File name: Pandora249s1_ChicagoIL_20231115_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20231116T090937.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231115_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231115T131548.8Z 8719.552648 52 1 54.15 2 85.02 120.45 110.60 109.44 0.00 1 0.00 1 0 25 5.978e-01 6.681e-02 2.610e-01 2.407e-02 1.053131e+00 1.473453e-02 1.425070e-02 -6.000000e+00 3.699874e-01 222.93 -2.00 3.53 -2.00 321.80 0.00e+00 -3.896297e-02 4.672048e-03 1.346078e-03 -6.000000e+00 1.758687e-02 278.51 -2.00 20.00 -2.00 321.24 0.00e+00 9.863 0.018 302.00 328.00 3 2.3788e-01 4.6469e-02 1.1425e-01 -6.0000e+00 9.0995e-01 2.2230e+00 5.4002e-02 8.0914e-02 -6.0000e+00 9.9270e-01 -2.2756e+00 3.1056e-02 2.8268e-02 -6.0000e+00 5.8802e-01 7.8319e-01 1.7201e-02 3.2745e-02 -6.0000e+00 2.4752e-01 8.1088e-06 -2.7200e-03 6.4235e-04 6.0161e-04 -6.0000e+00 1.9124e-02 -1.0528e-02 1.4286e-04 12 8 8 10 0 0 41.19 24.55 1.73 -0.01053 -0.03097 30 3 1 5 0 1804.920 32.00 20.18 24.55 12.90 9.2 888.57 1062 29096 7970 79068 -5679 900000 -36988 900000 60211 900000 112352 -2632 160571 900000 10292 140059 53185 96832 58572 900000 900000 13357 -49299 29612 94550 -30713 900000 188980 -25392 900000 900000 85677 -45907 -6154 900000 -47854 -40027 79238 118455 -7698 900000 57231 90960 81350 12346 15330 91245 -42309 900000 -7541 82051 150950 126565 17497 36546 184078 30970 280652 53471 96550 -32791 111658 900000 -1018 59499 45721 -3965 34863 15848 -19997 4945 56942 126715 -25450 51630 47278 -32440 14991 -58493 4093 -15757 20117 27125 42707 96117 22924 24896 18818 31217 7605 -13203 4228 -4667 11044 28000 -20010 -1785 5480 14711 -1837 -1865 -9526 -919 -12851 2340 -2208 -1377 2422 -12160 3126 -4299 638 2374 -4151 2818 -1950 2136 6078 -4753 3257 -3897 -830 -4185 1761 2085 8012 13938 2177 -1724 571 -2009 -5047 6726 6794 -1110 1398 -3892 -3968 73 2358 -768 999 -300 174 3350 995 4012 -543 900000 -4547 900000 3995 900000 5262 -395 5128 900000 1446 5367 4755 5360 4489 900000 900000 1280 -9026 2837 5636 -7062 900000 4425 -3730 900000 900000 3648 -7721 -707 900000 -7335 -5709 3880 4791 -1344 900000 6336 6971 6235 1656 1762 4468 -7476 900000 -979 4716 4820 5658 2533 4746 5878 4813 6572 6147 7009 -7051 6014 900000 -196 6688 5996 -854 5307 3192 -6509 1390 10001 10979 -9417 7859 6532 -8888 2492 -21779 939 -5203 5418 7750 11401 15981 8321 9153 7447 10746 3170 -6338 1604 -1901 4034 9704 -13073 -1137 3747 10266 -1588 -1568 -7919 -627 -9209 1463 -1525 -997 1815 -11703 2972 -5114 818 3219 -6173 3873 -2740 2846 7942 -7191 4683 -5959 -1174 -5792 2210 2534 8931 14361 2595 -2402 913 -3816 -11085 14381 15767 -2747 3603 -10970 -11337 201 6681 -2090 2452 -696 SS 20231115T132740.8Z 8719.560889 55 1 54.28 2 83.14 122.56 108.63 111.11 0.00 1 0.00 1 0 25 5.915e-01 1.813e-02 2.444e-01 4.189e-03 8.743870e-01 2.414354e-03 9.722331e-03 -6.000000e+00 3.498686e-01 222.93 -2.00 3.53 -2.00 321.80 0.00e+00 1.663003e-03 1.341285e-03 2.768714e-03 -6.000000e+00 1.617048e-02 278.51 -2.00 20.00 -2.00 321.36 0.00e+00 7.665 0.008 302.00 328.00 3 6.4282e-01 8.8889e-03 8.9999e-02 -6.0000e+00 8.6127e-01 5.8492e-01 1.3131e-02 5.4655e-02 -6.0000e+00 9.3532e-01 -7.8655e-01 1.3711e-02 