File name: Pandora153s1_ChelseaMA_20240827_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241015T152711.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20240827_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240827T104756.6Z 9005.449961 233 1 49.84 2 82.97 83.13 16.69 149.83 0.00 1 0.00 1 0 25 4.782e-01 3.419e-02 4.636e-01 3.356e-02 8.525925e-01 1.877445e-02 1.044864e-02 -6.000000e+00 2.738621e-01 230.79 -2.00 3.54 -2.00 322.06 0.00e+00 1.570108e-02 9.783729e-03 5.323939e-03 -6.000000e+00 1.319212e-02 288.18 -2.00 20.00 -2.00 321.50 0.00e+00 7.495 0.008 302.00 328.00 3 2.1800e+00 7.1437e-02 8.8646e-02 -6.0000e+00 6.8431e-01 1.3250e+00 8.7068e-02 4.6228e-02 -6.0000e+00 7.4286e-01 -1.5657e+00 5.7195e-02 2.5113e-02 -6.0000e+00 4.4225e-01 6.0452e-01 2.8716e-02 1.1728e-02 -6.0000e+00 1.8825e-01 1.2313e-05 -1.0065e-03 8.9321e-04 2.3110e-04 -6.0000e+00 1.2921e-02 2.2189e-02 0.0000e+00 12 8 8 10 0 0 2.95 18.45 0.76 0.02219 0.01463 19 4 1 5 0 2622.790 21.69 15.00 18.45 24.20 0.0 961.99 900000 -60904 43231 -11916 -18213 29161 -123921 -27318 139437 900000 -78719 -102857 -52152 23496 -9599 10135 76551 -21435 -9321 420 232604 35300 46548 -26040 59042 -25149 900000 -1250 32117 900000 -53388 -38831 -8048 164256 106261 68347 93077 -18926 16482 129647 33332 32421 199486 10762 76707 31485 -6198 126437 61357 30307 39977 37197 80215 33521 10050 45034 26389 30822 52809 -12614 18752 18975 43791 20027 1507 8426 8281 32553 -9358 37526 3280 21530 8060 30728 -4259 -17266 -2085 25261 -4115 644 1070 -7863 -1468 6017 2173 2315 -5985 6164 3652 -887 -4459 -3313 -1855 -9882 -11514 -2848 -1357 -4668 -681 -1797 532 -11405 -3277 -3979 -4192 4887 -690 -3627 -2843 957 -1274 3741 3950 -2859 459 -688 -2020 -900 -1878 2291 2666 1020 4286 2108 2567 58 -3111 2491 -673 1959 2504 2154 -2424 599 -731 616 303 -387 1713 -1042 -1847 -747 -798 900000 -4443 1414 -487 -645 954 -9352 -893 4560 900000 -3432 -6447 -2558 768 -497 497 2503 -1636 -635 25 7607 1251 1522 -1561 1931 -1371 900000 -48 1050 900000 -4801 -3598 -614 5372 3475 2235 3044 -1599 1123 4240 2271 2297 6524 968 3554 2317 -676 4135 3679 2643 3486 3649 5465 3837 1479 4664 3236 3444 4461 -1994 2249 2534 5251 3438 324 1653 1625 5234 -2550 7261 956 5281 2153 5945 -1033 -4235 -420 4130 -1065 193 347 -3185 -606 2422 962 1077 -3147 2915 1746 -422 -2042 -1417 -775 -4847 -6720 -1819 -1011 -4169 -633 -1673 446 -9497 -2292 -2853 -3237 3639 -579 -3431 -3025 1132 -1737 5176 5514 -4165 620 -920 -2820 -1315 -2934 3498 3923 1448 5672 2763 3241 73 -3975 3302 -1078 3519 4971 4618 -5799 1492 -1978 1712 856 -1112 4740 -2794 -4613 -1713 -1792 SS 20240827T105858.9Z 9005.457626 236 1 50.59 2 80.95 84.96 15.79 157.74 0.00 1 0.00 1 0 17 5.462e-01 1.619e-02 3.349e-01 8.557e-03 7.685850e-01 4.859087e-03 8.959436e-03 -6.000000e+00 3.169457e-01 230.79 -2.00 3.54 -2.00 321.88 0.00e+00 6.185127e-03 2.857719e-03 5.081252e-03 -6.000000e+00 1.549104e-02 288.18 -2.00 20.00 -2.00 321.30 0.00e+00 6.021 0.004 302.00 328.00 3 2.0641e+00 1.9356e-02 7.6391e-02 -6.0000e+00 7.9439e-01 3.4246e-01 2.7597e-02 5.0346e-02 -6.0000e+00 8.6452e-01 -4.5879e-01 2.6537e-02 2.6930e-02 -6.0000e+00 5.1175e-01 1.7688e-01 1.2076e-02 8.4488e-03 -6.0000e+00 2.1464e-01 7.6446e-05 -5.5100e-04 