File name: Pandora153s1_ChelseaMA_20240722_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240723T050011.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240722_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T101117.0Z 8969.424502 211 1 49.40 2 83.49 68.61 88.13 238.25 0.00 1 0.00 1 0 17 6.596e-01 5.666e-02 4.602e-01 4.324e-02 9.081053e-01 2.519746e-02 1.077395e-02 -6.000000e+00 3.988465e-01 232.76 -2.00 3.54 -2.00 321.97 0.00e+00 1.210411e-02 1.176303e-02 2.427509e-03 -6.000000e+00 1.844593e-02 288.66 -2.00 20.00 -2.00 321.39 0.00e+00 7.978 0.010 302.00 328.00 3 1.3440e+00 9.1758e-02 9.3596e-02 -6.0000e+00 1.0041e+00 1.7360e+00 1.0650e-01 4.9191e-02 -6.0000e+00 1.0901e+00 -1.8665e+00 6.0893e-02 2.3503e-02 -6.0000e+00 6.4120e-01 6.9909e-01 3.3084e-02 1.0906e-02 -6.0000e+00 2.6440e-01 1.4291e-05 -2.5039e-03 1.1852e-03 2.0706e-04 -6.0000e+00 1.9787e-02 3.3784e-02 6.5420e-06 12 8 8 10 0 0 35.86 18.65 1.07 0.03378 0.01497 15 3 1 5 0 3292.880 21.88 15.00 18.65 26.42 0.0 972.06 -32393 316383 132641 -50159 900000 900000 900000 37431 900000 -79013 35746 19287 900000 299 302550 900000 -58972 900000 -5315 48651 -22380 697 54076 7009 216622 40784 273527 -29198 900000 -5549 26394 76332 3090 68218 50237 28761 -78411 900000 146093 197214 41987 87191 73381 -719 76622 -9912 18225 -48699 138368 -3224 11413 80465 42554 71531 11192 68779 27572 144739 -727 30512 56283 -6194 65395 11477 81311 -779 35435 20998 11412 -284 10747 56714 22417 64899 -14170 -3467 -38891 29208 -33550 -13588 5245 17306 24776 24275 27324 -18680 14579 -5791 2352 -4232 -5066 -9007 -13040 -4708 -9213 7603 -4160 5989 2086 -375 -1228 300 4188 -11892 -751 -18774 5962 -2989 6782 1702 -645 474 -4127 -623 -1510 1516 -5255 1420 -3296 3017 5701 2087 7483 -1885 2789 -4821 7157 5223 1015 4658 -2300 688 -920 2201 -3657 1669 -596 177 794 1880 -1705 -751 -2121 -3522 13318 5583 -5630 900000 900000 900000 1576 900000 -6375 1505 812 900000 19 12735 900000 -9309 900000 -549 2793 -2398 53 2276 456 9118 1717 11514 -2123 900000 -340 1414 3213 272 3133 2499 1651 -13502 900000 6150 8301 3213 4337 4212 -85 4515 -1252 1744 -9318 5824 -432 1441 6097 4559 6624 1756 6659 3587 6093 -111 3596 5212 -1067 6882 2108 8557 -167 5817 3777 2489 -78 2838 10504 5061 9561 -3687 -788 -10864 4795 -10913 -4368 1646 5497 7964 8267 9515 -10794 6248 -3080 1134 -2073 -2326 -4067 -6088 -2180 -5183 4306 -3136 4721 1860 -342 -1048 224 2724 -9056 -543 -17170 4540 -2723 6333 1928 -847 662 -6160 -882 -2081 1985 -7521 2000 -5122 4479 7984 2875 9364 -2503 3415 -6181 8079 6536 1541 7879 -4664 1469 -2138 5323 -10033 4528 -1681 499 2181 4821 -4182 -1692 -4700 SS 20240722T102224.3Z 8969.432226 214 1 50.09 2 81.57 70.39 89.80 240.12 0.00 1 0.00 1 0 25 5.543e-01 1.901e-02 3.193e-01 1.045e-02 8.091616e-01 5.915589e-03 9.180158e-03 -6.000000e+00 3.256451e-01 232.76 -2.00 3.54 -2.00 322.03 0.00e+00 4.386149e-03 3.539510e-03 4.774415e-03 -6.000000e+00 1.453683e-02 288.66 -2.00 20.00 -2.00 321.48 0.00e+00 6.407 0.005 302.00 328.00 3 1.2892e+00 2.4128e-02 8.1008e-02 -6.0000e+00 8.1685e-01 5.7543e-01 3.2807e-02 5.2197e-02 -6.0000e+00 8.8409e-01 -7.4079e-01 2.8644e-02 2.5601e-02 -6.0000e+00 5.2650e-01 