File name: Pandora153s1_ChelseaMA_20240702_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240703T045540.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240702_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T100532.1Z 8949.420511 175 1 50.47 2 82.13 65.96 47.96 97.33 0.00 1 0.00 1 0 17 4.425e-01 2.659e-02 3.824e-01 1.681e-02 9.453322e-01 9.725907e-03 1.066941e-02 -6.000000e+00 2.616724e-01 233.00 -2.00 3.54 -2.00 322.26 0.00e+00 7.748435e-03 5.785641e-03 4.131211e-03 -6.000000e+00 1.157605e-02 287.34 -2.00 20.00 -2.00 321.74 0.00e+00 6.803 0.006 302.00 328.00 3 1.3463e+00 4.0059e-02 8.6798e-02 -6.0000e+00 6.5827e-01 1.1924e+00 5.1515e-02 5.3484e-02 -6.0000e+00 7.1302e-01 -1.4650e+00 3.9990e-02 2.7766e-02 -6.0000e+00 4.2246e-01 5.7221e-01 1.8868e-02 9.9769e-03 -6.0000e+00 1.7534e-01 5.0674e-05 -9.2077e-04 4.4804e-04 2.0330e-04 -6.0000e+00 1.2742e-02 3.5743e-02 2.2941e-05 12 8 8 10 0 0 46.84 18.28 0.64 0.03574 0.02882 36 7 1 5 0 1401.740 21.58 15.01 18.28 23.13 0.0 957.32 -46528 -76499 21623 -100639 -101954 -106296 -138809 900000 -71293 -80365 -122282 -57524 -110483 900000 21573 -37265 65540 -34648 22275 -52294 8075 -67894 20803 168975 -34557 116239 -31936 58203 -77662 58158 -53838 -16399 -18002 30398 27719 -55359 68174 -5053 146405 -13208 70807 23615 58981 24687 26552 90651 10231 52704 11183 44627 8525 60195 68255 31704 54727 38954 43956 1195 50177 -18173 20662 -1404 45061 32282 27554 41201 7149 35425 23839 34476 2688 17306 12621 7483 5368 -11484 13451 -14558 18548 1176 11254 3727 -3258 3297 265 10249 -2784 6959 -2288 2273 -9623 3771 -926 -8932 -2605 -7651 248 -6275 -24 -3002 -2157 -3725 -1787 -3133 -2755 -457 -7272 87 -998 -218 411 -669 -275 -1031 -239 -1843 2464 -2937 559 547 1672 2826 3478 3228 -55 2831 -764 2746 -118 1126 405 -71 1100 -689 671 -344 1119 -232 155 -633 -537 -179 -2214 -901 -2165 354 -3148 -2733 -2691 -4755 900000 -1274 -1556 -3643 -1028 -4278 900000 353 -1277 1074 -1342 498 -2414 192 -3236 443 2768 -1184 1904 -1099 954 -3944 953 -2999 -752 -944 996 863 -3809 1452 -257 2399 -974 2436 1354 2416 1416 1479 2673 687 2418 824 2559 782 3649 4137 2961 4214 3574 3817 153 3699 -2560 2031 -191 4430 4072 3837 4995 1242 4933 4179 6157 644 3998 2915 1655 1073 -2427 2138 -3291 3555 326 3337 1243 -1276 1282 113 4137 -1327 3047 -1080 975 -4343 1563 -368 -4217 -1354 -5002 178 -5552 -21 -2758 -1818 -2830 -1214 -2170 -2023 -346 -6314 77 -1018 -255 543 -960 -401 -1490 -332 -2551 3350 -4436 855 846 2463 3893 4569 4110 -70 3403 -952 3636 -189 2049 831 -160 2609 -1792 1840 -991 3224 -679 443 -1708 -1334 -412 -5068 SS 20240702T101558.4Z 8949.427760 178 1 50.25 2 80.36 67.60 46.08 99.25 0.00 1 0.00 1 0 17 6.727e-01 1.480e-02 3.024e-01 7.205e-03 8.428027e-01 4.068967e-03 9.644866e-03 -6.000000e+00 3.957599e-01 233.00 -2.00 3.54 -2.00 321.92 0.00e+00 6.658876e-03 2.431167e-03 4.651919e-03 -6.000000e+00 1.754302e-02 287.34 -2.00 20.00 -2.00 321.37 0.00e+00 5.689 0.003 302.00 328.00 3 1.4770e+00 1.6286e-02 7.5966e-02 -6.0000e+00 9.9385e-01 4.6321e-01 2.3503e-02 5.2231e-02 -6.0000e+00 1.0761e+00 -5.5362e-01 2.2593e-02 2.8425e-02 -6.0000e+00 6.4045e-01 2.1789e-01 1.0145e-02 9.5024e-03 -6.0000e+00 