File name: Pandora153s1_ChelseaMA_20240911_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241015T154044.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20240911_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240911T110259.1Z 9020.460407 57 1 51.28 2 83.00 90.61 165.50 18.14 0.00 1 0.00 1 0 17 4.905e-01 3.469e-02 4.704e-01 3.365e-02 8.463251e-01 1.903654e-02 9.708393e-03 -6.000000e+00 2.828845e-01 229.47 -2.00 3.54 -2.00 322.02 0.00e+00 -3.703685e-03 1.011347e-02 1.163533e-02 -6.000000e+00 1.405647e-02 286.98 -2.00 20.00 -2.00 321.45 0.00e+00 7.516 0.008 302.00 328.00 3 2.2758e+00 7.3403e-02 1.1405e-01 -6.0000e+00 7.1088e-01 1.0477e+00 9.4967e-02 1.1110e-01 -6.0000e+00 7.7596e-01 -1.3246e+00 7.0799e-02 3.7952e-02 -6.0000e+00 4.5740e-01 5.4404e-01 3.3567e-02 9.2136e-03 -6.0000e+00 1.9234e-01 1.2487e-05 -1.3011e-03 9.1878e-04 1.1794e-04 -6.0000e+00 1.3616e-02 2.8177e-02 0.0000e+00 12 8 8 10 0 0 28.45 17.66 0.77 0.02818 0.01840 17 3 1 5 0 3015.840 21.06 15.00 17.66 18.57 0.0 936.13 -70068 -7737 900000 900000 -94515 100487 -89460 900000 900000 -39117 900000 -88512 24140 -71947 45553 85530 -6851 900000 165503 900000 11969 83778 -51983 9557 -39353 -42808 163821 -41126 -116813 55493 40381 46897 6822 112475 -28011 30641 -22950 -24054 38775 3798 -4562 70682 25248 -8924 220575 2219 93540 1591 59863 -39398 221648 67023 32031 58616 51959 13956 24391 77262 6504 55620 -13796 23881 16697 -4315 26815 19818 38709 14800 29792 12429 5830 21967 10968 7019 -4991 23292 -5099 -7489 -5345 25342 8924 1066 1539 -4567 5914 -4310 7242 2027 3093 -5418 2201 -710 -14147 -12735 -4822 -136 -4722 4718 -3449 -2124 -2994 -12298 -3928 -9774 122 -1357 -1455 343 2798 -2166 -720 523 380 4375 -651 -641 -400 1268 1301 -39 2165 1661 2280 1108 3850 -1825 2199 3085 804 33 106 -1225 -2739 -820 1107 1401 716 -361 619 1 -1257 56 -1701 -2827 -254 900000 900000 -3574 3294 -3158 900000 900000 -1282 900000 -4017 791 -3991 1493 2803 -276 900000 5425 900000 392 2746 -3146 337 -2381 -2698 5370 -2177 -12370 1819 1324 1537 344 3687 -1836 1172 -1504 -1880 1955 316 -449 3386 1910 -923 7230 196 3577 144 3434 -6059 7265 4394 3230 4877 4847 1970 3136 5649 902 4488 -2261 2950 2526 -903 4259 3298 5368 2761 5408 3071 1661 5428 2904 1770 -1258 3935 -1093 -1737 -1415 5942 2902 399 627 -2096 2603 -2220 3459 1034 1535 -2778 974 -331 -6988 -6738 -2743 -87 -3715 3888 -3327 -1994 -2614 -10452 -2824 -7643 93 -1109 -1267 319 2876 -2692 -993 759 559 6023 -902 -868 -553 1819 1970 -60 3198 2342 3080 1469 4804 -2328 2662 4052 1259 59 212 -2665 -6444 -2033 2884 3785 1976 -1013 1684 3 -3026 124 -3739 SS 20240911T111407.1Z 9020.468137 60 1 50.15 2 80.94 92.50 164.76 26.74 0.00 1 0.00 1 0 17 5.169e-01 1.349e-02 2.663e-01 7.575e-03 7.495243e-01 4.123531e-03 8.686796e-03 -6.000000e+00 2.942632e-01 229.47 -2.00 3.54 -2.00 321.78 0.00e+00 4.953207e-03 2.333992e-03 4.367653e-03 -6.000000e+00 1.335429e-02 286.98 -2.00 20.00 -2.00 321.20 0.00e+00 6.019 0.004 302.00 328.00 3 1.9511e+00 1.5872e-02 7.4718e-02 -6.0000e+00 7.3491e-01 3.3902e-01 2.2248e-02 4.7257e-02 -6.0000e+00 7.9921e-01 -4.2069e-01 2.1179e-02 2.5111e-02 -6.0000e+00 4.7463e-01 1.6241e-01 9.7282e-03 7.7825e-03 -6.0000e+00 1.9980e-01 8.7113e-05 -6.9330e-04 2.0841e-04 