File name: Pandora153s1_ChelseaMA_20240819_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240820T045304.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240819_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240819T131102.2Z 8997.549331 338 1 51.34 2 55.38 105.92 129.62 283.32 0.00 1 0.00 1 0 17 3.108e-02 1.296e-02 2.260e-02 6.922e-03 2.537783e-01 3.543528e-03 3.050986e-03 -6.000000e+00 1.819867e-02 231.49 -2.00 3.54 -2.00 317.64 0.00e+00 -2.118319e-04 5.541576e-04 5.149870e-04 -6.000000e+00 8.160298e-04 288.81 -2.00 20.00 -2.00 316.76 0.00e+00 1.755 0.000 302.00 328.00 3 6.1896e+00 9.4581e-03 2.2132e-02 -6.0000e+00 4.5506e-02 1.4623e-01 1.0694e-02 1.3526e-02 -6.0000e+00 4.9270e-02 -1.8877e-02 6.3690e-03 6.3795e-03 -6.0000e+00 2.9376e-02 1.2155e-03 3.1027e-03 1.8232e-03 -6.0000e+00 1.2319e-02 1.3125e-04 6.1389e-04 2.0777e-04 1.9982e-05 -6.0000e+00 8.7830e-04 2.4056e-02 4.7926e-05 12 8 8 10 0 0 99.47 19.13 0.94 0.02406 0.02867 14 3 1 5 0 3666.940 22.19 15.01 19.13 29.47 0.0 986.03 -2832 9618 -5827 10286 -9504 -554 9517 -3525 5184 -16863 1736 -8083 3865 1797 -867 226 -5023 4698 -6289 3635 300 3299 -1649 4811 -628 239 1104 -4305 2006 -2425 6486 1693 861 -4210 -1636 -1506 -3051 2252 -2365 3208 -1874 812 -1388 -1886 157 321 1835 -3007 186 -1674 2025 -535 1773 891 423 4130 -1287 1004 -302 134 -599 2441 2293 2107 -361 -1974 1307 -1045 3742 -579 1877 740 1599 1402 -527 -1 -2415 -707 -4827 -1205 -3893 -436 -2582 -892 885 -812 2332 879 1585 -1360 1089 -775 -1556 -815 -1221 308 -115 1822 410 490 -1576 -1779 -2037 -1073 -945 -1530 412 -749 1085 532 1911 393 254 839 -834 207 -1652 776 -834 209 478 790 2135 590 925 -907 596 -94 108 -516 -536 -609 -543 516 -914 1379 41 782 181 -102 -896 -646 -406 -323 1045 -744 1035 -1044 -54 888 -420 624 -2629 223 -1181 557 301 -168 47 -1144 1003 -1552 836 72 765 -412 1187 -172 67 301 -1157 473 -589 1520 448 246 -1274 -454 -414 -934 765 -1005 1482 -987 433 -774 -1059 86 174 954 -1594 93 -865 1062 -307 1048 556 273 2610 -869 656 -196 86 -401 1703 1728 1668 -287 -1469 963 -777 2849 -470 1607 663 1407 1301 -460 -1 -1747 -483 -3633 -980 -3632 -430 -2759 -984 933 -928 2711 1062 1887 -1590 1258 -829 -1544 -788 -1258 345 -143 2436 526 673 -2059 -2147 -2370 -1289 -1221 -2092 577 -1108 1507 788 2910 607 374 1251 -1162 271 -2209 1061 -1241 325 752 1217 3147 842 1247 -1182 732 -118 144 -737 -801 -929 -845 828 -1574 2421 74 1441 334 -184 -1563 -1083 -670 SS 20240819T131553.4Z 8997.552702 341 1 2.07 2 54.53 106.92 130.43 284.29 0.00 1 0.00 1 0 17 1.009e-02 6.819e-03 3.915e-03 2.249e-03 2.335480e-01 1.168123e-03 2.823514e-03 -6.000000e+00 5.908845e-03 231.49 -2.00 3.54 -2.00 315.69 0.00e+00 3.543520e-04 1.175067e-04 3.181193e-05 -6.000000e+00 2.649865e-04 288.81 -2.00 20.00 -2.00 314.93 0.00e+00 1.718 0.000 302.00 328.00 3 2.1721e+00 3.0371e-03 2.1149e-02 -6.0000e+00 1.4775e-02 6.4484e-02 3.3853e-03 1.2253e-02 -6.0000e+00 1.5999e-02 -1.1249e-02 1.9307e-03 5.9334e-03 -6.0000e+00 9.5394e-03 1.9195e-03 8.6246e-04 1.6308e-03 -6.0000e+00 3.9983e-03 8.1074e-03 -5.6078e-05 6.5601e-05 2.1309e-05 -6.0000e+00 2.8535e-04 2.5602e-02 -7.9289e-06 12 9 1 12 1 1 96.63 19.16 0.25 0.02560 0.02518 7 37 1 5 