File name: Pandora153s1_ChelseaMA_20240901_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240902T045113.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240901_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240901T111403.4Z 9010.468094 120 1 50.11 2 79.08 89.10 61.82 91.86 0.00 1 0.00 1 0 25 4.312e-01 1.177e-02 1.868e-01 6.181e-03 6.485447e-01 3.363281e-03 7.352479e-03 -6.000000e+00 2.530211e-01 230.35 -2.00 3.54 -2.00 321.33 0.00e+00 2.412447e-04 1.689088e-03 1.579410e-03 -6.000000e+00 1.128787e-02 287.78 -2.00 20.00 -2.00 320.69 0.00e+00 5.084 0.002 302.00 328.00 3 2.2235e+00 1.1965e-02 6.2010e-02 -6.0000e+00 6.3136e-01 1.8583e-01 1.6104e-02 3.6824e-02 -6.0000e+00 6.8488e-01 -2.1280e-01 1.4571e-02 1.7984e-02 -6.0000e+00 4.0697e-01 8.1852e-02 6.8573e-03 4.9043e-03 -6.0000e+00 1.6996e-01 1.8026e-04 -7.0129e-04 1.8223e-04 6.8587e-05 -6.0000e+00 1.2333e-02 2.9910e-02 -5.4559e-05 12 8 8 10 0 0 99.27 19.06 0.41 0.02991 0.02464 44 8 1 5 0 1138.650 22.19 15.00 19.06 27.86 0.0 979.07 -165690 -188511 65263 -138242 -120298 -150515 900000 -169336 -159944 -98231 -105552 -107365 -107671 -12189 -68951 -47116 -67490 24536 6605 -37418 13363 -62120 16647 -27869 17786 -44806 -2944 -62267 -32354 -8439 -14530 407 -17648 13497 -23392 6469 -16664 9530 1905 5954 6237 1874 10470 -3350 8681 2642 6748 8813 11792 7043 4313 11795 6769 6138 2616 12318 8886 2697 6037 64 8548 4491 9219 4408 6339 1331 6841 4755 791 1258 818 5675 499 3399 -345 -637 -1553 -2727 533 -1120 -1313 -4056 -938 -3494 -1043 -885 -78 -1054 1137 1751 455 339 -1956 -347 -2052 -203 69 142 -424 -892 -846 -1749 -901 -994 -872 -1727 -1078 -753 -186 824 -46 876 137 600 16 17 -43 -6 127 -297 310 431 1176 -122 676 -165 844 1311 193 678 -68 4 230 -159 -623 152 275 71 265 -528 -37 -449 -383 -2270 -3718 393 -1666 -1233 -1897 900000 -3247 -3155 -1243 -1527 -1812 -2271 -125 -1538 -994 -1952 311 107 -992 217 -2171 281 -806 354 -1755 -76 -2815 -1072 -239 -517 15 -872 512 -1241 257 -934 494 131 466 545 183 978 -365 848 279 695 919 1251 845 539 1525 1009 999 467 2085 1597 511 1075 12 1527 923 2046 1137 1660 358 1732 1284 248 450 320 2192 199 1236 -118 -198 -460 -843 181 -455 -622 -2240 -547 -2222 -693 -624 -57 -798 834 1220 299 210 -1204 -221 -1494 -167 66 153 -490 -1020 -900 -1697 -810 -916 -861 -1815 -1193 -892 -242 1181 -73 1436 224 940 24 24 -63 -10 206 -500 511 683 1787 -181 955 -226 1124 1848 310 1210 -134 9 500 -370 -1423 359 664 174 640 -1227 -87 -1013 -850 SS 20240901T111930.9Z 9010.471886 123 1 25.43 2 78.07 90.02 60.85 92.79 0.00 1 0.00 1 0 17 3.616e-01 1.726e-02 2.638e-01 1.092e-02 5.990266e-01 5.861820e-03 7.156916e-03 -6.000000e+00 2.107191e-01 230.35 -2.00 3.54 -2.00 320.94 0.00e+00 2.165141e-03 2.603248e-03 4.013195e-03 -6.000000e+00 1.017839e-02 287.78 -2.00 20.00 -2.00 320.28 0.00e+00 4.688 0.002 302.00 328.00 3 3.3298e+00 1.9498e-02 5.9629e-02 -6.0000e+00 5.2562e-01 1.9300e-01 2.5145e-02 4.0619e-02 -6.0000e+00 5.7008e-01 -2.4201e-01 2.1883e-02 1.8314e-02 -6.0000e+00 3.4022e-01 1.1279e-01 1.0647e-02 4.3696e-03 -6.0000e+00 1.4419e-01 8.9895e-05 -2.3493e-04 3.2181e-04 8.7717e-05 -6.0000e+00 1.0441e-02 3.0033e-02 -3.1748e-05 12 9 9 12 1 1 99.98 19.08 