File name: Pandora249s1_ChicagoIL_20231230_L2Fit_fwvt1c2d20230104p1-8.txt File generation date: 20240113T071700.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231230_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0095 492.1302 492.2510 492.3717 492.4924 492.6131 492.7337 492.8544 492.9750 493.0956 493.2162 493.3368 493.4574 493.5779 493.6985 493.8190 493.9395 494.0600 494.1805 494.3009 494.4213 494.5418 494.6622 494.7825 494.9029 495.0233 495.1436 495.2639 495.3842 495.5045 495.6248 495.7450 495.8652 495.9855 496.1057 496.2258 496.3460 496.4662 496.5863 496.7064 496.8265 496.9466 497.0667 497.1867 497.3067 497.4268 497.5468 497.6667 497.7867 497.9066 498.0266 498.1465 498.2664 498.3863 498.5061 498.6260 498.7458 498.8656 498.9854 499.1052 499.2250 499.3447 499.4644 499.5841 499.7038 499.8235 499.9432 500.0628 500.1824 500.3021 500.4216 500.5412 500.6608 500.7803 500.8998 501.0194 501.1388 501.2583 501.3778 501.4972 501.6166 501.7361 501.8554 501.9748 502.0942 502.2135 502.3328 502.4521 502.5714 502.6907 502.8099 502.9292 503.0484 503.1676 503.2868 503.4060 503.5251 503.6442 503.7634 503.8825 504.0015 504.1206 504.2397 504.3587 504.4777 504.5967 504.7157 504.8347 504.9536 505.0725 505.1914 505.3103 505.4292 505.5481 505.6669 505.7857 505.9046 506.0233 506.1421 506.2609 506.3796 506.4983 506.6171 506.7357 506.8544 506.9731 507.0917 507.2103 507.3289 507.4475 507.5661 507.6846 507.8032 507.9217 508.0402 508.1587 508.2772 508.3956 508.5140 508.6325 508.7508 508.8692 508.9876 509.1059 509.2243 509.3426 509.4609 509.5792 509.6974 509.8157 509.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231230T132543.3Z 8764.559529 259 1 45.43 2 89.70 122.26 63.10 271.82 0.00 1 0.00 1 0 22 9.827e-03 9.723e-03 2.574e-04 2.556e-04 9.439567e+03 1.684746e+01 6.279979e+02 -6.000000e+00 5.451238e+02 274.23 -2.00 20.00 -2.00 505.45 0.00e+00 7.396735e-03 7.076733e-06 3.987800e-04 -6.000000e+00 2.734056e-04 274.23 -2.00 20.00 -2.00 501.27 0.00e+00 9.326450e-01 4.956883e-03 1.018382e-01 -6.000000e+00 1.972196e-01 223.02 -2.00 3.53 -2.00 502.73 0.00e+00 20.272 0.157 489.00 513.00 1 2.7246e+00 3.7878e-04 3.7988e-02 -6.0000e+00 1.5121e-02 -5.5303e-02 9.3861e-05 2.7956e-03 -6.0000e+00 3.8709e-03 6.4165e-03 2.3284e-03 2.7593e-05 1.7657e-04 -6.0000e+00 1.1094e-03 -1.4532e-03 1.0111e-04 12 9 9 12 1 1 85.36 23.83 7.86 -0.00145 0.01470 222 27 1 4 0 203.680 31.50 20.01 23.83 3.62 9.0 825.49 -2354 -2032 -1100 -145 449 1181 1636 1704 1567 1066 656 145 -397 -683 -938 -993 -848 -180 443 611 668 737 756 880 1114 1078 929 622 10 -877 -1434 -1475 -1083 -236 490 639 486 282 86 -129 -86 100 418 746 1055 1209 1144 825 361 -275 -974 -1583 -1969 -1881 -1275 -484 128 512 702 758 853 980 1100 1063 930 611 274 -157 -414 -764 -960 -999 -849 -535 -245 -326 -807 -1129 -1376 -1547 -1600 -1388 -1301 -1157 -808 -616 -724 -620 -560 -478 -292 136 687 1058 1108 799 440 -220 -829 -1538 -1987 -1983 -1509 -733 -167 -103 -292 -550 -741 -602 -203 251 726 1286 1554 1718 1887 1898 1693 1333 981 656 487 688 781 777 856 791 644 707 537 47 -367 -643 -958 -786 -399 -102 138 445 520 514 506 537 470 315 -84 -738 -1382 -1650 -1612 -2012 -1754 -970 -127 405 1085 1483 1561 1438 975 595 130 -364 -622 -853 -906 -761 -164 409 573 631 680 701 821 1047 1022 882 588 9 -808 -1342 -1382 -1001 -223 473 610 466 270 82 -122 -82 96 411 725 1040 1201 1141 820 356 -268 -937 -1544 -1913 -1839 -1235 -479 126 513 708 768 867 1002 1131 1097 958 626 279 -158 -414 -758 -949 -988 -845 -537 -247 -329 -811 -1124 -1358 -1522 -1576 -1370 -1292 -1157 -813 -622 -735 -628 -566 -482 -289 136 693 1070 1115 793 439 -216 -798 -1502 -1934 -1898 -1474 -736 -167 -105 -300 -566 -745 -609 -209 261 766 1338 1632 1821 2020 2004 1797 1413 1055 699 516 730 833 817 906 842 689 756 574 51 -388 -677 -1012 -837 -431 -110 150 490 580 565 561 597 524 350 -93 -807 -1534 -1826 -1758 SQ 20231230T132848.8Z 8764.561675 263 1 54.52 2 89.22 122.78 63.67 272.31 0.00 1 0.00 1 0 22 6.960e-03 6.900e-03 1.432e-04 1.425e-04 8.995397e+03 9.387936e+00 6.108057e+02 -6.000000e+00 3.860720e+02 274.23 -2.00 20.00 -2.00 505.43 0.00e+00 5.924769e-03 3.947777e-06 3.215964e-04 -6.000000e+00 1.936296e-04 274.23 -2.00 20.00 -2.00 501.15 0.00e+00 1.235907e+00 2.776678e-03 8.897522e-02 -6.000000e+00 1.396611e-01 223.02 -2.00 3.53 -2.00 502.63 0.00e+00 19.341 0.136 489.00 513.00 1 1.8951e+00 2.1234e-04 3.4708e-02 -6.0000e+00 1.0708e-02 -4.4782e-02 5.2658e-05 2.5702e-03 -6.0000e+00 2.7408e-03 1.6683e-02 2.1865e-03 1.5348e-05 1.4843e-04 -6.0000e+00 7.8567e-04 -6.9456e-03 1.4351e-04 12 8 8 10 0 0 93.98 23.82 5.07 -0.00695 0.00822 616 62 1 4 0 88.500 31.50 20.54 23.82 3.72 9.0 826.24 -1547 -1302 -667 -14 416 871 1220 1198 1133 825 477 113 -234 -496 -609 -656 -547 -135 329 458 425 509 498 561 762 790 590 434 17 -626 -994 -1008 -790 -165 372 392 273 198 46 -192 -129 24 246 497 725 818 729 522 214 -230 -742 -1155 -1464 -1396 -938 -350 57 307 428 492 549 702 735 701 647 415 160 -139 -306 -517 -669 -697 -610 -384 -117 -199 -578 -825 -990 -1084 -1126 -979 -973 -837 -610 -458 -511 -472 -407 -369 -197 90 505 770 749 575 248 -217 -634 -1081 -1455 -1457 -1122 -490 -108 -135 -252 -447 -564 -446 -135 122 496 871 1107 1210 1367 1384 1217 926 705 484 367 511 637 565 629 611 466 517 469 64 -219 -398 -640 -531 -169 -7 90 366 414 364 394 405 296 187 -67 -556 -1005 -1191 -1123 -1368 -1136 -596 -12 385 804 1144 1136 1077 780 447 105 -215 -452 -554 -599 -506 -127 308 435 407 490 471 534 731 762 570 417 16 -595 -932 -946 -752 -158 364 382 267 193 44 -185 -125 23 245 490 725 825 737 525 213 -226 -731 -1120 -1411 -1354 -908 -347 57 310 435 501 562 707 744 712 656 417 162 -140 -305 -510 -658 -686 -604 -384 -118 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-6.0000e+00 5.9756e-04 -7.0555e-03 1.7378e-04 12 9 9 12 1 1 92.46 23.82 3.43 -0.00706 0.00337 728 86 1 4 0 64.150 31.50 19.71 23.82 3.77 9.0 827.03 -1158 -959 -477 31 304 673 945 929 848 626 356 112 -201 -359 -454 -485 -424 -59 270 341 281 362 375 427 589 561 429 340 12 -494 -697 -758 -619 -88 302 270 178 166 24 -124 -97 0 169 379 545 618 535 388 138 -195 -598 -904 -1112 -1084 -742 -277 12 204 283 362 419 538 546 531 507 345 122 -80 -232 -404 -519 -502 -483 -300 -52 -119 -433 -658 -732 -796 -847 -744 -732 -646 -435 -318 -362 -338 -322 -261 -174 43 375 596 560 400 182 -196 -447 -823 -1100 -1113 -878 -377 -60 -119 -217 -337 -458 -347 -87 113 364 648 810 896 1011 1085 910 727 536 391 284 430 534 452 494 507 375 415 386 65 -167 -302 -514 -388 -68 25 73 287 345 275 290 318 240 137 -89 -453 -808 -921 -861 -1041 -854 -435 29 283 641 898 893 817 599 338 105 -190 -337 -424 -455 -396 -56 257 329 273 354 362 414 575 551 420 331 12 -473 -657 -716 -594 -85 294 267 176 164 24 -121 -95 0 167 378 550 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