File name: Pandora153s1_ChelseaMA_20241019_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241020T043711.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20241019_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20241019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241019T114015.5Z 9058.486290 237 1 49.54 2 84.13 109.64 69.44 281.70 0.00 1 0.00 1 0 17 3.865e-01 3.061e-02 3.972e-01 3.039e-02 8.659780e-01 1.758275e-02 9.947930e-03 -6.000000e+00 2.198025e-01 225.27 -2.00 3.54 -2.00 322.04 0.00e+00 -8.891501e-03 8.265101e-03 7.914801e-03 -6.000000e+00 1.009295e-02 282.43 -2.00 20.00 -2.00 321.54 0.00e+00 8.692 0.012 302.00 328.00 3 1.0479e+00 6.2895e-02 1.1154e-01 -6.0000e+00 5.4367e-01 1.2963e+00 7.8715e-02 8.8978e-02 -6.0000e+00 5.8974e-01 -1.6355e+00 5.8090e-02 3.0840e-02 -6.0000e+00 3.5203e-01 6.4916e-01 2.8826e-02 1.1543e-02 -6.0000e+00 1.5471e-01 1.4124e-05 -1.1107e-03 8.5204e-04 1.0288e-04 -6.0000e+00 1.0457e-02 3.5643e-02 0.0000e+00 12 8 8 10 0 0 -6.14 17.26 0.86 0.03564 0.02730 24 5 1 5 0 2063.720 20.77 15.02 17.26 12.04 0.3 907.34 -15265 900000 -17399 900000 -49653 94288 -94759 -66118 -10284 -63328 -72730 -44061 66578 24814 -12108 130206 7840 134548 48129 900000 81078 155880 900000 43292 29153 -17511 26997 -55859 -1729 -72261 29824 -12051 59090 -11739 21937 -32645 -27655 92547 18052 29097 55415 66027 96105 38570 58512 -1304 80947 13254 80356 -9820 20320 12629 24970 101380 15474 27031 27724 57691 -3747 17480 9398 12298 15564 6898 36385 10014 31166 -5573 8274 17628 11430 19080 5863 10469 -2186 -1626 -13240 5906 -706 6118 5913 3284 -114 -8940 -1057 -6356 -640 6683 2917 1662 4674 -7415 3591 -3322 -8009 -1704 412 -2472 -2932 -3637 -4400 -6566 -1470 -7397 537 -7938 -2447 -6941 4500 -20 -770 1785 -1477 2238 -2844 2308 -1769 1097 1654 2775 1977 2040 4225 -928 5935 -807 -780 -192 2882 781 -697 376 -1684 210 -1638 797 949 810 495 306 -1715 -1981 900000 -753 900000 -816 900000 -2205 2792 -6546 -3752 -355 -3750 -4666 -2283 1971 935 -687 3855 443 3984 1814 900000 2401 4615 900000 1631 1334 -1273 1163 -4811 -79 -7002 1204 -843 2227 -885 1063 -2636 -2308 2740 1361 2271 3580 3910 4139 2803 3307 -130 3486 1142 3677 -1189 2024 1496 2823 5730 2166 3492 3582 5280 -585 2070 1214 1688 2346 1263 5093 1779 4530 -1245 1826 4033 2984 4673 1562 2423 -506 -333 -2922 1145 -171 1663 1894 1134 -44 -4037 -469 -3136 -309 3034 1346 734 1868 -3201 1527 -1524 -4505 -1064 295 -2092 -2677 -3284 -3680 -4973 -979 -5402 391 -6639 -2071 -6731 4430 -23 -1043 2515 -2179 3109 -3993 3018 -2480 1578 2498 4197 2907 2849 5587 -1258 7292 -1028 -989 -268 4580 1455 -1463 839 -4110 543 -4621 2278 2749 2365 1419 824 -4345 -4681 900000 SS 20241019T114228.5Z 9058.487830 239 1 50.49 2 83.75 110.03 69.82 282.03 0.00 1 0.00 1 0 17 4.056e-01 2.261e-02 4.771e-01 2.324e-02 8.732948e-01 1.354905e-02 1.010360e-02 -6.000000e+00 2.332684e-01 225.27 -2.00 3.54 -2.00 322.12 0.00e+00 -4.753031e-04 7.527076e-03 5.595532e-03 -6.000000e+00 1.029281e-02 282.43 -2.00 20.00 -2.00 321.68 0.00e+00 8.262 0.011 302.00 328.00 3 1.0924e+00 5.2131e-02 1.0025e-01 -6.0000e+00 5.7782e-01 9.5924e-01 6.8977e-02 6.3550e-02 -6.0000e+00 6.2800e-01 -1.1946e+00 6.1025e-02 2.8795e-02 -6.0000e+00 3.7494e-01 4.7573e-01 2.8921e-02 8.2774e-03 -6.0000e+00 