2.6651e-01 1.5987e-04 -6.6445e-04 1.9546e-04 1.8128e-04 -6.0000e+00 1.9056e-02 3.5677e-02 -3.1162e-05 12 8 8 10 0 0 2.63 18.30 0.43 0.03568 0.03068 60 11 1 5 0 837.320 21.58 15.00 18.30 23.45 0.0 959.23 -239475 -233415 -219377 -123337 -271085 -166610 -247096 -189318 -143490 -223992 -190885 -194863 -101247 -64425 900000 -101193 80927 -36436 -58037 -19866 -89159 83336 2546 -67059 -74300 10733 -32067 -70418 -51070 -56149 -24393 -39138 7360 21864 45427 -56146 -21892 -274 8800 -6666 -5491 34940 32538 31437 28407 20968 24766 27733 17384 18257 22556 9552 33082 14858 17702 15668 9501 12215 10910 13335 9575 8072 13333 11820 15055 5832 11440 7534 6072 7209 4287 2205 3918 5855 -2311 2935 -4831 4454 -2090 -2947 -44 -844 -1249 850 -821 75 -1042 -969 1946 1114 1852 -2682 -896 -2099 -3436 -1586 -1440 651 -1495 -252 -1434 -1597 -455 -1396 -3513 -2774 -1399 -1261 808 214 17 151 116 -268 -69 -23 254 -377 230 178 655 1216 1610 1198 971 -481 591 1339 509 183 156 -122 -305 14 60 202 250 257 -264 -163 -144 -752 -449 -3365 -3578 -3082 -866 -5540 -1170 -4103 -1934 -1008 -3719 -2438 -3111 -841 -543 900000 -1745 569 -461 -978 -237 -2130 585 25 -1413 -1775 113 -518 -1632 -1005 -1341 -531 -1210 165 445 702 -2406 -738 -9 315 -328 -297 1350 1349 1347 1277 1046 1235 1422 1062 1218 1632 886 2673 1566 1915 1794 1175 1442 1257 1480 1157 1111 1831 1864 2423 1028 1943 1419 1311 1759 1169 629 1063 1440 -553 602 -1034 927 -545 -935 -16 -355 -577 409 -428 41 -600 -567 1091 600 926 -1334 -437 -1121 -2155 -1155 -1232 626 -1578 -259 -1382 -1375 -356 -1120 -3069 -2539 -1346 -1320 933 283 25 238 184 -416 -102 -33 375 -590 375 294 1045 1836 2326 1676 1313 -638 771 1888 836 344 325 -273 -668 32 149 523 659 681 -689 -403 -360 -1766 -1032 SS 20240702T102440.6Z 8949.433803 183 1 50.33 2 78.86 68.96 44.52 100.91 0.00 1 0.00 1 0 17 6.379e-01 1.230e-02 1.387e-01 3.273e-03 7.680502e-01 1.817428e-03 8.802153e-03 -6.000000e+00 3.750431e-01 233.00 -2.00 3.54 -2.00 321.62 0.00e+00 4.471978e-03 1.007825e-03 4.123758e-03 -6.000000e+00 1.663744e-02 287.34 -2.00 20.00 -2.00 321.03 0.00e+00 4.993 0.002 302.00 328.00 3 1.0453e+00 6.7685e-03 6.7530e-02 -6.0000e+00 9.4175e-01 2.5595e-01 9.6029e-03 4.7561e-02 -6.0000e+00 1.0194e+00 -2.8779e-01 9.3445e-03 2.4916e-02 -6.0000e+00 6.0646e-01 1.1001e-01 4.2891e-03 7.4792e-03 -6.0000e+00 2.5256e-01 5.3028e-04 -5.1599e-04 9.0772e-05 1.2382e-04 -6.0000e+00 1.8047e-02 3.5486e-02 -2.8207e-05 12 8 8 10 0 0 10.37 18.32 0.37 0.03549 0.03161 134 25 1 5 0 375.550 21.58 15.01 18.32 23.96 0.0 961.36 -207740 -240739 -148221 -245296 -167900 -259633 -171591 -228906 -165776 -198987 -187104 -80867 -179861 -2431 -104121 -46430 -82284 -39496 -42423 -64606 -35818 -60761 -35687 -63210 20218 -42985 -32763 -51369 -35701 -21160 -38497 7270 -22373 20140 -15822 16978 -14829 7007 -2982 4025 18904 7661 15162 4894 24450 2686 7462 8399 10169 12171 5869 19176 9526 15026 6713 11944 4870 6400 7030 6150 11420 5811 10573 4738 8739 5180 6483 3899 4269 4498 3081 4483 75 2354 -1259 673 -2417 -1983 -235 -2476 545 -3075 -913 -2371 194 -986 -498 78 -635 791 -93 371 -1899 -697 -1769 -846 -192 114 -300 -789 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