File name: Pandora249s1_ChicagoIL_20231208_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240113T145809.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231208_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231208T134248.1Z 8742.571390 197 1 54.74 2 85.13 126.73 51.79 172.22 0.00 1 0.00 1 0 25 7.897e-01 1.177e-01 3.045e-01 3.998e-02 1.028239e+00 2.472927e-02 1.304936e-02 -6.000000e+00 4.889082e-01 222.61 -2.00 3.53 -2.00 320.90 0.00e+00 -4.261962e-02 5.116827e-03 4.235803e-03 -6.000000e+00 2.443037e-02 275.95 -2.00 20.00 -2.00 320.21 0.00e+00 10.037 0.019 302.00 328.00 3 3.8962e-01 6.9956e-02 1.2577e-01 -6.0000e+00 1.1992e+00 2.5559e+00 8.0830e-02 1.1213e-01 -6.0000e+00 1.3080e+00 -2.1241e+00 4.5280e-02 2.5728e-02 -6.0000e+00 7.7598e-01 6.3453e-01 2.3846e-02 3.8370e-02 -6.0000e+00 3.2749e-01 4.6893e-06 -4.6268e-03 1.0496e-03 5.4873e-04 -6.0000e+00 2.5476e-02 -1.2515e-02 1.9551e-04 12 8 8 10 0 0 85.85 24.55 2.40 -0.01251 -0.04728 17 2 1 5 0 3219.340 32.00 19.85 24.55 12.95 9.2 889.14 38659 -1353 -16022 285548 -25937 900000 31901 -31705 105627 185489 900000 10594 163453 900000 54908 94446 85225 351686 111095 900000 900000 54073 -16683 61002 104923 -34323 900000 900000 9942 900000 900000 91255 -21820 -28880 900000 -19931 -18538 253170 22776 11201 379288 15730 106173 90534 53283 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-18904 10740 10523 -17354 5996 -44187 -610 -4662 -4723 12399 17723 19820 17587 20097 12113 17248 2183 -15357 289 1448 9051 11731 -17568 1240 7214 21692 2394 5255 -18239 12352 -21427 4648 4964 -3319 4665 1729 3805 1525 15744 1656 1459 1305 -10609 17618 14152 -5395 -850 -11188 -6982 -750 -2908 483 5098 16622 -2212 -13523 -2550 -6355 -19994 33928 29759 -19367 9893 -18414 -18141 141 11653 -538 2804 16131 SS 20231208T135446.9Z 8742.579710 200 1 54.86 2 83.37 128.87 51.61 175.92 0.00 1 0.00 1 0 25 5.617e-01 2.634e-02 2.720e-01 6.037e-03 8.405203e-01 3.418387e-03 9.464173e-03 -6.000000e+00 3.327398e-01 222.61 -2.00 3.53 -2.00 321.81 0.00e+00 2.920912e-03 1.789157e-03 1.400964e-03 -6.000000e+00 1.506587e-02 275.95 -2.00 20.00 -2.00 321.37 0.00e+00 7.891 0.009 302.00 328.00 3 9.1237e-01 1.2266e-02 8.9474e-02 -6.0000e+00 8.1900e-01 8.8911e-01 1.6025e-02 4.7488e-02 -6.0000e+00 8.9006e-01 -1.1746e+00 1.4583e-02 2.4475e-02 -6.0000e+00 5.2836e-01 4.8076e-01 6.9160e-03 7.9374e-03 -6.0000e+00 2.2497e-01 4.2840e-05 -2.0327e-03 1.7403e-04 1.2231e-04 -6.0000e+00 1.7108e-02 -1.2987e-02 1.6945e-04 12 8 8 10 0 0 67.14 24.56 0.85 -0.01299 -0.02826 74 7 1 5 0 741.220 32.00 20.00 24.56 13.15 9.2 890.91 -155481 -76039 -124180 17470 -47381 900000 -161226 -122052 45739 900000 -7833 -104595 41889 79464 -108666 296246 -5966 153792 32817 33586 156715 