File name: Pandora249s1_ChicagoIL_20230531_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T070753.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230531_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230531T110536.2Z 8551.462225 144 1 54.00 2 83.04 66.68 122.31 289.20 0.00 1 0.00 1 0 17 5.601e-01 2.973e-02 3.201e-01 9.099e-03 1.028699e+00 6.018195e-03 1.117558e-02 -6.000000e+00 3.522259e-01 231.91 -2.00 3.53 -2.00 322.32 0.00e+00 -2.672286e-03 3.872357e-03 9.141426e-03 -6.000000e+00 2.010073e-02 283.55 -2.00 20.00 -2.00 321.89 0.00e+00 7.565 0.008 302.00 328.00 3 1.7631e+00 2.5574e-02 1.1074e-01 -6.0000e+00 8.9652e-01 1.0044e+00 4.0472e-02 1.0326e-01 -6.0000e+00 9.7694e-01 -1.3086e+00 4.0813e-02 4.7074e-02 -6.0000e+00 5.6986e-01 5.1506e-01 1.7682e-02 1.1228e-02 -6.0000e+00 2.4297e-01 1.8884e-05 -8.6700e-04 2.7287e-04 1.6885e-04 -6.0000e+00 1.9267e-02 7.2094e-03 0.0000e+00 12 8 8 10 0 0 45.43 26.59 0.96 0.00721 0.00069 47 5 1 5 0 1148.790 33.25 20.00 26.59 28.25 9.3 997.01 -88607 900000 900000 900000 900000 -207583 -151306 900000 900000 900000 -123708 900000 900000 900000 -121510 -70884 120800 900000 900000 900000 900000 778 -141865 -57154 900000 -170494 -46737 -113737 87668 900000 900000 900000 -50364 -33334 -34498 -24675 900000 54397 900000 900000 900000 173850 85553 900000 106251 93519 43495 98213 38184 900000 74035 900000 14230 57830 11515 110212 82187 25207 99246 36166 65301 48407 40783 11116 38749 72601 62819 24779 34307 37475 1119 21270 23250 39696 10303 35777 2828 31439 -45987 -4310 9083 249 3194 16053 12449 7722 -1179 2728 2563 1187 6876 13900 -3237 -717 6937 -7055 -2176 -1678 -1044 -938 -804 -1563 -3342 -8042 4561 -2280 682 -2979 -5114 -1340 -3966 -722 244 -2844 995 -55 -863 941 -820 223 266 535 2205 2231 -345 3279 3333 4418 -595 1410 -1643 -24 -585 3185 -513 343 329 -360 116 544 -1288 -1776 -340 -782 900000 900000 900000 900000 -3497 -1457 900000 900000 900000 -1191 900000 900000 900000 -2437 -1024 1066 900000 900000 900000 900000 7 -5236 -963 900000 -9986 -787 -3559 774 900000 900000 900000 -1414 -856 -886 -554 900000 655 900000 900000 900000 1534 1510 900000 1500 1486 1152 1560 1179 900000 1960 900000 867 2501 854 3210 3264 1757 3153 2043 2709 2521 2591 1089 3180 4421 4324 2646 3694 4465 213 3492 3714 5045 1582 3789 387 3302 -11851 -883 1964 69 978 4704 4032 2774 -484 1105 1038 472 2445 4379 -1197 -274 2810 -3916 -1375 -1240 -863 -811 -670 -1196 -2333 -5571 2866 -1626 502 -2471 -4861 -1291 -4541 -895 318 -3882 1286 -70 -1113 1234 -1147 318 374 714 2745 2676 -412 4036 4042 5541 -814 2218 -3063 -50 -1308 7418 -1223 860 851 -948 302 1354 -3034 -4220 -750 SS 20230531T111627.4Z 8551.469761 147 1 54.34 2 81.18 68.38 124.16 291.35 0.00 1 0.00 1 0 17 6.454e-01 1.359e-02 2.147e-01 2.805e-03 8.621888e-01 1.626481e-03 9.585070e-03 -6.000000e+00 3.973226e-01 231.91 -2.00 3.53 -2.00 321.48 0.00e+00 4.125858e-03 8.723434e-04 1.048884e-03 -6.000000e+00 1.762393e-02 283.55 -2.00 20.00 -2.00 320.97 0.00e+00 6.165 0.004 302.00 328.00 3 1.5722e+00 5.8129e-03 7.7103e-02 -6.0000e+00 9.9919e-01 3.1620e-01 8.5670e-03 4.9313e-02 -6.0000e+00 1.0797e+00 -4.3520e-01 8.9417e-03 2.7028e-02 -6.0000e+00 6.3883e-01 1.6949e-01 