File name: Pandora249s1_ChicagoIL_20230819_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T074912.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230819_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230819T120925.0Z 8631.506539 69 1 53.97 2 78.78 82.86 110.38 68.32 0.00 1 0.00 1 0 25 3.481e-01 3.707e-02 2.404e-01 1.090e-02 5.800609e-01 6.146644e-03 6.948554e-03 -6.000000e+00 2.151220e-01 231.44 -2.00 3.53 -2.00 320.81 0.00e+00 2.875937e-03 2.576842e-03 2.196785e-03 -6.000000e+00 1.018970e-02 288.29 -2.00 20.00 -2.00 320.13 0.00e+00 4.959 0.002 302.00 328.00 3 4.7111e+00 1.9752e-02 5.8210e-02 -6.0000e+00 5.4074e-01 3.7243e-01 2.5014e-02 3.3278e-02 -6.0000e+00 5.8494e-01 -4.0860e-01 2.0469e-02 1.6938e-02 -6.0000e+00 3.4573e-01 1.5546e-01 9.9854e-03 4.9665e-03 -6.0000e+00 1.4442e-01 1.8546e-05 -1.4551e-03 3.4313e-04 7.4873e-05 -6.0000e+00 1.0807e-02 6.4723e-03 0.0000e+00 12 8 8 10 0 0 99.91 26.10 1.22 0.00647 -0.00446 16 2 1 5 0 3372.710 33.00 20.01 26.10 24.53 9.4 968.28 -142219 -44656 -85499 41892 62709 900000 -53631 -161443 900000 -35936 900000 -8352 -29795 47249 -55120 -55646 4253 900000 51494 900000 30819 -758 -27571 1818 141344 -99248 -24965 19631 18967 900000 -5587 134855 3927 -24377 311 -10544 35493 6295 -3803 -1982 55330 8193 29697 59617 57981 668 126 -782 37606 17271 20895 76453 14067 -5382 17070 55989 185 24255 19689 24138 -8879 2301 15567 -4088 6512 14032 1800 3833 1109 -4300 2566 6873 13999 386 6011 7431 -11901 -7759 -35357 -5485 -2384 -4430 -1696 3827 2830 1927 2411 2220 3474 2075 -3804 -1578 -1543 -2864 719 -4307 -1523 -2050 2662 -114 -2376 -5226 1076 -6623 1775 -899 -436 -1025 640 -2835 -1242 4651 -460 -927 945 -848 1711 4260 -3296 1239 -2283 582 627 1671 -534 2064 4133 2183 295 512 1252 -1058 2401 5657 -1141 -586 -1977 -1807 219 -113 -1015 -1499 1228 -5630 -776 -2394 445 666 900000 -932 -8884 900000 -659 900000 -129 -662 593 -2341 -2794 131 900000 1143 900000 893 -30 -1437 74 1501 -12169 -1470 720 678 900000 -314 2148 263 -2330 23 -851 1885 508 -404 -244 4348 1114 3406 5192 5172 106 20 -129 4313 2531 3173 7307 2734 -1366 3662 8443 50 5152 4286 4922 -2546 628 4116 -1454 2213 4411 621 1299 410 -1877 1161 3160 6051 184 2515 2778 -4942 -2999 -19075 -2505 -1225 -2649 -1091 2500 1986 1455 1913 1830 2852 1688 -3103 -1173 -1083 -2020 523 -3719 -1467 -2257 3076 -140 -2869 -5988 1065 -6886 1774 -983 -501 -1260 835 -3826 -1811 6821 -722 -1425 1355 -1296 2509 6266 -5009 1891 -3673 895 1025 2611 -819 2962 5614 3041 452 870 2107 -1951 4499 10802 -2476 -1338 -4739 -4409 526 -266 -2305 -3238 2480 SS 20230819T121517.5Z 8631.510619 72 1 30.81 2 77.70 83.82 109.41 69.42 0.00 1 0.00 1 0 17 3.022e-01 1.168e-02 2.065e-01 5.009e-03 5.516007e-01 2.748183e-03 6.407649e-03 -6.000000e+00 1.839194e-01 231.44 -2.00 3.53 -2.00 320.41 0.00e+00 1.552208e-03 1.055706e-03 4.719854e-04 -6.000000e+00 8.205952e-03 288.29 -2.00 20.00 -2.00 319.72 0.00e+00 4.555 0.002 302.00 328.00 3 3.7527e+00 8.4868e-03 5.3469e-02 -6.0000e+00 4.5972e-01 4.2473e-02 1.0717e-02 2.9812e-02 -6.0000e+00 4.9534e-01 -6.4213e-02 9.4557e-03 1.5029e-02 -6.0000e+00 2.9549e-01 1.8439e-02 4.7185e-03 4.7755e-03 -6.0000e+00 1.2468e-01 