File name: Pandora153s1_ChelseaMA_20240606_L2Fit_fwvt1c6d20231012p1-8.txt File generation date: 20241009T164719.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v6d20231012.txt Level 1 file used: Pandora153s1_ChelseaMA_20240606_L1_smca1c6d20231012p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 5 First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0301 492.1513 492.2725 492.3937 492.5149 492.6361 492.7573 492.8784 492.9995 493.1206 493.2417 493.3628 493.4838 493.6048 493.7259 493.8469 493.9678 494.0888 494.2098 494.3307 494.4516 494.5725 494.6934 494.8143 494.9351 495.0560 495.1768 495.2976 495.4184 495.5391 495.6599 495.7806 495.9013 496.0220 496.1427 496.2634 496.3840 496.5047 496.6253 496.7459 496.8665 496.9870 497.1076 497.2281 497.3486 497.4691 497.5896 497.7101 497.8305 497.9510 498.0714 498.1918 498.3122 498.4325 498.5529 498.6732 498.7935 498.9138 499.0341 499.1544 499.2746 499.3948 499.5151 499.6353 499.7554 499.8756 499.9957 500.1159 500.2360 500.3561 500.4762 500.5962 500.7163 500.8363 500.9563 501.0763 501.1963 501.3162 501.4362 501.5561 501.6760 501.7959 501.9158 502.0357 502.1555 502.2753 502.3951 502.5149 502.6347 502.7545 502.8742 502.9939 503.1136 503.2333 503.3530 503.4727 503.5923 503.7119 503.8315 503.9511 504.0707 504.1902 504.3098 504.4293 504.5488 504.6683 504.7878 504.9072 505.0267 505.1461 505.2655 505.3849 505.5042 505.6236 505.7429 505.8622 505.9815 506.1008 506.2201 506.3393 506.4586 506.5778 506.6970 506.8161 506.9353 507.0545 507.1736 507.2927 507.4118 507.5309 507.6499 507.7690 507.8880 508.0070 508.1260 508.2450 508.3639 508.4829 508.6018 508.7207 508.8396 508.9585 509.0773 509.1962 509.3150 509.4338 509.5526 509.6714 509.7901 509.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240606T135839.7Z 8923.582404 240 1 51.61 2 39.28 106.83 37.30 100.65 0.00 1 0.00 1 0 15 2.929e-03 2.919e-03 1.487e-03 1.478e-03 8.066630e+03 1.067583e+02 5.415407e+02 -6.000000e+00 1.716313e+02 284.89 -2.00 20.00 -2.00 505.24 0.00e+00 5.465034e-04 4.157851e-05 4.656593e-05 -6.000000e+00 8.417795e-05 284.89 -2.00 20.00 -2.00 500.13 0.00e+00 3.206224e-02 3.055498e-02 5.291747e-02 -6.000000e+00 5.972249e-02 232.46 -2.00 3.54 -2.00 501.78 0.00e+00 1.291 0.000 489.00 513.00 1 8.1572e+00 2.3443e-03 4.9701e-03 -6.0000e+00 4.5923e-03 5.9701e-03 5.9418e-04 1.2700e-03 -6.0000e+00 1.1767e-03 4.5671e-04 -2.1809e-04 1.6139e-04 4.7886e-05 -6.0000e+00 3.4371e-04 9.1720e-03 -3.3945e-05 10 0 0 10 0 0 79.03 19.37 1.08 0.00917 0.00766 14 3 1 4 0 3685.960 22.40 14.99 19.37 29.53 0.0 986.85 -317 -123 -267 -239 140 357 590 369 381 60 -2 16 -13 -349 -307 -295 -284 -130 162 170 -482 -134 9 76 405 208 326 321 24 -154 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144 419 140 234 82 79 171 396 174 313 177 13 -161 -118 -149 -244 149 7 -27 -75 -43 120 -12 191 14 244 152 -205 -304 -530 -205 SQ 20240606T140834.3Z 8923.589285 244 1 49.11 2 37.54 109.22 35.55 102.73 0.00 1 0.00 1 0 15 2.525e-03 2.511e-03 1.253e-03 1.247e-03 5.600288e+03 8.586590e+01 3.931049e+02 -6.000000e+00 1.479631e+02 284.89 -2.00 20.00 -2.00 505.24 0.00e+00 5.091218e-04 3.505029e-05 3.702475e-05 -6.000000e+00 7.257133e-05 284.89 -2.00 20.00 -2.00 500.22 0.00e+00 2.436923e-02 2.558662e-02 3.603273e-02 -6.000000e+00 5.149554e-02 232.46 -2.00 3.54 -2.00 501.84 0.00e+00 1.260 0.000 489.00 513.00 1 7.8574e+00 1.9630e-03 3.6703e-03 -6.0000e+00 3.9595e-03 