File name: Pandora249s1_ChicagoIL_20231206_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T082725.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20231206_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231206T134147.4Z 8740.570688 275 1 53.70 2 84.98 126.56 41.75 200.31 0.00 1 0.00 1 0 25 8.268e-01 1.349e-01 2.852e-01 4.042e-02 1.096814e+00 2.424367e-02 1.388182e-02 -6.000000e+00 4.992842e-01 222.64 -2.00 3.53 -2.00 320.06 0.00e+00 -3.259964e-02 4.004519e-03 2.612619e-03 -6.000000e+00 2.221233e-02 276.17 -2.00 20.00 -2.00 319.28 0.00e+00 9.817 0.018 302.00 328.00 3 4.5743e-01 6.5837e-02 1.1765e-01 -6.0000e+00 1.2245e+00 2.9971e+00 7.5899e-02 8.8311e-02 -6.0000e+00 1.3312e+00 -2.3063e+00 4.2109e-02 2.7192e-02 -6.0000e+00 7.9573e-01 6.2667e-01 2.1203e-02 2.7852e-02 -6.0000e+00 3.3935e-01 4.1274e-06 -4.3789e-03 9.7389e-04 3.9894e-04 -6.0000e+00 2.5766e-02 -4.6263e-03 0.0000e+00 12 8 8 10 0 0 96.65 24.05 2.21 -0.00463 -0.03753 15 2 1 5 0 3579.550 31.75 19.71 24.05 7.10 9.0 849.43 900000 33097 -3581 104836 -18970 900000 -45003 -22431 18293 91050 209593 -85 121537 900000 48421 140055 63182 106655 28299 900000 129052 3317 2687 25960 122420 -26436 125964 445729 -11041 900000 900000 68518 -18634 -28548 130681 -30000 -13892 21713 29889 -25069 356491 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6.8524e-01 7.1274e-03 1.4572e-02 -6.0000e+00 2.4200e-01 3.0971e-05 -2.5224e-03 1.7385e-04 2.9060e-04 -6.0000e+00 1.8479e-02 -5.4391e-03 0.0000e+00 12 8 8 10 0 0 99.13 24.08 0.62 -0.00544 -0.02439 68 7 1 5 0 804.980 31.75 20.09 24.08 7.86 9.0 854.59 900000 -38509 -74700 51782 -67185 900000 -102168 -103386 -4332 268619 -74720 -103445 8686 900000 -73431 46013 -22184 70159 62165 34198 151248 55132 -28138 13504 46388 -75539 305516 187577 -46731 -7983 900000 35302 -45334 -37806 164698 -14828 -2308 139869 35804 2704 112922 40459 87625 41980 36042 8349 70196 -313 152147 45214 77716 107849 49403 37243 54294 74942 40046 67753 25062 44554 -2488 77907 78386 21947 50733 33409 12380 16625 23735 11859 17386 29229 38316 -2875 22894 3374 -15082 7909 -22222 -3516 -4416 -856 1739 3153 13126 4006 6497 511 3923 1536 -3016 -1880 -2104 -1997 -1664 -8111 -5690 -2035 324 -1576 -3200 -4694 -837 -8034 -878 -3539 -2633 -2572 -3543 -1700 -3125 -1925 50 -406 -152 -904 1297 1127 -129 365 -255 1237 1777 2466 2231 4544 4293 1649 -26 777 657 -121 2522 916 -240 717 -162 -1108 -941 41 -100 -983 -1564 900000 -1222 -3363 598 -2171 900000 -3951 -4296 -73 1705 -2760 -5373 165 900000 -4323 929 -960 1255 1220 868 1135 1018 -1169 390 1044 -6017 1940 1191 -2293 -258 900000 937 -3061 -2531 1568 -800 -110 1776 1523 191 3011 2389 3282 2425 2105 615 2718 -25 2705 2497 3404 3903 