0.27 0.03003 0.02827 11 5 1 5 0 2118.330 22.19 15.00 19.08 28.10 0.0 980.32 -112850 900000 -140296 900000 -77790 -111764 115523 -132893 46157 -81303 900000 -165132 -43354 -69898 4501 37906 -70334 87474 -51356 28704 -7514 119413 -45504 4691 14471 6464 62343 -20454 43111 -41791 39721 -23591 12448 5380 14092 -18335 -3417 9798 -6879 20689 -2313 27779 1745 26654 -2075 -9177 836 -2051 12166 -5657 12113 11181 9169 9856 19143 18976 1123 9708 -4601 10485 -1091 7254 6643 1919 2833 1986 3800 2627 2634 1150 3099 2546 6618 1254 -7894 744 -7437 3320 -1233 2777 -5113 -591 -2944 -1998 -1087 -3213 1082 -3309 1844 658 1108 -1512 -1445 -706 -2177 -1153 -51 1271 -1506 242 -1978 -333 -1678 -1922 -482 -1746 651 -1268 689 521 1094 169 555 854 -1663 -25 -513 1005 -79 434 1095 858 840 353 1169 -150 796 94 1013 -354 -644 -473 -314 25 -540 493 209 1201 -431 -22 -582 -309 -942 -1965 900000 -3801 900000 -978 -1946 1230 -3472 491 -1495 900000 -8308 -797 -2097 78 550 -3335 1024 -2335 611 -233 1271 -2157 145 434 219 1327 -871 1055 -2345 1268 -1506 626 302 695 -1260 -225 673 -679 1822 -284 2688 228 2759 -289 -1394 116 -302 1613 -958 1899 1958 1783 2050 3816 3929 284 2226 -1184 2303 -281 1895 1967 601 902 618 1250 908 927 468 1347 1150 2812 528 -3319 282 -2885 1185 -519 1209 -2789 -348 -1922 -1372 -792 -2542 859 -2805 1472 508 792 -1038 -959 -485 -1699 -1026 -52 1430 -1852 288 -2235 -335 -1608 -1898 -503 -1948 750 -1598 933 783 1780 266 931 1363 -2566 -37 -768 1556 -132 738 1829 1387 1311 532 1675 -210 1077 136 1618 -635 -1159 -895 -622 52 -1209 1139 493 2845 -1025 -49 -1245 -626 -1889 SS 20240901T112355.2Z 9010.474945 126 1 12.89 2 77.26 90.76 60.07 93.55 0.00 1 0.00 1 0 25 2.857e-01 1.185e-02 1.472e-01 6.035e-03 5.711758e-01 3.175447e-03 6.664089e-03 -6.000000e+00 1.664679e-01 230.35 -2.00 3.54 -2.00 320.48 0.00e+00 2.591333e-03 1.226180e-03 1.493572e-03 -6.000000e+00 7.465880e-03 287.78 -2.00 20.00 -2.00 319.76 0.00e+00 4.411 0.002 302.00 328.00 3 2.3956e+00 9.8587e-03 5.3650e-02 -6.0000e+00 4.1522e-01 1.3776e-01 1.2342e-02 3.1044e-02 -6.0000e+00 4.5021e-01 -1.3843e-01 1.0535e-02 1.5589e-02 -6.0000e+00 2.6852e-01 4.9241e-02 5.2613e-03 4.6088e-03 -6.0000e+00 1.1261e-01 3.0970e-04 -5.0973e-04 1.7444e-04 6.2456e-05 -6.0000e+00 8.0751e-03 2.9259e-02 -4.1242e-05 12 9 9 12 1 1 97.83 19.09 0.36 0.02926 0.02543 11 9 1 5 0 1073.910 22.19 15.01 19.09 28.33 0.0 981.52 -86480 -56318 -75232 -83049 -145704 -59934 -151817 34616 -115299 -17045 -71073 -74048 -45348 -53254 -9544 -32874 29295 -28432 34845 -25952 -1389 -23482 -3773 16470 -30691 15384 -31314 2631 -18903 7646 -5383 702 -5722 -7241 16304 -19677 6973 -5677 4479 2023 6499 3911 4339 9194 -3763 7718 -3900 7251 372 7080 5059 3138 2936 2191 8181 -1134 7065 1014 3195 2118 4678 2150 2823 6065 1260 1841 61 3207 -370 1239 2249 2213 521 295 704 -3856 -245 -2310 -2039 -1736 -1361 -688 -3651 -999 -3045 132 -297 981 45 -651 226 -613 -309 -967 -135 -1241 678 225 926 -273 -1160 -513 -859 -652 -2279 -596 -1359 -304 779 215 347 278 945 429 234 70 270 -190 241 -246 -409 44 603 759 1105 256 771 1735 515 -179 90 -311 248 -499 295 -129 -148 18 -385 -253 -451 -7 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