File name: Pandora249s1_ChicagoIL_20231028_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20231102T113517.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231028_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231028T141417.9Z 8701.593263 320 1 54.06 2 71.81 128.16 111.63 310.67 0.00 1 0.00 1 0 17 1.328e-01 1.811e-02 4.630e-02 5.544e-03 3.749139e-01 2.893565e-03 4.613047e-03 -6.000000e+00 7.875884e-02 224.52 -2.00 3.53 -2.00 318.93 0.00e+00 -3.437493e-04 6.618369e-04 2.885573e-04 -6.000000e+00 3.492264e-03 280.77 -2.00 20.00 -2.00 318.25 0.00e+00 3.161 0.001 302.00 328.00 3 5.5288e+00 7.9131e-03 3.6420e-02 -6.0000e+00 1.9417e-01 1.4135e-01 9.0940e-03 1.9712e-02 -6.0000e+00 2.1053e-01 -7.4852e-02 6.2861e-03 9.7313e-03 -6.0000e+00 1.2568e-01 3.1409e-02 3.2559e-03 2.8444e-03 -6.0000e+00 5.3461e-02 5.9006e-05 -1.3931e-03 1.7624e-04 3.7948e-05 -6.0000e+00 4.0444e-03 -8.3753e-03 5.7927e-05 12 8 8 10 0 0 99.99 24.43 0.05 -0.00838 -0.01884 62 6 1 5 0 871.840 32.00 20.25 24.43 11.46 9.1 878.88 -35802 -32742 -36079 28857 -43213 56858 -43952 -28359 -8280 57393 -19289 -38937 6564 35854 -19440 15108 -6175 964 -467 -1817 20622 -6923 -6363 -9506 22179 -21850 23415 12114 -8139 7360 22925 1606 -14310 -13384 4042 -7329 -11572 7593 4767 -3494 8111 2844 3829 574 -454 936 5042 -3470 10475 -3523 5773 9240 5498 -705 149 3820 -826 2895 -1689 412 -4168 4088 9643 523 2526 2368 -1673 -37 1407 -2599 -713 1247 2658 -2763 -373 628 -5938 -941 -10718 -1348 -2921 -2417 -1653 -1292 3034 1222 -544 396 897 -290 -715 -654 22 1612 1588 -2952 -761 1096 1274 223 -1154 -779 18 -1003 -806 -1697 -314 279 -1635 735 714 785 999 -67 -412 -705 390 -10 -970 199 -1448 470 426 518 1152 1567 2261 385 -206 432 278 -988 2016 1773 -631 838 -578 -950 -902 323 -965 84 -584 -1725 -1722 -2057 837 -2379 1199 -2376 -1595 -425 1645 -1231 -3158 376 1783 -1955 1217 -668 103 -53 -217 2018 -898 -836 -1357 2458 -3946 2722 1526 -1193 907 2541 242 -2778 -2721 682 -1351 -2334 1441 1108 -1041 2425 963 1335 211 -169 343 1764 -1308 3421 -1343 2104 3502 2325 -337 74 1894 -439 1490 -897 211 -2260 2155 5229 336 1651 1511 -1051 -22 866 -1839 -548 1000 2136 -2281 -283 429 -3936 -560 -7174 -907 -2265 -2090 -1549 -1284 3066 1221 -585 439 1000 -321 -748 -632 21 1492 1516 -2935 -829 1308 1646 299 -1505 -938 20 -1104 -929 -2105 -404 376 -2375 1118 1164 1334 1690 -109 -633 -1017 540 -14 -1463 315 -2397 761 673 789 1668 2154 2951 504 -285 641 443 -1679 3432 3137 -1202 1660 -1102 -1860 -1782 620 -1974 163 -1100 SS 20231028T142402.7Z 8701.600031 326 1 53.76 2 70.41 130.19 112.89 312.73 0.00 1 0.00 1 0 25 2.194e-01 2.953e-02 9.019e-02 8.324e-03 3.501540e-01 4.321102e-03 4.453863e-03 -6.000000e+00 1.295926e-01 224.52 -2.00 3.53 -2.00 318.62 0.00e+00 5.180997e-04 8.978046e-04 2.101612e-04 -6.000000e+00 5.762588e-03 280.77 -2.00 20.00 -2.00 317.95 0.00e+00 2.949 0.000 302.00 328.00 3 6.2506e+00 1.1682e-02 3.4055e-02 -6.0000e+00 3.1946e-01 1.9100e-01 1.3304e-02 1.8589e-02 -6.0000e+00 3.4689e-01 -9.2892e-02 8.8458e-03 9.2014e-03 -6.0000e+00 2.0704e-01 4.1273e-02 4.5852e-03 2.7327e-03 -6.0000e+00 8.7711e-02 3.5346e-05 -5.9057e-03 2.6156e-04 3.6116e-05 -6.0000e+00 6.6918e-03 -2.0817e-03 -8.4687e-04 