File name: Pandora153s1_ChelseaMA_20241104_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241105T115354.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20241104_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20241104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241104T121021.4Z 9074.507192 32 1 49.99 2 82.73 118.93 114.78 106.21 0.00 1 0.00 1 0 17 4.575e-01 1.457e-02 2.687e-01 8.282e-03 7.815246e-01 4.696875e-03 9.064574e-03 -6.000000e+00 2.600674e-01 223.82 -2.00 3.54 -2.00 321.91 0.00e+00 1.548766e-03 2.575487e-03 4.870325e-03 -6.000000e+00 1.151513e-02 280.43 -2.00 20.00 -2.00 321.45 0.00e+00 7.295 0.007 302.00 328.00 3 6.9686e-01 1.7638e-02 8.7465e-02 -6.0000e+00 6.4083e-01 4.7791e-01 2.4616e-02 5.3683e-02 -6.0000e+00 6.9612e-01 -6.7632e-01 2.4378e-02 2.7437e-02 -6.0000e+00 4.1385e-01 2.7782e-01 1.1365e-02 8.0237e-03 -6.0000e+00 1.7984e-01 9.3397e-05 -5.4400e-04 2.3641e-04 1.3229e-04 -6.0000e+00 1.2177e-02 4.0721e-02 0.0000e+00 12 8 8 10 0 0 36.71 16.73 0.57 0.04072 0.03663 104 20 1 5 0 480.620 20.35 14.99 16.73 7.37 0.6 885.71 -47168 -190938 -64128 -191646 -85388 900000 -153948 -107963 -183648 -150392 -191136 -73361 -117471 -52273 -83065 -67580 -5169 -56264 1893 -49417 -36331 -20661 6140 -41966 -25268 -25938 -28027 -37002 -53087 -28061 -62558 -5096 -2 -25632 9204 -29634 -22046 -18006 16758 16415 40306 26684 34720 23926 448 3344 19927 21972 5489 12541 11224 20585 11865 17024 14565 13278 18001 -1020 21838 9412 6619 12055 15596 13837 12690 10492 2675 7335 6506 9416 6493 8920 5268 1766 2236 217 -1890 -5026 -2465 -767 810 -1605 -1642 -493 1151 2074 -706 344 394 335 -992 -894 202 -2830 -3887 -1879 -720 -977 -500 -639 -1772 -3011 -2260 -831 -2623 -1881 -1963 -934 -553 665 581 137 943 -400 -430 -1575 -387 138 1107 834 967 1357 1769 865 854 617 299 471 -228 409 523 32 37 -160 118 -240 264 71 332 -242 -626 -987 900000 -381 -3924 -518 -3657 -689 900000 -2113 -1046 -4152 -2550 -5093 -711 -2276 -675 -1811 -1473 -67 -1317 26 -1157 -733 -350 84 -1017 -551 -586 -634 -866 -1457 -680 -2627 -144 0 -1035 245 -1172 -908 -858 690 795 1692 1357 1682 1294 31 227 1175 1331 417 972 997 1862 1167 1724 1593 1530 2008 -134 2180 1043 792 1540 2221 2255 2161 1794 503 1405 1438 2315 1773 2423 1427 456 514 46 -397 -1170 -660 -244 298 -691 -768 -242 595 1125 -411 201 227 183 -512 -440 99 -1558 -2525 -1412 -626 -894 -486 -607 -1559 -2599 -1810 -683 -2366 -1777 -1984 -936 -624 849 827 207 1408 -585 -601 -2183 -546 205 1721 1318 1476 1969 2476 1184 1132 792 384 668 -379 766 1076 71 87 -405 318 -675 749 204 931 -644 -1552 -2306 900000 SS 20241104T121228.2Z 9074.508660 34 1 50.24 2 82.39 119.32 114.42 106.51 0.00 1 0.00 1 0 17 4.959e-01 1.398e-02 1.939e-01 6.562e-03 7.507685e-01 3.618480e-03 8.832528e-03 -6.000000e+00 2.800960e-01 223.82 -2.00 3.54 -2.00 321.81 0.00e+00 4.478807e-03 1.953562e-03 4.698234e-03 -6.000000e+00 1.235055e-02 280.43 -2.00 20.00 -2.00 321.35 0.00e+00 7.016 0.006 302.00 328.00 3 6.7957e-01 1.3391e-02 8.3314e-02 -6.0000e+00 6.9070e-01 4.0581e-01 1.8732e-02 4.9034e-02 -6.0000e+00 7.5004e-01 -5.9068e-01 1.8734e-02 2.7057e-02 -6.0000e+00 4.4722e-01 2.4644e-01 8.7542e-03 8.8805e-03 -6.0000e+00 1.9495e-01 1.2781e-04 -4.9029e-04 1.8464e-04 1.6158e-04 -6.0000e+00 1.3167e-02 4.0171e-02 