File name: Pandora249s1_ChicagoIL_20230909_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20230910T124722.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20230909_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230909T121914.8Z 8652.513366 241 1 25.08 2 80.71 91.22 23.67 120.99 0.00 1 0.00 1 0 25 4.264e-01 2.073e-02 2.135e-01 7.552e-03 6.878229e-01 4.245831e-03 8.153230e-03 -6.000000e+00 2.574938e-01 229.63 -2.00 3.53 -2.00 321.16 0.00e+00 8.357264e-03 1.977032e-03 2.048043e-03 -6.000000e+00 1.148063e-02 286.60 -2.00 20.00 -2.00 320.56 0.00e+00 5.886 0.004 302.00 328.00 3 2.5911e+00 1.4192e-02 6.8324e-02 -6.0000e+00 6.4115e-01 4.5168e-01 1.8265e-02 3.7272e-02 -6.0000e+00 6.9219e-01 -5.6042e-01 1.5822e-02 2.1355e-02 -6.0000e+00 4.1301e-01 2.2804e-01 7.6491e-03 1.0088e-02 -6.0000e+00 1.7467e-01 5.8472e-05 -1.6402e-03 2.2209e-04 1.4804e-04 -6.0000e+00 1.3010e-02 -1.8546e-03 2.2276e-05 12 9 9 12 1 1 99.98 25.33 0.44 -0.00185 -0.01418 21 5 1 5 0 1139.720 32.50 20.00 25.33 20.24 9.3 939.22 -136550 -38029 -152623 -53324 -184721 -154666 -69612 -130814 -52269 -59881 -113698 -137955 -14438 10431 -60641 -73348 -81206 -31291 25309 25547 168658 -1981 -51180 -20685 15229 -80882 30253 -5435 -62779 15372 17133 23324 -20141 -30190 -15508 12294 65562 21339 54201 11828 58447 23678 -980 12874 14632 24333 -2763 4475 13853 7880 23856 49138 11284 6680 7521 17761 8516 15098 9891 14372 2889 10359 19822 4898 7809 14888 2847 1628 7043 2550 2781 10092 5621 -1997 4036 250 -4871 -252 -13577 -2141 -2694 -1911 -2747 2257 2564 -1116 -1011 -766 530 -462 -3758 -1474 -1380 -2941 302 -2910 -2542 -1871 -379 735 -1499 -1332 23 -1479 -516 -1598 -2147 -1953 -1410 249 -245 273 157 -1114 -129 1476 543 350 -918 575 301 342 872 1676 591 2274 2388 1857 155 1050 410 640 1230 1141 -560 234 -665 -637 -643 111 -608 -922 -482 -2926 -356 -4803 -607 -7173 -4142 -792 -2890 -560 -722 -2436 -4156 -155 112 -1665 -2750 -3751 -964 474 546 1242 -55 -2337 -716 381 -5421 668 -168 -3421 408 517 790 -1216 -2179 -959 561 1835 1053 2275 888 3099 1918 -107 1261 1433 2204 -336 521 1530 981 2758 4885 1795 1200 1418 3126 1675 2769 1865 2540 583 2090 4088 1317 2197 3947 841 495 2178 928 1120 3999 2339 -858 1504 88 -1654 -81 -5390 -883 -1315 -1065 -1720 1446 1743 -762 -727 -569 392 -337 -2685 -1061 -947 -2066 224 -2324 -2355 -1983 -440 874 -1763 -1438 22 -1406 -504 -1681 -2405 -2338 -1831 325 -358 429 254 -1800 -199 2137 785 523 -1463 946 501 556 1355 2497 856 3407 3472 2753 235 1776 777 1309 2449 2409 -1281 563 -1668 -1623 -1646 275 -1437 -2056 -1022 SS 20230909T125028.5Z 8652.535052 258 1 54.62 2 74.93 96.54 19.19 135.04 0.00 1 0.00 1 0 17 2.671e-01 2.750e-02 2.060e-01 1.033e-02 4.737586e-01 5.512839e-03 5.634850e-03 -6.000000e+00 1.613806e-01 229.62 -2.00 3.53 -2.00 319.86 0.00e+00 -5.213367e-03 1.713380e-03 6.338939e-04 -6.000000e+00 7.194058e-03 286.60 -2.00 20.00 -2.00 319.15 0.00e+00 3.771 0.001 302.00 328.00 3 5.5881e+00 1.6049e-02 4.4605e-02 -6.0000e+00 4.0183e-01 1.9352e-01 1.9284e-02 2.5298e-02 -6.0000e+00 4.3372e-01 -1.4365e-01 1.4880e-02 1.3421e-02 -6.0000e+00 2.5880e-01 6.2838e-02 7.5982e-03 5.8758e-03 -6.0000e+00 1.0951e-01 2.7238e-05 -4.2452e-04 3.2375e-04 6.5736e-05 -6.0000e+00 8.1478e-03 -3.5803e-03 1.1323e-04 12 8 8 10 0 0 99.98 25.48 0.79 -0.00358 -0.00677 51 5 1 5 0 1070.800 32.50 20.01 25.48 21.60 9.3 947.82 -81957 76103 -33068 117996 -101524 56100 -83560 -83367 -13926 98252 7872 -6777 -37663 11142 -24385 6957 -44061 37334 47735 74712 62446 19673 -46746 13549 12688 -63552 11494 -16383 -2901 5385 41560 9937 -18527 -14911 -5399 -19618 15903 -3627 12659 15069 30811 11655 -5189 18031 2185 8261 2426 -5316 -4974 9835 8027 28497 6156 -1325 11636 6160 6368 1445 667 2361 1064 5888 11054 2802 -2296 9178 -2909 1972 -613 -4655 -458 3196 1348 -2350 -154 1095 -3244 3465 -25423 -5918 -5102 -1549 -1521 1668 4952 1494 1176 1452 -623 1501 -472 409 -763 602 1394 -2433 -1496 4 2832 167 -3 -3121 53 -605 -453 -600 469 -2784 -2416 -309 -212 986 495 62 -890 -2628 -483 518 -1094 659 700 -993 1419 822 1192 2698 3289 3229 -1138 1885 -794 -117 1885 2960 -143 909 -1547 -149 -561 -201 -714 -1508 -1070 -2926 766 -848 1188 -4647 565 -3289 -3739 -357 989 187 -199 -1689 357 -1295 306 -3509 1401 1704 2120 2058 1008 -4835 831 859 -9831 852 -1545 -248 417 2385 871 -2388 -1967 -642 -2647 1601 -515 1848 2564 5088 2511 -1374 3831 541 1913 591 -1392 -1307 2298 2037 6427 1884 -470 3843 2246 2392 575 262 894 410 2282 4441 1329 -1195 4177 -1432 917 -309 -2733 -286 2044 889 -1557 -93 594 -1676 1601 -16281 -3492 -3416 -1129 -1218 1382 4228 1410 1175 1500 -661 1522 -460 367 -648 493 1190 -2394 -1645 5 3633 225 -4 -3853 59 -662 -520 -735 598 -3872 -3566 -439 -326 1575 798 96 -1451 -4110 -723 785 -1773 1105 1199 -1711 2314 1302 1798 3830 4457 4359 -1707 2996 -1403 -216 3566 5259 -276 1836 -3313 -320 -1219 -425 -1455 -2945 -2005 SS 20230909T130120.2Z 8652.542595 261 1 54.49 2 72.93 98.44 17.88 141.22 0.00 1 0.00 1 0 25 2.570e-02 5.322e-03 3.565e-03 5.028e-04 4.203846e-01 2.657036e-04 4.989009e-03 -6.000000e+00 1.553245e-02 229.62 -2.00 3.53 -2.00 318.33 0.00e+00 6.943262e-04 5.280446e-05 1.358009e-04 -6.000000e+00 6.923711e-04 286.60 -2.00 20.00 -2.00 317.55 0.00e+00 3.355 0.001 302.00 328.00 3 1.5023e+00 7.2077e-04 3.9534e-02 -6.0000e+00 3.8675e-02 1.3494e-02 8.1905e-04 2.2102e-02 -6.0000e+00 4.1741e-02 -2.0148e-02 5.4483e-04 1.0784e-02 -6.0000e+00 2.4908e-02 5.6264e-03 2.8298e-04 3.1039e-03 -6.0000e+00 1.0542e-02 2.7042e-03 -1.4258e-04 1.5340e-05 3.7141e-05 -6.0000e+00 7.8392e-04 -3.7958e-03 1.6102e-04 10 0 0 10 0 0 99.99 25.54 0.28 -0.00380 -0.00487 677 69 1 5 0 80.470 32.50 20.01 25.54 22.34 9.4 953.65 -8165 -5256 -3730 -9737 -10380 -13252 -11363 -4568 -4961 -4191 -7891 -5578 -4388 -3333 -2919 -379 -1002 334 -218 -1442 -76 -492 -959 -937 -671 -1872 -1226 -2753 -2381 -2273 532 504 -584 -1197 -2449 -2379 -1366 -853 631 55 -141 -515 -281 -150 7 -97 -45 -332 -171 330 828 1357 1340 1308 1164 1095 897 512 458 669 1007 1454 1821 1259 785 513 126 121 586 784 112 -54 -221 -329 -360 -405 -311 -174 -438 -487 -940 -1263 -1578 -1487 -965 -772 -629 -247 -129 36 382 564 491 794 857 636 526 280 -71 -213 -349 -532 -170 91 -593 -922 -803 -438 -372 79 70 -180 -3 122 266 483 521 435 133 -194 -340 -166 -112 134 491 532 683 1092 777 395 287 83 29 172 -86 -117 -67 -70 -331 -293 -158 -294 -292 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