3544 3287 4343 5138 4017 5119 2753 3734 -317 4550 5026 2801 5347 4348 2012 2702 3918 2492 3852 6087 7273 -776 4302 681 -3332 1381 -5770 -895 -1363 -300 677 1321 5300 1872 3090 265 1963 763 -1484 -864 -950 -941 -880 -5396 -3994 -1614 284 -1489 -3003 -4104 -630 -6065 -691 -2751 -2152 -2272 -3519 -1910 -4126 -2829 77 -642 -236 -1379 1922 1716 -207 605 -422 1933 2619 3474 3054 5906 5483 2224 -40 1389 1241 -258 5673 2258 -594 1866 -441 -3064 -2585 107 -244 -2413 -3605 SS 20231206T150406.9Z 8740.627858 318 1 54.46 2 74.07 142.40 50.35 225.96 0.00 1 0.00 1 0 25 9.534e-02 6.261e-03 1.376e-02 1.051e-03 5.136184e-01 5.482163e-04 6.141397e-03 -6.000000e+00 5.618313e-02 222.64 -2.00 3.53 -2.00 319.14 0.00e+00 1.288714e-03 1.385851e-04 2.565990e-04 -6.000000e+00 2.467744e-03 276.17 -2.00 20.00 -2.00 318.59 0.00e+00 3.581 0.001 302.00 328.00 3 2.7979e+00 1.5054e-03 4.3624e-02 -6.0000e+00 1.3816e-01 5.8812e-02 1.7499e-03 2.6418e-02 -6.0000e+00 1.5017e-01 -4.3530e-02 1.3888e-03 1.3356e-02 -6.0000e+00 8.9470e-02 1.2945e-02 7.3869e-04 4.1596e-03 -6.0000e+00 3.8234e-02 5.2861e-04 -8.1749e-04 3.1408e-05 5.0566e-05 -6.0000e+00 2.9188e-03 -3.8843e-03 0.0000e+00 10 0 0 10 0 0 99.98 24.21 0.31 -0.00388 -0.01003 197 20 1 5 0 276.430 31.75 19.95 24.21 8.25 9.0 856.20 900000 -33066 -33702 -33885 -33478 -32457 -45565 -33656 -26003 -20187 -27687 -22379 -10977 -5473 -21637 -5816 -7760 -2450 -4335 -5633 -564 -762 -5140 -5029 -775 -11488 -460 -1843 -5485 -6583 1562 -1654 -4460 -3464 -863 -3465 -3249 -937 448 -910 476 -1146 408 -279 164 -13 294 -646 1462 333 1315 2059 2125 1852 1567 1144 1008 1062 411 889 664 2039 2160 1221 1149 1257 737 773 1068 507 53 157 -14 -423 -134 -318 -253 208 -1032 -887 -1347 -1094 -1563 -1562 -1067 -1039 -818 -349 92 -62 376 448 477 852 1013 425 340 317 9 -135 -339 -661 -201 -79 -625 -930 -823 -523 -443 -36 129 -109 14 19 275 558 533 501 69 -178 -504 -187 -100 143 456 536 933 1211 808 446 272 80 262 200 -87 -124 -136 -115 -376 -305 -209 -286 -218 900000 -691 -777 -792 -737 -675 -1111 -807 -653 -525 -825 -683 -348 -201 -1142 -311 -479 -157 -306 -425 -42 -58 -418 -434 -69 -1214 -45 -180 -539 -664 159 -199 -630 -527 -129 -523 -514 -165 85 -210 124 -332 123 -87 52 -4 95 -213 482 116 485 758 854 806 727 556 506 537 206 437 331 1067 1151 726 726 791 451 470 684 338 40 125 -10 -332 -98 -212 -166 130 -687 -618 -1089 -935 -1390 -1489 -1076 -1051 -873 -385 102 -67 384 453 452 789 990 439 400 398 12 -183 -442 -842 -235 -94 -743 -1179 -1040 -698 -602 -54 197 -177 22 30 412 828 772 743 103 -280 -811 -296 -153 221 675 758 1332 1722 1171 680 454 135 464 354 -163 -237 -267 -232 -732 -607 -396 -539 -394 SS 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