1.6347e-01 2.0491e-05 -1.4786e-03 6.4821e-04 1.2721e-04 -6.0000e+00 1.1056e-02 3.5203e-02 0.0000e+00 12 9 8 11 8 0 27.99 17.26 0.79 0.03520 0.02409 32 6 1 5 0 1577.700 20.77 15.00 17.26 12.16 0.3 907.84 900000 -97030 -41627 -85687 50810 -152283 -148651 -21266 -64949 -89567 -91601 -54848 -66301 900000 -62002 900000 900000 -57276 37445 -78392 57878 -28663 -28981 44181 -61654 -30099 23168 -67067 -10722 138 -85056 25950 14846 118988 -21421 -38915 900000 14529 3785 -21474 63538 50998 123407 125113 59808 2820 35696 -707 3298 40755 3504 19516 35386 41608 57232 77404 13716 25194 3047 23729 4435 4538 12548 11525 9034 27912 23231 21087 17921 7195 9420 21229 6146 18243 18221 -8221 8994 -8963 -1447 -829 -1394 -121 4929 3964 -4472 1850 1244 7014 -889 4336 765 -8292 665 -7947 -6884 -3794 -655 1514 -1258 -2647 -2089 -5384 -3633 -3926 -2050 -4588 -3840 -3526 -1262 -102 -987 1221 870 457 -608 -474 -684 332 1609 1385 2355 2311 502 1001 1706 913 -1506 2636 2459 1324 75 -1514 86 606 -296 -534 361 -648 130 871 -853 -1221 900000 900000 -2197 -943 -1940 1150 -4031 -3984 -482 -1471 -2028 -2074 -1242 -1501 900000 -1854 900000 900000 -2149 848 -3682 1310 -763 -801 1000 -2635 -962 525 -2715 -245 3 -5329 656 474 2694 -900 -1903 900000 544 190 -1590 2264 2148 2794 2833 2275 185 1735 -51 241 2260 310 1640 2789 3330 4147 4782 1569 2498 351 2166 501 565 1664 1733 1452 3687 3271 3214 3183 1616 2214 4542 1463 3540 3156 -1645 1487 -1875 -332 -228 -448 -44 1868 1598 -2073 850 598 3251 -435 1923 331 -3751 277 -3934 -3931 -2480 -488 1266 -1167 -2450 -1767 -4188 -2572 -2865 -1570 -3804 -3378 -3387 -1341 -123 -1357 1742 1262 650 -845 -645 -959 487 2457 2145 3479 3262 696 1343 2206 1161 -1952 3602 3928 2460 155 -3417 203 1532 -809 -1511 1035 -1888 369 2314 -2128 -2864 900000 SS 20241019T114700.9Z 9058.490983 242 1 50.03 2 82.97 110.83 70.60 282.71 0.00 1 0.00 1 0 17 5.038e-01 2.118e-02 3.376e-01 1.268e-02 8.228000e-01 7.224363e-03 9.589108e-03 -6.000000e+00 2.893300e-01 225.27 -2.00 3.54 -2.00 321.98 0.00e+00 5.040745e-04 3.989343e-03 5.725391e-03 -6.000000e+00 1.286845e-02 282.43 -2.00 20.00 -2.00 321.52 0.00e+00 7.495 0.008 302.00 328.00 3 1.1452e+00 2.7467e-02 9.2270e-02 -6.0000e+00 7.1765e-01 7.1702e-01 3.7414e-02 6.0927e-02 -6.0000e+00 7.7918e-01 -9.4686e-01 3.4282e-02 2.8683e-02 -6.0000e+00 4.6072e-01 3.8145e-01 1.5982e-02 7.8077e-03 -6.0000e+00 1.9949e-01 4.4363e-05 -1.0608e-03 3.5256e-04 1.3274e-04 -6.0000e+00 1.3612e-02 3.5419e-02 0.0000e+00 12 9 8 11 8 0 30.37 17.27 0.66 0.03542 0.02745 49 10 1 5 0 1020.820 20.77 15.02 17.27 12.47 0.3 909.57 -194633 -93389 -97684 -143194 -155973 191709 900000 -40954 900000 -205887 -91084 -82220 -97389 -56093 -100162 -46559 -15399 38176 -59633 253973 -5186 56360 -51313 -24828 -1974 -59085 276 -20174 -20290 -29424 9822 16285 -3787 35097 63353 49695 -12358 48078 4561 22062 38771 63319 18151 49237 29262 24296 52300 -4308 36057 19566 35039 17864 26722 33180 19096 22085 24759 26832 12137 21273 8177 26267 19569 13126 19829 10941 12067 5778 19551 11633 10265 7008 7996 5538 2326 -1001 -8085 2363 -3973 -2305 -3661 -1313 1144 26 4320 -3462 3766 -202 4253 -41 -5044 505 -8010 -4625 -3857 -831 -1306 -33 -2480 -1882 -2047 -3670 -2170 -4713 -729 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