0.0000e+00 12 8 8 10 0 0 31.62 16.73 0.41 0.04017 0.03649 126 25 1 5 0 398.700 20.35 15.00 16.73 7.57 0.6 886.82 -131362 -140200 -123142 -187303 -138076 -217270 -148492 -195079 -134886 -116348 -143442 -113923 -134927 -36957 -29947 -35178 -38877 -39535 -73817 -37624 -23673 -49255 24758 -60592 -8332 -52505 -13462 -42588 -13673 -12606 -19050 15568 -5321 26026 -26670 -9242 -8175 -6587 1308 16832 15752 4297 29970 22139 29834 5390 15477 16600 9850 25310 16088 21099 8193 12442 12832 19279 4677 7793 8284 6156 13453 1573 14151 10351 12244 7493 5440 943 4510 10583 3120 9286 526 4019 -508 347 -2125 -2487 -120 -3247 2492 -1516 -355 -1101 922 -1626 599 630 8 292 -1857 -557 -2791 -1552 -4265 -2006 -1123 -610 453 -698 -954 -3630 -1556 -2534 -1104 -1088 -1013 -1104 -643 -217 369 1068 155 -481 -842 -543 213 357 744 197 1163 832 1573 886 1164 429 -333 87 560 718 -29 2 -357 -103 -119 -226 276 584 299 -480 -379 -1046 900000 -1513 -1794 -1497 -3595 -1590 -4929 -1995 -4198 -1899 -1414 -2386 -1676 -3194 -426 -402 -585 -746 -835 -2104 -843 -454 -1198 301 -1861 -160 -1613 -276 -1117 -271 -282 -561 388 -187 683 -1109 -325 -319 -303 62 793 825 267 1499 1210 1527 361 963 1072 722 1737 1366 1902 920 1447 1560 2276 647 1020 1036 777 1667 248 2272 1939 2322 1460 1095 211 1112 2813 883 2520 150 1115 -132 81 -492 -619 -34 -1061 902 -651 -163 -542 476 -913 343 368 5 160 -969 -273 -1394 -834 -2742 -1487 -964 -596 467 -710 -893 -3101 -1219 -2088 -967 -1006 -999 -1188 -776 -298 558 1683 247 -741 -1240 -781 314 555 1220 329 1871 1282 2332 1280 1624 582 -453 130 964 1397 -63 4 -802 -249 -306 -604 748 1591 801 -1222 -898 -2542 900000 SS 20241104T122438.3Z 9074.517110 38 1 49.59 2 80.46 121.54 112.37 108.23 0.00 1 0.00 1 0 17 4.066e-01 1.407e-02 2.824e-01 1.036e-02 6.491200e-01 5.625618e-03 7.796041e-03 -6.000000e+00 2.311481e-01 223.82 -2.00 3.54 -2.00 321.36 0.00e+00 2.932595e-03 2.697440e-03 3.914753e-03 -6.000000e+00 1.023485e-02 280.43 -2.00 20.00 -2.00 320.85 0.00e+00 5.748 0.004 302.00 328.00 3 2.7634e+00 1.9167e-02 6.8854e-02 -6.0000e+00 5.6957e-01 2.0785e-01 2.5745e-02 4.1521e-02 -6.0000e+00 6.1873e-01 -2.8973e-01 2.5326e-02 2.1807e-02 -6.0000e+00 3.6784e-01 1.2348e-01 1.2187e-02 6.6031e-03 -6.0000e+00 1.5983e-01 5.7836e-05 -3.4167e-04 3.0058e-04 1.1300e-04 -6.0000e+00 1.0825e-02 4.1242e-02 0.0000e+00 12 8 8 10 0 0 99.66 16.77 0.28 0.04124 0.03867 42 8 1 5 0 1180.620 20.35 14.99 16.77 8.20 0.5 889.15 -169258 -42251 -33717 -138546 -157195 900000 -160557 -100255 -140189 -131024 -165428 22701 -74404 -45263 -20386 7147 -49617 -61469 16741 -73508 25132 -35550 -89632 63645 1217 -16437 -19268 -23503 -12209 -6840 3376 15309 46300 -13307 27184 -23388 11513 1132 38166 11527 28301 29140 5492 14303 5139 36157 -4006 2194 4474 16268 665 3887 10725 -67 14610 6100 14247 5151 1604 -3505 2414 9308 6317 7539 7194 4710 -3713 2049 2659 6806 2867 3429 1377 -47 -96 -3220 -5017 -2762 -1584 -2545 -1341 -257 -920 677 -109 644 -1196 -867 1178 445 55 -3587 -3466 -1052 -692 -1943 -437 -200 -256 351 -1065 -1049 -2318 -302 -2134 -1281 -1512 -631 464 582 1570 113 1097 -524 -546 -1090 -532 -535 434 560 651 1676 1010 1129 308 261 -115 -486 1032 188 522 -657 123 -477 51 -205 796 157 -355 431 -606 -997 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