7.9852e-05 -6.1723e-04 1.5430e-04 5.9843e-05 -6.0000e+00 9.2197e-03 5.7688e-04 0.0000e+00 12 9 9 12 1 1 94.78 26.11 0.61 0.00058 -0.00406 18 4 1 5 0 1464.440 33.00 20.00 26.11 24.67 9.4 968.69 -126513 128017 -141651 110442 -55401 -59123 -19517 -87952 107179 -51725 -48675 -6234 -59045 -32495 -85847 37024 -24333 56571 -2662 5353 43261 -28828 -8804 -6149 13380 -55388 3638 -9110 -33840 11130 30096 26459 -26025 -14700 -10298 -15820 3695 -5245 6005 1003 5930 4979 -6940 6435 -5657 -1428 -3185 -527 2156 7332 3316 14654 275 -563 4557 5164 4794 2845 2176 -380 -1131 789 4406 1258 2375 4364 3280 86 1590 1033 754 -476 3024 467 1366 1646 -96 -4023 -10799 -1302 -1647 -1466 -1874 -686 -17 -21 352 -886 -119 282 338 1738 -439 -810 638 1157 -666 14 580 -831 209 -1034 -251 -1122 -563 -1417 -346 367 -607 690 -509 788 -889 -246 -114 776 945 534 -635 366 -251 -609 112 500 409 489 817 1396 324 425 44 -551 567 453 -238 199 219 -450 -411 310 -379 -1002 421 -1798 625 -3082 540 -492 -525 -121 -1211 524 -682 -666 -61 -1154 -603 -3355 506 -701 801 -74 146 845 -1183 -305 -222 431 -3788 142 -401 -1868 402 1000 1060 -2021 -1113 -755 -1213 247 -443 549 116 747 693 -1153 968 -978 -241 -555 -91 374 1268 646 2821 67 -150 1235 1458 1405 860 655 -116 -354 259 1550 506 1007 1814 1343 36 709 473 386 -264 1642 252 683 822 -45 -1896 -5761 -654 -965 -978 -1391 -541 -14 -19 332 -806 -109 251 311 1471 -358 -656 544 1104 -679 16 729 -1092 262 -1213 -269 -1187 -621 -1678 -428 479 -796 978 -800 1301 -1514 -405 -177 1140 1363 795 -1009 607 -426 -1024 181 779 613 703 1224 2088 487 707 81 -1006 1075 904 -508 417 476 -1007 -927 681 -803 -2175 867 SS 20230819T122043.2Z 8631.514389 75 1 54.28 2 76.69 84.70 108.51 70.43 0.00 1 0.00 1 0 17 1.737e-01 7.389e-03 7.120e-02 2.295e-03 5.287996e-01 1.244371e-03 6.175564e-03 -6.000000e+00 1.056985e-01 231.44 -2.00 3.53 -2.00 320.02 0.00e+00 1.212323e-03 4.230660e-04 2.574061e-04 -6.000000e+00 4.716549e-03 288.29 -2.00 20.00 -2.00 319.29 0.00e+00 4.235 0.001 302.00 328.00 3 3.4411e+00 3.6988e-03 5.0210e-02 -6.0000e+00 2.6420e-01 3.2583e-02 4.5111e-03 2.8526e-02 -6.0000e+00 2.8468e-01 -5.1758e-02 3.7907e-03 1.4016e-02 -6.0000e+00 1.6983e-01 1.3472e-02 1.9389e-03 4.3375e-03 -6.0000e+00 7.1644e-02 1.5028e-04 -5.4234e-04 7.0049e-05 5.2243e-05 -6.0000e+00 5.2993e-03 1.3901e-03 0.0000e+00 11 8 0 10 0 0 99.01 26.14 0.64 0.00139 -0.00269 61 6 1 5 0 889.700 33.00 20.01 26.14 24.76 9.4 969.69 -104054 -26816 -61785 -16402 6498 -63656 -19182 -64062 78527 -29352 -44067 -38114 7258 -21591 -50559 -19611 -13440 -4630 -4959 -3389 6964 -942 -17327 2804 1812 -37545 -5188 -13792 -5978 -6579 8399 6758 -11186 -7703 -8744 -6201 -3218 -2805 128 247 3957 1078 -1683 2397 2209 703 -2697 -1717 -229 2050 1022 8368 1691 175 2244 690 2288 -92 1816 745 1168 942 2975 1183 1827 2592 1331 278 745 396 200 702 634 -410 596 146 -684 32 -4940 -969 -1129 -1732 -1817 -1203 -232 -571 -21 -78 549 341 120 737 305 1030 722 178 66 115 491 13 -364 -880 -665 -710 -442 -826 -599 -749 -260 -255 -130 416 -244 81 66 5 685 591 -218 -238 -172 -53 -100 82 489 693 628 878 638 471 55 106 158 666 -261 -87 -186 -105 -248 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