4.0986e-03 1.0763e-02 -6.0000e+00 2.6568e-01 1.1016e-04 -6.2399e-04 7.6873e-05 1.3376e-04 -6.0000e+00 2.0103e-02 6.7751e-03 0.0000e+00 12 8 8 10 0 0 47.04 26.63 0.59 0.00678 0.00209 135 14 1 5 0 402.490 33.50 20.01 26.63 28.77 9.3 1000.32 -244253 6906 -221878 -9018 900000 -279726 -283037 -229082 900000 -227654 -161929 -41582 23174 -98357 -151021 -79878 -94756 900000 -44780 -95466 82780 -77092 -115647 -83549 -53464 -136622 -35555 -111699 -45855 -91544 -7495 8854 -56809 -33399 -29859 -55320 11370 -20591 634 39505 22988 -6080 11436 22302 -7206 -99 -8441 1372 15608 8432 8103 46743 11590 11926 8148 11440 14348 5172 8419 8764 4924 6406 11495 5521 8734 9015 6952 6353 6543 1766 1720 5625 3383 2256 2911 1318 -3161 641 -10779 -2930 -1619 -1894 222 -596 2071 1692 703 333 334 245 451 1934 -1506 941 128 -1824 -598 -879 -420 -661 -400 -907 -842 -1916 -1639 -1668 -1178 -1076 -1471 -341 -302 -550 311 -321 -55 366 240 308 103 -67 443 471 778 253 624 841 1266 1159 767 448 328 214 395 217 -56 30 -30 -189 -377 -164 -262 -505 -329 -1822 19 -1820 -25 900000 -3825 -4151 -2164 900000 -2603 -1047 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328.00 3 1.3281e+00 1.9972e-03 6.2914e-02 -6.0000e+00 5.2476e-01 7.1843e-02 2.6094e-03 3.9594e-02 -6.0000e+00 5.6587e-01 -1.0887e-01 2.5656e-03 2.0286e-02 -6.0000e+00 3.3642e-01 3.6701e-02 1.2618e-03 7.3653e-03 -6.0000e+00 1.4097e-01 4.8113e-04 -4.7490e-04 3.2379e-05 7.9415e-05 -6.0000e+00 1.0489e-02 6.6709e-03 0.0000e+00 11 8 0 10 0 0 76.73 26.72 0.43 0.00667 0.00310 317 32 1 5 0 171.910 33.50 20.00 26.72 29.56 9.4 1005.92 -154854 -41611 -129150 -46711 -26136 -182467 -133751 -81636 3457 -73496 -105496 -68458 -65321 -82015 -64916 -46560 -31014 -23528 -16068 -60111 -16458 -30300 -43171 -35232 -30599 -53456 -21238 -27504 -36442 -35193 -18805 -11897 -18779 -12157 -6670 -19458 -5860 -8910 -3689 1873 1178 -551 -1693 41 -843 2287 -1908 524 117 1964 1544 4720 1960 1733 2737 2472 1847 1502 288 108 734 2093 3791 2628 1265 3412 1276 2221 2050 1439 914 750 705 639 -352 -367 -717 -533 -3189 -1116 -1296 -1402 -1465 -1531 -678 -324 -281 138 545 683 692 966 562 312 372 159 371 49 -55 -160 -423 -581 -229 -637 -746 -1082 -870 -592 -490 -218 -161 -152 -22 129 120 302 491 391 61 -104 -203 176 134 49 329 331 522 1060 667 210 306 -6 -80 202 -143 -74 103 -33 -323 -249 -169 -97 -121 -921 -98 -821 -134 -65 -2120 -1011 -414 9 -439 -952 -486 -560 -1082 -930 -688 -462 -369 -259 -1620 -301 -653 -1105 -906 -825 -1947 -582 -803 -1167 -1191 -632 -454 -907 -610 -323 -1073 -303 -555 -267 155 114 -60 -199 5 -105 283 -254 71 17 300 263 879 381 371 627 601 469 388 74 27 188 573 1153 915 484 1304 498 886 817 657 469 411 390 340 -174 -165 -300 -222 -1488 -597 -758 -948 -1108 -1162 -546 -277 -254 129 508 621 596 779 437 248 323 149 403 58 -67 -203 -517 -694 -249 -671 -821 -1269 -1077 -737 -665 -312 -242 -247 -35 212 189 456 734 603 99 -168 -329 292 213 76 512 496 759 1565 1030 350 566 -11 -155 417 -303 -165 229 -73 -731 -548 -367 -207 -246 SS 20230531T113521.3Z 8551.482886 155 1 54.49 2 77.88 71.32 127.32 295.30 0.00 1 0.00 1 0 25 2.414e-01 6.528e-03 4.119e-02 8.755e-04 6.683916e-01 4.782892e-04 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