2.7188e-03 4.9902e-04 8.8737e-04 -6.0000e+00 1.0149e-03 6.2255e-04 3.8052e-04 1.3840e-04 3.9130e-05 -6.0000e+00 2.9625e-04 6.3450e-03 -3.6820e-05 10 0 0 10 0 0 96.38 19.40 1.11 0.00634 0.00898 15 3 1 4 0 3273.530 22.40 15.01 19.40 29.41 0.0 987.08 -373 -364 -97 147 136 336 397 527 127 140 185 67 -25 -185 -343 -618 -170 -349 -176 46 61 -204 -60 179 186 429 96 142 26 -254 -249 179 38 201 275 -7 -55 114 67 -75 300 44 193 222 50 363 138 118 108 -98 -424 -242 -544 -623 -107 -343 -25 -283 -116 -60 257 321 429 315 -124 80 94 24 76 -416 -145 -66 -65 -85 79 -243 -316 -571 -364 -93 -249 48 -271 -188 -10 -139 -111 151 258 261 86 287 444 227 217 282 192 -3 -181 -567 -528 -455 -415 -6 -288 -291 -315 -379 -78 -3 182 -113 183 161 280 177 328 391 264 197 141 -83 116 389 66 -14 461 163 144 408 -83 -270 -118 -167 82 32 14 -156 -104 98 11 50 99 84 -18 265 -107 -387 -304 -146 -375 -369 -100 149 142 357 430 575 139 152 199 71 -26 -191 -353 -639 -177 -371 -191 50 68 -217 -64 190 198 455 102 155 28 -266 -256 183 39 215 287 -8 -58 120 70 -77 307 45 200 233 53 384 145 123 111 -98 -435 -242 -540 -622 -108 -342 -25 -291 -120 -62 264 330 442 324 -127 81 94 24 74 -402 -139 -64 -63 -83 77 -238 -305 -545 -343 -87 -233 45 -258 -181 -9 -135 -109 148 252 256 85 286 445 228 215 274 182 -3 -165 -510 -475 -416 -391 -6 -286 -291 -315 -376 -77 -3 181 -109 178 158 276 175 326 390 262 193 136 -79 110 367 62 -13 436 155 136 383 -78 -250 -112 -157 77 29 13 -148 -100 95 11 49 98 83 -18 259 -103 -368 -285 -137 SQ 20240606T141301.0Z 8923.592373 247 1 50.81 2 36.77 110.33 34.77 103.70 0.00 1 0.00 1 0 15 2.755e-03 2.724e-03 1.485e-03 1.477e-03 6.633924e+03 1.037872e+02 4.671191e+02 -6.000000e+00 1.614386e+02 284.89 -2.00 20.00 -2.00 505.23 0.00e+00 4.704971e-04 4.163475e-05 3.838048e-05 -6.000000e+00 7.917958e-05 284.89 -2.00 20.00 -2.00 500.17 0.00e+00 1.492714e-02 3.050830e-02 4.075368e-02 -6.000000e+00 5.618134e-02 232.46 -2.00 3.54 -2.00 501.80 0.00e+00 1.247 0.000 489.00 513.00 1 8.1562e+00 2.3458e-03 4.0297e-03 -6.0000e+00 4.3199e-03 4.6261e-03 5.9413e-04 1.0198e-03 -6.0000e+00 1.1071e-03 4.6226e-04 4.4391e-04 1.6327e-04 4.4141e-05 -6.0000e+00 3.2324e-04 3.3235e-03 -1.1658e-05 10 0 0 10 0 0 69.86 19.41 1.09 0.00332 0.00640 14 3 1 4 0 3628.920 22.40 15.00 19.41 29.55 0.0 987.93 -337 48 53 158 69 153 295 682 450 435 19 -150 141 -465 -275 -475 -342 -163 -16 14 -142 -50 108 -4 173 242 64 55 54 -234 -309 -183 126 114 274 -17 -13 282 -10 157 -88 165 147 174 218 279 364 -6 65 -267 -280 -792 -573 -539 -115 -154 -265 -21 -1 85 50 368 227 66 197 1 177 0 32 -31 -88 -422 -92 -222 71 -167 -539 -322 -131 -346 -324 -187 -579 -29 -214 64 147 -221 469 63 328 324 570 320 435 381 -155 -118 -347 -60 -386 -684 -454 -267 -125 -363 -430 -266 -118 -176 123 4 181 46 60 299 -34 340 212 420 79 452 61 146 306 244 510 180 224 43 4 -377 -122 -212 -169 -179 -54 165 -105 228 242 207 267 271 246 118 -225 -475 -359 -234 -340 48 53 163 73 166 315 732 484 465 20 -156 150 -490 -287 -499 -362 -170 -17 15 -155 -55 117 -4 189 265 70 59 57 -241 -313 -185 129 120 295 -19 -14 303 -11 166 -93 175 157 182 230 294 382 -7 69 -275 -281 -782 -559 -528 -114 -157 -268 -21 -1 87 51 378 233 68 201 1 176 0 32 -30 -87 -416 -91 -215 69 -162 -519 -315 -127 -333 -312 -181 -549 -28 -206 62 143 -216 454 62 321 320 565 318 426 365 -145 -108 -312 -55 -353 -618 -422 -256 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