2.4078e-04 1.4967e-04 -6.0000e+00 1.4956e-02 2.2028e-02 0.0000e+00 12 8 8 10 0 0 16.11 18.48 0.57 0.02203 0.01789 59 11 1 5 0 857.400 21.69 15.00 18.48 24.53 0.0 963.33 -150413 -15433 -213437 900000 -210648 900000 -211349 -80383 900000 -208607 900000 -201883 93464 -145808 900000 -87613 900000 78143 -49055 74070 -48938 -16024 -111296 900000 -81580 32007 -11045 8206 67007 -46863 91544 -36808 136983 -59252 72128 -37889 48272 43989 3571 22011 -1617 33834 -1303 57989 -15687 26348 -4441 30508 17806 7819 46068 14400 26280 6255 19880 6418 14165 11207 1181 12926 5261 20432 10969 10742 796 5852 2885 3229 11402 3321 7224 2129 8234 -2503 4377 -3119 -552 -3569 -3428 4049 -4695 3210 -2356 441 -2519 2628 686 103 2421 -417 3316 -3661 -207 -3310 -1406 -3264 -651 880 -1704 669 -2849 -1266 -4597 -175 -2777 -905 122 -1170 672 -1448 1472 178 1196 -562 -484 -769 -765 1335 -48 1270 -296 1571 497 1093 289 170 709 602 990 25 1216 -1225 -207 -322 -161 67 237 841 -271 730 -795 -115 -1267 -1253 -129 -3719 900000 -3032 900000 -3202 -670 900000 -3951 900000 -4436 779 -3203 900000 -1659 900000 651 -855 617 -890 -206 -3879 900000 -2410 315 -167 99 558 -1136 763 -1227 1142 -3008 929 -1464 878 1000 149 900 -93 1461 -84 2109 -1212 1377 -326 1664 1174 622 2827 1250 2227 704 2057 789 1643 1315 148 1418 654 2455 1676 1865 160 1097 561 662 2439 888 2022 645 2276 -714 1049 -723 -120 -843 -945 1251 -1865 1349 -1142 220 -1387 1460 407 63 1426 -241 1720 -1925 -104 -1837 -886 -2471 -562 794 -1701 643 -2617 -1103 -3818 -143 -2509 -846 120 -1169 738 -1854 2041 264 1760 -814 -667 -1034 -1054 1903 -73 1962 -451 2244 692 1464 377 214 873 806 1526 44 2343 -2583 -459 -766 -409 176 638 2274 -730 1846 -1903 -257 -2808 SS 20240827T111030.1Z 9005.465627 241 1 50.47 2 78.83 86.88 15.15 166.77 0.00 1 0.00 1 0 17 4.315e-01 9.482e-03 1.876e-01 3.307e-03 6.637847e-01 1.778120e-03 7.544501e-03 -6.000000e+00 2.464141e-01 230.79 -2.00 3.54 -2.00 321.39 0.00e+00 1.443790e-03 9.182452e-04 2.899642e-03 -6.000000e+00 1.110121e-02 288.18 -2.00 20.00 -2.00 320.76 0.00e+00 4.978 0.002 302.00 328.00 3 1.8400e+00 6.4496e-03 6.2693e-02 -6.0000e+00 6.1560e-01 6.7866e-02 8.9299e-03 4.0343e-02 -6.0000e+00 6.6807e-01 -1.2396e-01 8.6812e-03 1.9714e-02 -6.0000e+00 3.9822e-01 4.4505e-02 4.0761e-03 5.2387e-03 -6.0000e+00 1.6893e-01 3.0064e-04 -1.9743e-04 9.3068e-05 8.4066e-05 -6.0000e+00 1.1513e-02 2.1507e-02 0.0000e+00 12 8 8 10 0 0 24.30 18.52 0.34 0.02151 0.02002 130 25 1 5 0 388.200 21.79 15.01 18.52 25.28 0.0 967.91 900000 -199838 -64050 -195747 -76695 -202881 -144096 -125763 -138874 5149 -152131 77364 -99139 43056 -90515 -39651 -9504 -41155 11599 -43971 -11080 -57571 24673 -30403 -13630 -14662 -28433 -14607 -52761 11405 -29580 4590 -12745 1389 -6613 -6819 276 -15644 9181 -6676 5320 -4896 12606 3213 7408 4721 4646 6546 -1805 6098 -65 9761 2527 6624 3878 2100 6467 912 5915 -1226 4371 -373 7842 2457 3167 2423 -1527 2017 582 4486 1459 3045 450 2267 64 -1414 -1120 -2982 -525 -2529 101 -1877 -1343 -1455 -1170 -5 139 938 503 1715 -729 646 -1821 -936 -509 -548 214 427 495 -637 -807 -2275 -1119 -899 -1650 -948 -1377 -780 9 842 508 962 323 -140 -250 -566 -159 -404 599 150 541 169 728 878 196 79 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