2.7973e-02 -6.0000e+00 5.5685e-01 3.1748e-01 6.2633e-03 9.2516e-03 -6.0000e+00 2.3818e-01 7.0981e-05 -1.3233e-03 1.1785e-04 1.3059e-04 -6.0000e+00 1.8261e-02 -1.2520e-02 2.0376e-04 12 8 8 10 0 0 27.77 24.57 0.69 -0.01252 -0.02246 116 12 1 5 0 467.860 32.00 20.10 24.57 13.26 9.2 891.94 -267578 -181711 -146098 -86873 900000 -6328 -240961 -182458 -109893 900000 -130517 -196064 -36193 900000 -174092 129255 -92255 -18051 -17593 55398 147742 -45732 -44531 -82960 -15278 -131880 89893 -34481 -75227 -58096 900000 -31829 -60742 -22575 47495 -17417 -17610 21364 54775 -2415 69933 38399 14020 22649 -179 9742 41003 -1376 86086 13718 29241 66798 32352 17539 17425 24390 23980 28011 8307 15837 -130 19281 27712 13627 15886 17825 9371 8339 8229 3155 6361 9709 12231 70 7556 3641 -2635 -140 -16867 -3586 -2702 -345 459 81 4471 1937 2159 899 2451 -94 -460 38 -1896 -1239 -301 -4047 -2810 -703 13 -637 -1227 -1672 -2299 -1493 -1773 -1691 -1480 -1253 -1947 -577 -1419 -1166 83 459 223 -240 122 214 -519 579 -41 413 1252 791 1256 1598 2438 1242 561 590 290 210 938 1048 -128 362 -331 -564 -467 74 -298 -746 -639 -6355 -2158 -1301 -419 900000 -26 -4739 -2167 -693 900000 -1162 -3784 -175 900000 -5492 528 -1815 -188 -196 308 603 -696 -678 -1970 -198 -5775 477 -619 -1996 -1376 900000 -832 -2504 -700 737 -505 -532 497 1096 -103 1656 1364 670 1017 -10 505 1590 -85 2355 840 1707 3027 2311 1597 1714 2360 2408 2710 950 1616 -16 2015 3009 1953 2464 2823 1637 1535 1656 759 1659 2608 3225 20 1820 819 -582 -30 -4751 -1049 -942 -138 207 40 2247 1061 1128 492 1330 -51 -263 20 -1008 -676 -181 -2700 -2195 -629 13 -677 -1279 -1610 -2006 -1219 -1489 -1506 -1396 -1272 -2204 -674 -1910 -1738 129 718 342 -357 179 323 -830 952 -67 657 1883 1154 1765 2171 3214 1700 861 1047 544 435 2082 2316 -306 918 -874 -1517 -1256 193 -732 -1710 -1488 SS 20231115T133830.0Z 8719.568403 58 1 54.40 2 81.47 124.52 106.86 112.65 0.00 1 0.00 1 0 25 5.548e-01 8.439e-03 1.074e-01 1.683e-03 7.569051e-01 9.207592e-04 8.574401e-03 -6.000000e+00 3.274283e-01 222.93 -2.00 3.53 -2.00 321.01 0.00e+00 2.069690e-03 4.287102e-04 8.048256e-04 -6.000000e+00 1.446089e-02 278.51 -2.00 20.00 -2.00 320.52 0.00e+00 6.353 0.005 302.00 328.00 3 5.7335e-01 2.9929e-03 7.3564e-02 -6.0000e+00 8.0503e-01 1.3595e-01 4.2055e-03 4.1424e-02 -6.0000e+00 8.7376e-01 -1.7113e-01 4.4832e-03 2.2168e-02 -6.0000e+00 5.2154e-01 6.1440e-02 2.1442e-03 7.9807e-03 -6.0000e+00 2.2237e-01 3.0107e-04 -4.4340e-04 4.6821e-05 9.5856e-05 -6.0000e+00 1.6881e-02 -1.2781e-02 2.1461e-04 11 8 0 10 0 0 12.00 24.62 0.47 -0.01278 -0.01611 262 27 1 5 0 207.600 32.00 19.88 24.62 13.79 9.2 895.07 -225401 -199355 -158282 -161363 -98586 -183836 -232080 -209123 -106262 -29420 -151595 -119981 -140990 -92319 -131335 -58599 -58195 -57159 -40087 -68841 -17611 -27943 -66171 -50413 -34831 -69691 -18166 -39579 -35332 -52865 -6318 -22056 -41872 -19590 -13134 -22063 -13931 -5459 -6621 -3520 6082 3974 1564 -713 505 -1496 3756 -1939 6247 4418 1657 12502 5759 6425 5520 6529 3871 5173 -790 1667 423 3244 5570 2289 3864 2562 2379 1705 2287 1556 1705 1085 2966 -820 -62 -968 -2075 -799 -4302 -753 -1801 -932 -1070 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