30036 -14611 30358 25802 -99510 110059 134019 -32764 20168 900000 28911 -48429 -23789 74078 -27609 5866 183179 56671 7974 119648 824 76787 30834 19137 13562 68380 16508 118420 28048 49257 86433 48385 34020 26666 47854 27457 34002 16038 13404 10266 34029 37596 22465 38697 32051 11079 12751 20013 2910 8978 12227 20842 1283 16693 13921 -9903 4465 -19897 -979 -2600 -1582 1396 1912 7310 1118 2415 -1223 1305 -1242 -1938 -1277 -5967 -216 -1128 -7750 -4066 -1734 -966 -895 -1369 -3979 -701 -4027 -1101 -2784 -2397 -2100 -4126 -1425 -779 -1192 -1077 -62 142 -425 877 720 -1082 1074 897 1457 554 2062 1827 2662 3722 1653 842 1270 200 134 2330 1100 -138 448 -340 -714 -989 -527 -467 -425 -1262 -6820 -1708 -4650 150 -684 900000 -6296 -3330 269 900000 -75 -2854 314 510 -5639 1743 -147 905 614 629 922 546 -406 552 511 -7027 942 860 -1069 399 900000 783 -2979 -1358 1569 -1543 238 1401 1801 483 2675 65 2937 1887 1306 974 2857 1185 3205 1997 3101 4171 3758 3303 2966 4477 3215 3702 2010 1648 1287 3544 4226 3331 5351 4885 2086 2431 3827 743 2404 3360 5274 375 3821 2933 -2424 938 -5831 -280 -901 -634 614 908 3502 605 1354 -735 771 -736 -1098 -677 -3206 -112 -655 -5605 -3045 -1481 -924 -902 -1355 -3727 -573 -3212 -874 -2387 -2174 -2046 -4527 -1728 -1071 -1825 -1593 -92 223 -647 1306 1105 -1776 1649 1388 2367 869 3076 2646 3707 5011 2318 1319 2092 378 279 5131 2623 -330 1129 -896 -1914 -2663 -1374 -1146 -1050 -2969 SS 20231208T140539.5Z 8742.587263 203 1 54.41 2 81.82 130.86 51.57 179.28 0.00 1 0.00 1 0 25 5.620e-01 1.082e-02 1.137e-01 2.221e-03 7.392406e-01 1.208907e-03 8.332376e-03 -6.000000e+00 3.313053e-01 222.61 -2.00 3.53 -2.00 321.09 0.00e+00 2.301538e-03 5.562231e-04 1.081913e-03 -6.000000e+00 1.449697e-02 275.95 -2.00 20.00 -2.00 320.63 0.00e+00 6.598 0.005 302.00 328.00 3 8.2057e-01 3.9072e-03 7.4923e-02 -6.0000e+00 8.1472e-01 2.0957e-01 5.4193e-03 4.0073e-02 -6.0000e+00 8.8484e-01 -2.6677e-01 5.7697e-03 2.2196e-02 -6.0000e+00 5.2745e-01 1.0329e-01 2.7777e-03 7.8175e-03 -6.0000e+00 2.2453e-01 1.9058e-04 -5.0315e-04 6.3235e-05 1.0174e-04 -6.0000e+00 1.7098e-02 -1.3934e-02 2.0394e-04 12 8 8 10 0 0 20.99 24.58 0.54 -0.01393 -0.01771 184 19 1 5 0 295.670 32.00 20.25 24.58 13.51 9.2 892.72 -233341 -195733 -204413 -157195 -186045 -176922 -214299 -167547 -99387 -20276 -166970 -152630 -100532 13271 -129511 -24144 -84089 -24795 -10436 -58758 -2487 -59647 -58124 -53211 -30985 -77453 -3143 -38667 -41493 -63204 24091 -17529 -45105 -30467 22805 -18734 -10207 -1581 379 -4824 10203 -4885 5000 1922 1431 -328 10385 325 10928 3817 8361 13262 11444 5396 5165 7089 6123 7542 334 3500 1835 7055 7639 4084 5338 6209 2659 3234 3925 1338 1922 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