1.4000e-04 -6.0000e+00 1.3749e-02 2.8230e-02 0.0000e+00 12 8 8 10 0 0 81.21 17.69 0.35 0.02823 0.02302 56 11 1 5 0 895.350 21.06 15.00 17.69 19.10 0.0 938.71 -167321 -228776 -101250 -181706 -143967 -166158 -121120 -174453 900000 -138095 -113916 -166268 -149219 -92130 -84176 43590 -88406 -40254 -21072 -33000 -16768 -73353 -29139 -84763 5516 -78504 -40016 -43437 -39642 -29796 -16405 10786 -15077 4885 -20602 10926 -19180 11166 14810 15716 12590 6195 22552 4836 11136 20964 32782 8026 2728 21921 6844 10900 26417 20984 7043 9056 6556 15154 7196 6854 9469 800 6629 -72 9962 7322 2710 164 9003 4386 3883 6663 5827 1446 -389 595 -4285 -4435 -2064 -2481 -1062 -1745 824 -1507 483 -509 74 -867 506 -36 -387 -1893 -772 -2419 -4963 9 -10 751 -593 -416 -2022 -2088 -1293 -2278 -893 -2057 -339 -540 93 554 197 342 335 -513 -570 -318 -405 266 581 249 985 521 1718 36 1528 -211 585 660 207 654 98 -155 -667 -505 -109 248 394 801 231 -153 -185 -847 -721 -1797 -5223 -748 -2562 -1257 -1785 -895 -2460 900000 -1576 -1071 -3126 -3106 -1423 -1526 322 -2256 -703 -325 -598 -259 -1970 -528 -2902 81 -2794 -967 -1050 -932 -720 -430 261 -547 151 -775 301 -798 412 646 802 735 377 1332 318 699 1337 1915 578 220 1592 653 1120 2553 2325 945 1237 936 1949 965 911 1288 134 1204 -16 2054 1519 592 39 2217 1301 1257 2153 1840 442 -109 148 -1076 -1179 -626 -910 -451 -786 394 -782 263 -297 45 -541 307 -21 -210 -987 -425 -1344 -3268 7 -9 735 -631 -433 -1972 -1813 -1032 -1895 -789 -1938 -334 -577 111 746 295 540 527 -785 -830 -450 -587 404 933 409 1564 793 2493 51 2073 -281 760 932 339 1208 200 -336 -1545 -1250 -268 629 1019 2084 595 -374 -455 -1966 -1650 SS 20240911T112458.0Z 9020.475671 65 1 50.32 2 78.95 94.35 163.80 34.32 0.00 1 0.00 1 0 17 4.219e-01 8.040e-03 1.013e-01 2.875e-03 6.459135e-01 1.529330e-03 7.290685e-03 -6.000000e+00 2.395298e-01 229.47 -2.00 3.54 -2.00 321.25 0.00e+00 2.199999e-03 7.598449e-04 1.642717e-03 -6.000000e+00 1.073242e-02 286.98 -2.00 20.00 -2.00 320.62 0.00e+00 5.027 0.002 302.00 328.00 3 1.5897e+00 5.3863e-03 6.1122e-02 -6.0000e+00 5.9673e-01 7.7985e-02 7.3110e-03 3.5694e-02 -6.0000e+00 6.4840e-01 -9.5787e-02 7.0200e-03 1.8414e-02 -6.0000e+00 3.8663e-01 3.0352e-02 3.3280e-03 5.6875e-03 -6.0000e+00 1.6306e-01 3.7157e-04 -2.0562e-04 8.0680e-05 7.7274e-05 -6.0000e+00 1.1190e-02 2.7573e-02 0.0000e+00 11 8 0 10 0 0 84.24 17.72 0.29 0.02757 0.02603 142 27 1 5 0 354.330 21.06 15.00 17.72 19.76 0.0 942.29 -146164 -175191 -131346 -113778 -157507 -167927 -180669 -75187 -127378 -117618 -94330 -93715 -75338 -56300 -15191 -55346 -30026 -31695 -37176 -18153 -13172 -12438 -14053 -6727 -33643 -8779 -35421 -11444 -18875 -18966 -16165 -7388 -6501 -7878 -8533 -14569 -172 -285 3850 5692 2280 2988 3618 6229 3407 3702 1905 2979 984 4128 2899 4831 5417 2631 5816 1534 4101 2271 1925 1530 2798 3262 3917 4001 -457 1417 -989 -241 915 2080 1846 2015 1048 517 -361 -2500 -2120 -2339 -1286 -1143 -704 -877 -2110 -973 -652 -350 291 1038 853 1376 419 -530 -620 -516 -554 -705 601 614 508 456 -1081 -1669 -1854 -447 -1292 -868 -1550 -558 -171 475 807 534 443 -499 -300 -396 -252 -54 222 86 -27 522 584 851 533 -37 207 544 407 135 68 -515 -234 -127 -13 -326 463 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