File name: Pandora249s1_ChicagoIL_20230503_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T070853.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v1d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230503_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20230503T145822.6Z 8523.623872 1136 1 54.30 2 44.76 112.94 140.51 330.86 0.00 1 0.00 1 0 17 1.564e-02 7.341e-03 4.808e-03 1.960e-03 2.571373e-01 1.035968e-03 3.127268e-03 -6.000000e+00 9.464108e-03 229.91 -2.00 3.53 -2.00 316.63 0.00e+00 3.258738e-04 1.270177e-04 4.981850e-05 -6.000000e+00 4.112265e-04 280.57 -2.00 20.00 -2.00 315.97 0.00e+00 1.406 0.000 302.00 328.00 3 6.1378e+00 2.7129e-03 1.9432e-02 -6.0000e+00 2.3631e-02 7.1648e-02 3.0271e-03 1.3412e-02 -6.0000e+00 2.5525e-02 -1.8216e-02 1.7617e-03 6.5876e-03 -6.0000e+00 1.5174e-02 2.8745e-03 8.2659e-04 1.8512e-03 -6.0000e+00 6.3731e-03 2.0066e-04 3.0032e-05 6.0841e-05 2.4449e-05 -6.0000e+00 4.7681e-04 -6.8818e-04 0.0000e+00 11 9 0 11 8 0 91.86 25.49 0.36 -0.00069 -0.00046 15 2 1 5 0 3619.670 32.75 20.00 25.49 17.84 9.2 931.12 -4113 836 -3871 1096 -6578 6678 -1842 -4570 1549 -182 2205 -4717 -1163 3850 728 -439 -405 1113 872 2950 712 -56 -2196 135 1557 -3230 -325 395 -1172 3204 2962 605 1623 -1210 -1264 -2485 -2244 -856 -1159 -1208 555 -437 -1604 265 693 -1165 -347 -986 507 -1651 237 2389 570 87 1066 1529 272 1242 769 867 -313 1397 2468 1042 819 208 -670 -169 -87 53 405 -26 1181 -563 178 -75 -741 -759 -3783 -927 -1628 -1360 -1413 -1356 -451 -422 -161 369 508 347 168 22 88 -306 675 67 159 798 975 -133 -194 -796 -191 -763 -513 -600 -725 57 192 325 376 628 -114 100 -379 -77 643 52 -511 78 -593 31 66 79 244 632 691 835 216 154 562 -263 430 768 -206 186 -42 -311 -177 -21 -495 -451 -313 -612 132 -665 174 -1035 856 -259 -718 253 -32 390 -907 -232 824 182 -123 -121 340 252 947 217 -17 -698 44 519 -1174 -116 134 -418 1053 995 222 575 -459 -469 -995 -848 -361 -578 -705 325 -275 -1057 174 453 -772 -224 -627 311 -1027 149 1558 402 65 815 1190 218 987 606 675 -251 1156 2175 915 735 180 -586 -140 -74 46 382 -26 1192 -564 167 -70 -627 -598 -3083 -798 -1457 -1342 -1507 -1528 -496 -496 -200 473 656 439 201 25 95 -314 697 75 183 1004 1313 -171 -256 -984 -221 -880 -623 -778 -988 76 265 473 578 925 -177 146 -514 -104 837 70 -726 109 -870 45 95 109 342 840 873 1033 278 212 814 -372 617 1130 -321 304 -67 -507 -291 -34 -781 -731 -493 SU 20230503T150458.5Z 8523.628454 1150 1 53.73 2 43.64 114.55 141.09 333.18 0.00 1 0.00 1 0 17 1.507e-02 7.304e-03 4.430e-03 1.883e-03 2.489152e-01 9.963375e-04 3.030648e-03 -6.000000e+00 9.118537e-03 229.91 -2.00 3.53 -2.00 316.52 0.00e+00 5.216960e-04 1.190640e-04 4.964200e-05 -6.000000e+00 3.962286e-04 280.57 -2.00 20.00 -2.00 315.87 0.00e+00 1.380 0.000 302.00 328.00 3 6.1151e+00 2.6098e-03 1.8940e-02 -6.0000e+00 2.2768e-02 6.1718e-02 2.9091e-03 1.2993e-02 -6.0000e+00 2.4593e-02 -1.5019e-02 1.6917e-03 6.3766e-03 -6.0000e+00 1.4620e-02 2.6893e-03 7.8871e-04 1.8127e-03 -6.0000e+00 6.1402e-03 2.1431e-04 5.1593e-06 5.8558e-05 2.3562e-05 -6.0000e+00 4.5941e-04 -4.1467e-04 0.0000e+00 11 8 0 10 0 0 98.66 25.55 0.14 -0.00041 -0.00038 14 1 1 5 0 3837.490 32.75 20.01 25.55 18.16 9.3 933.62 -3459 -1580 -5244 -1020 -4256 7219 -2971 -4421 2139 -310 1499 -3792 -344 3951 849 -639 -725 261 1728 1821 2009 347 -1197 481 2497 -2857 -440 343 -1979 3086 2268 503 508 -35 -233 -2687 -2639 -1040 -703 -1355 157 -627 -965 285 534 -174 -740 -1146 262 -1589 284 2208 1091 742 352 1754 336 1063 586 465 -89 1301 2296 291 541 265 -632 -351 -80 719 107 203 1000 -931 93 685 -1126 -816 -3733 -917 -1088 -1632 -1323 -702 -41 -561 7 210 577 359 -32 -292 179 -224 478 -295 107 857 1095 358 -557 -712 -221 -766 -373 -781 -954 -196 506 381 153 913 -30 -14 -530 -63 373 241 -193 -94 -394 -313 189 423 235 680 965 988 260 169 271 -390 641 754 -276 155 -285 -580 -186 -182 -365 -120 -262 -545 -271 -973 -176 -696 978 -449 -735 368 -58 282 -761 -72 888 223 -189 -207 76 518 562 633 111 -394 161 859 -1076 -163 121 -672 1055 796 174 188 -13 -89 -1012 -1034 -454 -360 -816 95 -407 -650 192 360 -117 -496 -751 166 -1015 183 1480 783 561 277 1392 275 864 473 372 -73 1104 1915 264 497 233 -520 -298 -69 626 103 208 1029 -953 89 595 -974 -655 -3094 -803 -983 -1640 -1432 -741 -45 -669 9 255 707 461 -39 -326 196 -232 500 -335 125 1090 1391 464 -698 -890 -259 -895 -459 -1029 -1233 -263 706 562 223 1355 -43 -21 -727 -86 491 325 -258 -133 -583 -465 273 588 312 914 1230 1234 339 235 370 -555 923 1117 -433 239 -457 -955 -308 -297 -580 -183 -417 SU 20230503T151326.0Z 8523.634328 1171 1 53.74 2 42.22 116.69 141.77 336.23 0.00 1 0.00 1 0 17 1.403e-02 7.324e-03 4.758e-03 2.043e-03 2.470461e-01 1.084228e-03 3.000462e-03 -6.000000e+00 8.490203e-03 229.91 -2.00 3.53 -2.00 316.48 0.00e+00 6.496052e-04 1.269654e-04 5.215698e-05 -6.000000e+00 3.689382e-04 280.57 -2.00 20.00 -2.00 315.83 0.00e+00 1.349 0.000 302.00 328.00 3 6.2592e+00 2.8304e-03 1.8643e-02 -6.0000e+00 2.1199e-02 7.7695e-02 3.1493e-03 1.2873e-02 -6.0000e+00 2.2899e-02 -1.5759e-02 1.8312e-03 6.3144e-03 -6.0000e+00 1.3613e-02 6.3294e-04 8.5563e-04 1.8144e-03 -6.0000e+00 5.7169e-03 1.9056e-04 -1.4205e-05 6.3606e-05 2.3798e-05 -6.0000e+00 4.2776e-04 -2.0037e-04 0.0000e+00 11 8 0 10 0 0 99.86 25.62 0.47 -0.00020 -0.00031 15 2 1 5 0 3582.110 32.75 19.91 25.62 18.83 9.3 938.30 -2799 2123 -3959 910 -3537 3553 726 -2534 922 -3332 3781 -3659 -2533 2691 2094 -636 317 381 1206 3265 1644 -1905 -2470 -108 1577 -2878 149 537 -281 4439 854 1959 1236 -1077 -2153 -2571 -1874 -467 -1415 -1455 143 -1049 -1564 -260 442 318 -1163 -470 -223 -1565 301 2077 448 92 578 2277 592 1101 876 734 -336 1414 1997 793 265 233 -529 -132 -74 225 862 326 1273 -540 -182 65 -483 -1274 -3827 -1110 -913 -1763 -1219 -1370 -90 -238 411 428 401 497 76 224 160 -336 327 -352 -16 758 931 -16 -313 -710 -402 -689 -412 -723 -903 -195 385 440 165 915 -174 -233 -261 -103 444 -103 -104 155 -469 204 405 202 180 450 404 643 9 36 278 -475 455 946 -355 403 -150 -315 -81 -194 -585 -270 -50 -442 354 -731 155 -578 503 106 -415 161 -647 695 -734 -539 613 544 -188 99 123 399 1091 571 -625 -820 -36 544 -1077 54 207 -103 1486 302 729 496 -418 -826 -1053 -793 -200 -722 -866 94 -675 -1045 -174 294 211 -770 -301 -152 -1072 208 1369 318 69 445 1763 473 877 690 573 -269 1172 1770 697 239 217 -460 -109 -63 208 803 323 1270 -535 -170 59 -403 -999 -3081 -943 -866 -1720 -1276 -1517 -105 -274 497 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