2.9756e-01 1.3091e-02 7.0022e-03 -6.0000e+00 2.1973e-01 1.0417e-04 -7.3892e-04 2.9448e-04 1.4470e-04 -6.0000e+00 1.5679e-02 3.3996e-02 -1.9730e-05 12 8 8 10 0 0 70.56 18.67 0.68 0.03400 0.02844 58 11 1 5 0 863.560 21.88 15.00 18.67 26.94 0.0 974.27 -227051 -163874 18280 -215786 -194559 -157785 -97148 -163958 -81084 -99105 -147386 -137952 -133334 -62626 -106045 170977 -104001 -53269 -70889 -45360 18623 -18175 -26132 -51269 -60699 -54887 -59575 -73228 5994 -25306 -5337 22105 -9803 -9060 -16892 38589 -45485 42566 17000 69475 10232 21877 14345 13767 54085 41538 31560 2974 56874 8290 38087 27236 21515 56093 17137 32970 18532 29294 16786 21427 3860 27829 11249 13569 15882 15670 12323 4663 9381 11483 6783 10116 8069 2929 7129 4750 -10460 863 -4835 -209 1817 -1971 -660 -2190 -88 -1247 1289 -1048 1326 -178 -151 -901 -4671 -4984 -2835 -875 -613 262 -266 -2457 -2444 -2496 -705 -1929 -3394 -3511 -2057 -2026 -1577 -495 -738 135 -123 -337 -135 -165 255 942 504 331 1498 930 2205 784 2405 883 1337 1947 747 65 447 1158 -155 -210 -376 112 -661 588 271 -394 -780 -255 -892 -6313 -2734 186 -5800 -3787 -2047 -990 -2583 -827 -1010 -2322 -2301 -2719 -813 -2654 1743 -3374 -1136 -1905 -1064 228 -315 -506 -1359 -1857 -1623 -1822 -2464 92 -593 -125 473 -330 -314 -603 787 -2365 1085 676 1912 563 1138 834 814 2151 1906 1641 215 2551 659 2524 2249 2062 4118 1957 3328 2192 3046 1900 2272 508 3206 1755 2324 2785 2732 2249 975 2104 2618 1760 2606 2057 728 1679 1032 -2538 198 -1365 -62 618 -796 -288 -1033 -43 -659 693 -588 718 -93 -74 -423 -2260 -2605 -1674 -598 -489 238 -261 -2442 -2254 -2064 -529 -1491 -2847 -3118 -1920 -2058 -1790 -633 -1057 203 -187 -501 -192 -230 360 1392 788 528 2304 1374 3098 1079 3143 1134 1696 2665 1191 118 899 2485 -359 -521 -1000 309 -1871 1658 753 -1044 -1931 -588 -2034 SS 20240722T103747.0Z 8969.442905 219 1 50.35 2 78.87 72.83 92.16 242.65 0.00 1 0.00 1 0 17 4.430e-01 9.907e-03 1.732e-01 2.807e-03 6.653036e-01 1.530301e-03 7.638037e-03 -6.000000e+00 2.603143e-01 232.76 -2.00 3.54 -2.00 321.35 0.00e+00 4.200725e-03 7.849314e-04 3.029389e-03 -6.000000e+00 1.161963e-02 288.66 -2.00 20.00 -2.00 320.71 0.00e+00 4.996 0.002 302.00 328.00 3 9.1133e-01 5.4450e-03 6.2634e-02 -6.0000e+00 6.5298e-01 1.4793e-01 7.4792e-03 3.9186e-02 -6.0000e+00 7.0670e-01 -1.5236e-01 7.0946e-03 2.0749e-02 -6.0000e+00 4.2086e-01 5.3211e-02 3.3340e-03 6.5108e-03 -6.0000e+00 1.7567e-01 7.0081e-04 -3.5745e-04 8.0850e-05 9.6598e-05 -6.0000e+00 1.2532e-02 3.2971e-02 -2.7033e-05 12 8 8 10 0 0 31.46 18.71 0.38 0.03297 0.03029 166 31 1 5 0 303.290 21.88 15.01 18.71 27.32 0.0 976.06 -81279 -217840 56797 -196684 -22949 -187780 -136798 -118234 -143332 -108739 -165528 -7977 -115190 36935 -75574 -29936 -53787 8345 -27929 -65498 -2336 -70653 15408 -48683 4464 -26483 -10361 -27604 -24171 -4139 -30257 16992 -14705 8877 -20513 -6023 -6298 1499 9237 -7953 7768 -6926 18784 -987 12957 2661 4588 5888 4393 8484 1603 13143 3913 10501 5038 7709 3193 1220 5110 1620 6463 1902 7172 3557 4057 2619 1694 1491 1485 3776 421 3596 -904 3109 -2058 -713 -835 -2312 692 -3073 622 -2543 -1284 -2203 -601 -626 -392 1174 23 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