File name: Pandora153s1_ChelseaMA_20240904_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240905T045513.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240904_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240904T104623.4Z 9013.448882 53 1 49.80 2 84.73 85.45 99.39 79.61 0.00 1 0.00 1 0 17 4.875e-01 6.061e-02 4.564e-01 6.616e-02 9.768897e-01 3.672462e-02 1.070314e-02 -6.000000e+00 2.838834e-01 230.09 -2.00 3.54 -2.00 321.50 0.00e+00 -2.999841e-03 1.190576e-02 2.949403e-03 -6.000000e+00 1.353026e-02 287.54 -2.00 20.00 -2.00 320.76 0.00e+00 9.429 0.016 302.00 328.00 3 1.6622e-01 1.1478e-01 1.0819e-01 -6.0000e+00 7.0681e-01 2.3214e+00 1.3591e-01 5.3834e-02 -6.0000e+00 7.6732e-01 -2.0647e+00 7.6835e-02 2.4103e-02 -6.0000e+00 4.5776e-01 6.7496e-01 4.0430e-02 7.2920e-03 -6.0000e+00 1.9180e-01 9.4023e-06 9.1518e-04 1.6627e-03 8.5071e-05 -6.0000e+00 1.3915e-02 4.2947e-02 -4.0098e-05 12 8 8 10 0 0 -125.01 17.81 1.98 0.04295 0.04982 15 3 1 5 0 3319.730 21.17 15.00 17.81 19.80 0.0 941.58 134151 13876 137923 -16305 57199 -58760 10000 -53209 -80735 -28388 56954 900000 50681 306211 14412 42940 24343 34416 215178 123514 -17640 43484 35739 62736 53964 -1526 900000 -33713 5570 -212 62067 5183 -41263 -29424 -47144 27795 89807 116527 16916 177 101864 23882 29413 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4.1274e-02 1.7952e-06 12 8 8 10 0 0 -4.38 17.83 0.64 0.04127 0.03419 62 12 1 5 0 817.870 21.17 15.00 17.83 20.15 0.0 943.25 105050 -109736 900000 -157806 -44197 -146666 -63557 -126583 -100604 8388 -132973 -91447 -109163 -11234 -35373 -33228 -11312 26863 306740 -49747 900000 -26555 225014 -59782 900000 -71461 34628 -13659 -22629 4231 -30837 157167 -30506 40162 -7639 39842 9906 8139 30330 -12524 45309 3466 121654 24710 52814 30622 26084 28072 19722 35395 16775 71148 10998 45926 29750 40951 19231 14641 24263 6579 48001 5361 31217 16717 20282 17818 11410 17952 14893 20574 6818 22046 2926 12139 -3168 -2036 -5468 -11977 -566 -2646 4203 -3395 6928 803 2387 -3245 -621 4646 -1195 5096 -2338 1180 -4659 -5215 -5501 -4337 320 -2475 175 -4309 -1773 -2576 -3387 -2565 -3467 -2046 -2086 -504 -1496 1809 -2378 -292 -1828 -313 -1321 -326 780 -918 719 609 2353 1647 2290 2836 2265 1196 299 2064 -12 1100 -689 777 351 -715 585 -17 890 148 211 -349 -204 -1558 -1609 1312 -3489 900000 -7169 -552 -4664 -866 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287.54 -2.00 20.00 -2.00 321.14 0.00e+00 5.890 0.004 302.00 328.00 3 4.2646e-01 8.2370e-03 7.4320e-02 -6.0000e+00 8.8173e-01 2.6302e-01 1.1578e-02 4.9159e-02 -6.0000e+00 9.5686e-01 -3.2825e-01 1.0928e-02 2.6381e-02 -6.0000e+00 5.7071e-01 1.2972e-01 4.9946e-03 8.3049e-03 -6.0000e+00 2.3890e-01 4.6504e-04 -5.4240e-04 1.1081e-04 1.7271e-04 -6.0000e+00 1.7209e-02 4.1891e-02 -4.8972e-05 12 8 8 10 0 0 -12.59 17.86 0.41 0.04189 0.03781 171 32 1 5 0 295.720 21.17 15.00 17.86 20.43 0.0 944.12 -197818 -172958 -205525 -202552 -245758 -165862 -202696 -131162 -191592 -169664 -188842 -153470 -98178 -137809 -73916 -93297 784 -76820 -54510 -32636 -36410 -49336 -63244 -32265 -54514 -31299 -50385 -47121 -48944 -47536 -22280 -30560 -615 -13609 -5453 -22424 -10197 -9113 6699 12714 -7104 7693 5497 16220 6162 13965 5429 17405 2736 12104 16440 7903 13852 10464 14986 9467 12683 5332 6006 3286 5400 10082 8916 11986 6319 7826 4996 6603 4839 5634 5089 2714 5238 -16 1598 -1358 -630 -36 -426 1368 17 -1072 -2409 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