 -9223 900000 900000 900000 900000 900000 -79799 900000 234703 900000 105142 900000 163308 900000 900000 900000 28831 900000 900000 900000 900000 900000 900000 -27420 900000 900000 900000 107638 900000 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5.5835e-05 3.3599e-04 1.3144e-04 1.2887e-04 -6.0000e+00 1.8182e-02 1.8464e-03 1.5681e-04 12 8 8 10 0 0 20.16 23.31 0.50 0.00185 0.00437 108 19 1 5 0 469.470 26.11 20.00 23.31 19.05 34.4 959.95 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -302458 900000 -159634 900000 900000 900000 -139224 900000 900000 -78061 -91947 900000 900000 900000 900000 900000 -195765 900000 -116582 900000 131813 900000 -71354 175204 202182 900000 5104 127108 900000 66875 76083 91754 163038 -36681 900000 12542 -22620 9438 84446 93361 9816 51370 12189 -6615 2614 -371 546 24419 -5460 19504 -17804 -2651 6170 14057 1671 9628 -5810 10272 -1627 3021 -3129 4191 -6620 9035 -3614 -91 -1063 -2335 5739 -3860 6893 1243 288 1157 -3130 1017 -576 -323 2783 -5196 430 3260 178 -136 -862 335 92 739 -172 38 -2045 2051 314 -1128 -1379 -2759 402 1508 -599 -261 -546 -23 -582 159 -239 977 842 93 817 -349 -235 1373 232 -1286 948 -837 269 719 919 -119 76 -250 -1032 -195 35 -119 591 262 -884 668 -331 832 -615 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -1691 900000 -669 900000 900000 900000 -730 900000 900000 -327 -456 900000 900000 900000 900000 900000 -4240 900000 -1333 900000 553 900000 -1224 734 848 900000 53 533 900000 714 841 944 870 -1358 900000 335 -838 302 1416 1637 425 1840 669 -488 190 -30 44 1544 -450 1247 -1766 -260 655 1581 225 1214 -899 1486 -308 581 -695 887 -1505 1755 -715 -16 -186 -456 1243 -1038 1983 437 112 478 -1446 478 -286 -163 1340 -2577 190 1349 78 -66 -496 211 68 629 -159 34 -1738 1484 213 -795 -1044 -2235 339 1379 -638 -299 -706 -32 -815 216 -314 1244 1102 129 1180 -515 -333 1816 299 -1632 1141 -997 317 930 1389 -196 139 -500 -2099 -423 81 -289 1453 653 -2190 1539 -716 1766 -1305 SS 20231117T124449.5Z 8721.531129 59 1 50.89 2 81.20 122.15 128.92 97.98 0.00 1 0.00 1 0 25 4.149e-01 5.130e-03 2.161e-01 1.852e-03 7.655999e-01 1.016306e-03 8.012339e-03 -6.000000e+00 2.379029e-01 223.96 -2.00 3.44 -2.00 321.41 0.00e+00 2.157921e-03 4.191946e-04 8.205628e-04 -6.000000e+00 1.201037e-02 283.10 -2.00 20.00 -2.00 321.07 0.00e+00 6.181 0.004 302.00 328.00 3 8.2584e-01 3.0680e-03 7.2771e-02 -6.0000e+00 5.9495e-01 -2.8628e-02 4.9069e-03 4.0008e-02 -6.0000e+00 6.5493e-01 4.0719e-02 6.3059e-03 2.2948e-02 -6.0000e+00 3.7862e-01 -2.5607e-02 3.0315e-03 7.8016e-03 -6.0000e+00 1.6569e-01 2.4710e-04 -1.5309e-04 5.2935e-05 8.9799e-05 -6.0000e+00 1.2001e-02 1.7163e-03 1.4764e-04 10 0 0 10 0 0 4.41 23.31 0.36 0.00172 0.00057 250 45 1 5 0 203.510 26.11 20.00 23.31 21.34 34.4 969.69 900000 900000 900000 900000 -35692 900000 124251 900000 900000 900000 900000 -55592 900000 -121731 900000 -67174 -21973 -41811 274237 -62710 -69286 217999 -50396 65390 -40626 124205 -75172 24471 -53020 25727 -44393 48379 -18161 -6193 -6377 -12613 8347 -5672 53454 -8173 4948 268 9258 -11573 11679 -1851 1434 -560 -492 13117 -3816 9995 -2340 1757 -1284 876 -1382 2024 -1298 2057 -1299 318 5512 1723 2564 1468 1048 1067 873 146 216 974 -1475 1767 -2471 1398 -2648 127 -1031 -191 268 -652 -1561 -1467 -1179 -465 343 -272 907 -810 930 290 433 182 692 -21 737 404 -77 302 -763 709 157 -244 -1243 -864 -425 110 -64 -262 139 87 69 112 446 350 733 -113 -79 -560 -316 201 -48 -97 -8 210 290 611 174 224 -77 -48 -418 -285 -10 -115 390 -140 -321 12 83 261 38 900000 900000 900000 900000 -64 900000 224 900000 900000 900000 900000 -130 900000 -918 900000 -462 -123 -295 494 -637 -772 393 -537 271 -486 336 -1380 181 -817 236 -946 549 -426 -134 -135 -300 187 -181 1182 -400 239 15 491 -779 643 -122 96 -41 -39 1017 -369 955 -282 224 -180 127 -210 294 -189 291 -203 56 1066 391 600 346 255 280 263 47 75 346 -521 562 -801 397 -764 38 -342 -76 125 -350 -921 -856 -736 -306 233 -190 618 -534 564 182 270 115 502 -18 685 430 -88 337 -794 649 144 -230 -1187 -866 -452 127 -77 -361 212 132 105 165 660 506 1078 -166 -121 -885 -484 311 -71 -141 -11 283 386 879 272 398 -142 -96 -884 -610 -22 -274 897 -329 -743 27 179 559 79 SS 20231117T125822.7Z 8721.540540 64 1 50.94 2 78.95 124.47 126.39 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