0 257.510 22.29 15.02 19.16 29.59 0.0 986.50 376 -2131 -1760 -4227 -2610 -2974 -1396 91 -344 -1621 -2333 -1294 -488 1016 828 -455 566 1031 946 1462 759 751 1732 1080 1066 287 514 -771 164 1937 1422 1496 1288 -1524 -2797 -1529 -1498 -662 39 -962 -915 -760 -116 -1025 55 -609 -361 -269 -461 715 781 1038 524 1000 710 1122 71 147 240 673 1440 1124 1587 788 -444 -291 -483 710 692 411 30 12 244 276 -426 -131 -258 -139 22 -896 -1269 -1867 -2121 -1181 -1044 -454 -258 -20 100 -68 505 -25 584 957 559 383 887 436 -347 -465 -436 -693 414 100 -1087 -1071 -766 -646 -24 297 104 -16 307 95 322 586 400 296 201 -241 -206 -87 456 504 947 330 1144 1268 650 217 -52 -394 122 4 -9 -402 555 -133 -156 -397 -392 -477 -560 87 -542 -450 -1025 -604 -665 -325 23 -90 -446 -639 -361 -150 349 298 -180 230 430 381 604 320 314 734 484 500 139 246 -350 74 844 655 689 636 -780 -1364 -730 -783 -377 25 -668 -652 -563 -87 -783 42 -458 -264 -191 -338 522 568 802 408 809 592 948 61 126 202 563 1239 991 1503 752 -420 -265 -430 615 612 391 30 13 248 281 -405 -117 -219 -119 19 -826 -1250 -1937 -2342 -1301 -1181 -545 -312 -25 124 -83 593 -28 623 997 592 429 1051 547 -440 -598 -545 -803 476 120 -1373 -1370 -984 -866 -33 424 150 -23 435 129 417 745 511 383 268 -331 -287 -120 628 662 1219 423 1390 1561 823 293 -71 -551 173 6 -13 -615 863 -205 -240 -618 -588 -718 -832 SS 20240819T132556.2Z 8997.559678 344 1 50.51 2 52.76 109.03 132.11 286.37 0.00 1 0.00 1 0 17 8.880e-03 5.680e-03 1.566e-03 6.127e-04 2.236467e-01 3.146474e-04 2.691946e-03 -6.000000e+00 5.199620e-03 231.49 -2.00 3.54 -2.00 316.99 0.00e+00 3.945204e-04 4.194457e-05 6.885390e-05 -6.000000e+00 2.331555e-04 288.81 -2.00 20.00 -2.00 316.15 0.00e+00 1.648 0.000 302.00 328.00 3 2.2525e+00 8.3153e-04 2.0301e-02 -6.0000e+00 1.3002e-02 6.5345e-02 9.3272e-04 1.1784e-02 -6.0000e+00 1.4077e-02 -6.7615e-03 5.4245e-04 5.7039e-03 -6.0000e+00 8.3934e-03 -2.2524e-03 2.5773e-04 1.5678e-03 -6.0000e+00 3.5194e-03 8.1469e-03 2.3346e-04 1.8340e-05 1.8478e-05 -6.0000e+00 2.5097e-04 2.4225e-02 3.8084e-05 10 0 0 10 0 0 99.97 19.26 0.23 0.02423 0.02598 484 92 1 5 0 104.130 22.29 15.01 19.26 30.70 0.0 994.10 272 -1191 -1815 -2812 -3295 -484 -1065 1537 -989 -1356 -2605 -1361 -747 -373 421 -547 271 -163 1008 375 308 285 1084 900 313 617 -682 -128 -412 969 1025 1646 1186 -1917 -2342 -2206 -1658 -957 -145 -689 -826 -603 -590 -322 10 -119 -557 -202 -567 587 720 717 1052 720 870 855 776 102 531 589 1083 1373 1561 1139 -284 -83 -399 186 939 396 167 319 254 244 100 -317 -400 -509 -48 -823 -995 -1538 -2062 -1184 -899 -505 -226 196 320 123 423 157 329 722 512 242 775 478 -253 -433 -574 -650 -90 41 -992 -960 -723 -612 35 296 190 102 127 15 151 294 431 381 345 -251 -241 118 288 413 447 359 783 1306 514 254 -27 -222 168 69 1 -294 257 54 -238 -264 -308 -372 -486 40 -174 -296 -429 -452 -62 -145 228 -165 -236 -453 -240 -145 -82 103 -146 74 -46 293 113 94 86 333 290 106 215 -237 -41 -125 284 315 538 416 -698 -806 -751 -614 -411 -73 -368 -477 -362 -362 -198 6 -72 -331 -128 -351 361 464 447 687 493 610 610 561 74 375 416 788 1069 1306 1002 -248 -67 -298 135 726 346 159 313 248 228 87 -248 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