12 9 8 11 8 0 99.99 24.45 -0.28 -0.00208 -0.04646 20 2 1 5 0 2687.640 32.00 20.16 24.45 11.59 9.2 880.42 -52614 -24652 -40235 17744 -42678 159698 -52963 -39973 3787 72843 49510 -36260 28051 82646 6624 14956 -1647 17645 4754 68345 27260 2753 -12464 -3754 7702 -31466 15733 15191 -13074 26100 19729 13436 -13724 -5830 10995 -85 -15322 3476 4321 -8748 9134 6938 5399 8290 4307 -1224 3253 -5201 13965 -7221 3478 13611 3023 -3182 -2141 10304 -2652 7319 -1278 39 -8167 4390 12407 968 2099 1602 -2751 2330 -882 -5664 99 874 8495 -4950 -1040 1605 -6569 -3630 -15925 -5567 -2597 -3991 936 1181 5841 1559 2259 -751 1677 -1459 -1612 -1256 133 -209 1673 -5098 -813 766 1635 1544 -572 -1908 962 -3720 15 -320 0 1623 238 31 -408 2914 92 -998 -660 -1087 2190 1245 -2743 -136 -2559 76 422 945 777 1705 3432 -38 249 826 563 -1741 4151 3100 -1608 -38 -716 -2141 -498 580 -1339 19 -333 -4387 -1728 -3415 812 -3275 1532 -4377 -3186 215 2204 1936 -3479 1573 3422 616 1578 -221 2048 656 5160 3164 409 -2185 -631 1219 -7663 2401 2244 -2430 3220 2723 2159 -3153 -1297 2026 -17 -3756 804 1175 -3174 3099 2568 2104 3190 1727 -518 1304 -2238 4920 -3177 1437 5447 1438 -1705 -1185 5177 -1546 3868 -724 21 -4952 2480 7020 661 1462 1086 -1834 1432 -579 -4304 79 728 6648 -4308 -817 1119 -4506 -2278 -11492 -3986 -2040 -3551 863 1154 5771 1715 2610 -844 2045 -1795 -1874 -1342 130 -195 1575 -5604 -956 986 2054 1982 -721 -2487 1133 -4509 19 -420 0 2302 329 45 -646 4644 150 -1572 -965 -1640 3101 1812 -3973 -204 -4053 117 632 1494 1175 2432 4594 -52 352 1252 916 -2758 7025 4983 -2842 -70 -1369 -4242 -979 1113 -2526 33 -574 SS 20231028T150343.8Z 8701.627591 348 1 8.27 2 65.16 138.95 117.56 321.60 0.00 1 0.00 1 0 17 1.027e-02 5.658e-03 2.543e-03 1.129e-03 2.864246e-01 5.911749e-04 3.508889e-03 -6.000000e+00 6.096383e-03 224.52 -2.00 3.53 -2.00 316.42 0.00e+00 1.951543e-04 6.972082e-05 5.152320e-05 -6.000000e+00 2.701873e-04 280.77 -2.00 20.00 -2.00 315.78 0.00e+00 2.365 0.000 302.00 328.00 3 2.4136e+00 1.5276e-03 2.7234e-02 -6.0000e+00 1.5030e-02 2.3867e-02 1.7071e-03 1.4617e-02 -6.0000e+00 1.6291e-02 -6.8726e-03 9.9474e-04 7.2443e-03 -6.0000e+00 9.7260e-03 1.4212e-03 4.6850e-04 2.0783e-03 -6.0000e+00 4.1405e-03 3.3408e-03 2.0135e-04 3.4888e-05 2.8151e-05 -6.0000e+00 3.1270e-04 -1.0197e-02 2.1490e-04 12 1 1 12 1 1 99.89 24.57 0.29 -0.01020 -0.00868 46 31 1 5 0 175.700 32.00 19.82 24.57 12.90 9.2 889.38 -1072 -1439 -2563 -4640 -4326 -3742 -3414 -691 147 -1919 -2228 -1478 541 888 1027 1004 -83 74 645 632 1208 865 519 869 536 581 -266 -1070 -1017 65 1676 1093 1120 -386 -1440 -1104 -779 10 652 -97 -468 -433 -706 -595 -446 -371 -542 -796 -425 -64 1126 1271 1119 992 392 527 910 265 243 550 884 1243 1457 945 73 -79 -50 -302 537 674 -7 -447 -84 -278 -315 -162 202 261 314 -105 -880 -1158 -1616 -1312 -1011 -886 -743 -313 -143 -249 58 341 667 1028 967 480 427 317 -205 -252 -283 -457 -2 261 -295 -832 -826 -543 -408 39 121 -144 35 -83 238 507 682 544 313 -66 -376 -111 -37 83 648 484 809 1106 928 379 276 3 -50 270 -91 -30 -43 -150 -468 -441 -108 -361 -390 -173 -237 -445 -797 -743 -604 -563 -122 26 -373 -445 -302 119 222 271 295 -26 23 207 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