File name: Pandora153s1_ChelseaMA_20241117_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241119T080234.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20241117_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20241117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241117T121043.6Z 9087.507449 244 1 49.83 2 85.55 121.13 74.42 292.69 0.00 1 0.00 1 0 25 5.317e-01 6.397e-02 5.319e-01 6.749e-02 9.994870e-01 4.101394e-02 1.115276e-02 -6.000000e+00 3.042527e-01 222.88 -2.00 3.54 -2.00 322.00 0.00e+00 -1.939533e-02 1.486482e-02 4.055490e-03 -6.000000e+00 1.499532e-02 278.85 -2.00 20.00 -2.00 321.46 0.00e+00 10.682 0.023 302.00 328.00 3 -3.3967e-01 1.3197e-01 1.2467e-01 -6.0000e+00 7.4876e-01 2.1186e+00 1.5892e-01 7.7213e-02 -6.0000e+00 8.1598e-01 -2.1376e+00 1.0655e-01 2.7662e-02 -6.0000e+00 4.8793e-01 7.3073e-01 5.6333e-02 1.6493e-02 -6.0000e+00 2.1534e-01 5.9860e-06 1.6718e-03 1.8293e-03 1.9628e-04 -6.0000e+00 1.4657e-02 3.5272e-02 0.0000e+00 12 8 8 10 0 0 70.66 17.18 1.37 0.03527 0.04783 22 4 1 5 0 2264.970 20.67 15.00 17.18 12.03 0.3 909.70 110405 900000 40297 86405 19287 -32425 54592 -59203 12758 13979 900000 -88491 900000 900000 35473 900000 126465 285597 23763 900000 32441 900000 8490 83120 145472 73809 900000 -38723 900000 -76339 900000 -39045 1203 87732 116268 900000 -28080 140209 58497 12618 28960 156124 172473 71190 9267 -22670 12600 -28921 58467 -46741 900000 11848 29305 122818 58617 45298 30103 101768 6994 900000 -39865 -18504 26065 -6358 -11095 -31857 -23943 -8095 26654 -1221 30499 -1282 46362 10567 -25959 -10187 -45180 13407 -20186 30683 11756 20701 16464 -3566 25111 -5759 35016 8505 19300 15857 3527 673 2579 23519 -183 32670 -18806 -1798 -7766 6945 -3766 -17117 5450 758 -7385 -7494 -426 -7483 7244 -4141 9622 2935 -1080 3936 -6297 -2071 -2945 2660 -9547 4485 5502 208 7615 1525 5307 1829 -1028 2156 -3072 1943 -3696 -1942 -336 3848 807 1370 -233 1917 -1465 -1378 1093 -2987 900000 7247 900000 2645 5671 1266 -2515 3583 -7419 837 918 900000 -16897 900000 900000 2540 900000 8301 18746 1843 900000 2129 900000 659 5456 9548 4845 900000 -4159 900000 -10932 900000 -4893 108 5758 7632 900000 -3016 9203 3840 1506 3110 10248 11321 4673 940 -2976 1241 -3969 3838 -8646 900000 1633 3655 8061 6156 5649 4347 6680 1056 900000 -7850 -3522 3593 -1335 -2476 -7794 -5572 -1913 5073 -313 6606 -344 7912 2289 -6986 -2073 -12752 2288 -5697 6243 3395 6250 5620 -1425 8735 -2577 11721 3349 7221 5724 1343 256 999 8336 -88 14796 -15149 -1395 -6766 5056 -2764 -12563 2959 448 -5067 -5411 -308 -6430 6224 -4671 10737 3748 -1463 4979 -8529 -2658 -3936 3540 -14983 6075 6993 263 8679 1801 5890 2041 -1203 2792 -5004 3490 -7851 -4403 -811 9691 2250 3923 -687 5547 -4248 -3708 2628 -6970 900000 SS 20241117T121255.6Z 9087.508977 246 1 49.94 2 85.20 121.52 74.78 293.01 0.00 1 0.00 1 0 25 4.735e-01 4.420e-02 4.746e-01 4.746e-02 1.006863e+00 2.754145e-02 1.157444e-02 -6.000000e+00 2.666996e-01 222.88 -2.00 3.54 -2.00 322.06 0.00e+00 -3.699292e-03 1.054881e-02 1.196039e-03 -6.000000e+00 1.188305e-02 278.85 -2.00 20.00 -2.00 321.55 0.00e+00 10.132 0.020 302.00 328.00 3 -3.6541e-01 9.2155e-02 1.1437e-01 -6.0000e+00 6.5666e-01 2.0955e+00 1.0640e-01 5.2087e-02 -6.0000e+00 7.1359e-01 -2.1789e+00 7.1276e-02 2.6721e-02 -6.0000e+00 4.2589e-01 7.6365e-01 3.9713e-02 8.4779e-03 -6.0000e+00 1.8667e-01 1.0038e-05 -9.1219e-04 1.2254e-03 1.1798e-04 -6.0000e+00 1.2653e-02 3.5433e-02 0.0000e+00 12 8 8 10 0 0 85.90 17.18 0.98 0.03543 0.02858 33 6 1 5 0 1513.300 20.67 15.00 17.18 12.16 0.3 910.22 212862 142243 900000 110653 18129 -74147 145155 78570 50584 -1105 73269 12964 83977 900000 25629 86817 20019 -2145 75816 -50124 33269 9873 217936 8465 84763 11578 -54396 56834 -32018 56625 -12592 -33742 -9198 61186 -48601 -61456 92820 -38898 53510 52354 51819 9825 -16910 96173 31294 33379 -45698 87393 -14811 -11004 2530 22290 32934 61110 86532 21950 46033 7447 -51783 -27076 -21834 -4207 -9592 40015 -16757 52753 29977 61170 8025 48555 15410 5928 809 -5552 41947 -25106 1975 -9438 8000 -26518 20094 3691 24454 14458 1005 18487 2467 4481 -1644 -3000 9180 17439 315 -4636 4054 -2323 7412 -4480 4914 2349 -5942 -3000 2928 5611 -5639 -1750 -9502 8183 -378 -684 -4029 2618 626 -2606 -5933 -2198 3102 -1395 158 435 3955 -654 304 6407 723 755 -4418 -221 -727 2649 563 -1430 501 -1210 -724 -706 1782 773 1952 -243 -41 -2867 900000 9846 6580 900000 5118 915 -8419 6714 3634 2340 -60 3389 654 3885 900000 1832 4016 1684 -225 3858 -7588 2155 731 10081 666 3921 857 -6405 2629 -2666 2619 -1107 -4214 -979 3113 -6520 -8813 4294 -5398 3465 3875 4075 1182 -2581 4449 2606 2625 -7821 4043 -1987 -1527 339 2681 3809 5654 6404 3148 5110 1137 -12935 -4885 -3737 -662 -1819 5183 -3953 6101 4437 7074 1782 8086 3778 1590 213 -1387 5627 -5807 338 -1965 1665 -9445 5298 1315 7692 5284 441 7098 1141 2031 -768 -1332 3355 5647 124 -2145 2044 -1358 4644 -3655 3926 1886 -4722 -2018 1687 3530 -3865 -1214 -7632 6090 -354 -756 -5270 3457 863 -3661 -8334 -2930 4044 -2006 235 644 5372 -875 389 7517 876 889 -5517 -299 -1187 4879 1190 -3361 1249 -3326 -2127 -2151 5365 2363 5745 -683 -106 -6981 900000 SS 20241117T130959.4Z 9087.548605 273 1 50.26 2 76.78 132.18 83.73 301.34 0.00 1 0.00 1 0 17 1.367e-01 6.177e-03 1.395e-02 6.503e-04 5.096991e-01 3.366534e-04 6.035657e-03 -6.000000e+00 7.701572e-02 222.88 -2.00 3.54 -2.00 320.28 0.00e+00 1.043470e-03 1.184282e-04 9.407212e-04 -6.000000e+00 3.382045e-03 278.85 -2.00 20.00 -2.00 319.73 0.00e+00 4.265 0.001 302.00 328.00 3 -1.5880e-02 9.8844e-04 4.9897e-02 -6.0000e+00 1.8963e-01 3.3893e-02 1.2323e-03 2.7015e-02 -6.0000e+00 2.0605e-01 -3.0492e-02 1.1498e-03 1.4243e-02 -6.0000e+00 1.2283e-01 6.4040e-03 5.9049e-04 4.5253e-03 -6.0000e+00 5.3631e-02 4.4590e-03 -3.9889e-05 1.8630e-05 5.2285e-05 -6.0000e+00 3.6277e-03 3.3473e-02 0.0000e+00 10 0 0 10 0 0 3.05 17.27 0.25 0.03347 0.03317 1002 197 1 5 0 50.050 20.77 15.01 17.27 14.04 0.2 920.40 -52471 -30520 -47927 -36006 -60368 -45394 -56455 -37176 -44489 -41411 -34347 -33986 -17061 -18149 -8265 -12936 -6301 -6493 -5193 -4893 -6638 -3869 -8976 -1678 -5838 -3249 -7404 -6644 -9612 -7381 -2764 -2721 1868 -4355 -3872 -7698 -4634 -2161 -580 747 146 1063 396 1626 860 1092 281 240 718 521 1882 1062 2352 1358 1802 1741 1352 855 5 332 639 2275 2535 2658 798 -49 -1153 -914 866 987 1318 906 905 462 -108 -1295 -2137 -2024 -1594 -734 -1010 -1125 -2128 -1302 -863 -292 452 768 1055 589 710 -81 -713 -519 -252 65 583 899 459 60 -763 -1348 -1051 -569 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