File name: Pandora249s1_ChicagoIL_20240104_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240113T051954.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240104_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240104T142349.1Z 8769.599874 300 1 54.35 2 81.10 131.83 59.15 221.41 0.00 1 0.00 1 0 25 5.976e-01 2.005e-02 2.012e-01 3.596e-03 8.329908e-01 1.988193e-03 9.399344e-03 -6.000000e+00 3.525453e-01 223.19 -2.00 3.53 -2.00 321.35 0.00e+00 5.713925e-03 9.268341e-04 1.184339e-03 -6.000000e+00 1.528061e-02 273.92 -2.00 20.00 -2.00 320.92 0.00e+00 6.126 0.004 302.00 328.00 3 1.8353e+00 6.5102e-03 7.4056e-02 -6.0000e+00 8.6863e-01 5.5744e-01 8.8393e-03 4.5130e-02 -6.0000e+00 9.4379e-01 -6.9097e-01 9.0180e-03 2.5065e-02 -6.0000e+00 5.6164e-01 2.8507e-01 4.3250e-03 1.0022e-02 -6.0000e+00 2.3804e-01 8.5994e-05 -1.5804e-03 9.8566e-05 1.4271e-04 -6.0000e+00 1.8186e-02 -8.9308e-03 6.1964e-05 12 8 8 10 0 0 99.43 23.76 0.33 -0.00893 -0.02081 65 7 1 5 0 836.070 31.50 19.50 23.76 3.50 8.9 823.77 -235610 -151400 -197396 -107788 -180824 -76253 -230910 -184825 -129559 132588 -164706 -166371 -31364 114584 -105219 134921 -56933 16090 -54618 27154 -9225 -24464 -73339 -28968 16780 -99336 81781 -7808 -69006 -24903 185197 73807 -27528 -12110 43170 -16210 189 73361 29037 -4969 45600 3365 35176 23328 22965 8291 29269 8608 38697 10165 21395 33659 25331 13876 14436 24570 9802 21873 1909 10225 -2468 15468 21508 9848 13873 11776 3277 6599 10206 1895 4785 6319 9596 -2420 3220 1519 -7679 -288 -8778 -2798 -2273 -1209 -74 -917 2323 103 -233 500 1216 -1142 -1464 88 -2618 -998 -724 -3488 -2320 -1310 -273 -788 -1135 -1668 -983 -1688 -874 -1652 -1843 -1508 -1979 -673 -870 -444 -567 -51 54 -436 1185 659 282 969 47 1344 621 1247 1385 1896 2011 1446 521 747 432 179 1479 859 -191 -43 -447 -415 -864 -194 -431 -366 -888 -6911 -2269 -5035 -1100 -3517 -486 -6920 -3712 -1611 465 -3256 -3766 -230 402 -2717 473 -1289 214 -1590 362 -178 -541 -2649 -701 271 -5295 717 -164 -2662 -664 714 1061 -1284 -531 1090 -722 7 1569 1151 -328 2063 253 2023 1554 1554 660 1940 731 2579 973 2026 3164 2869 1922 2126 3412 1616 3183 329 1567 -431 2419 3583 2103 3128 2800 854 1722 2788 635 1735 2389 3517 -950 1091 470 -2402 -84 -3060 -1086 -1048 -584 -40 -538 1403 67 -161 353 856 -802 -978 55 -1608 -619 -496 -2865 -2220 -1324 -306 -929 -1302 -1760 -927 -1654 -871 -1611 -1906 -1670 -2426 -922 -1250 -699 -935 -84 86 -671 1773 1018 458 1622 79 2159 959 1841 1969 2808 2899 2143 797 1311 797 363 3179 1849 -444 -105 -1136 -1066 -2226 -482 -1008 -793 -1960 SS 20240104T143734.6Z 8769.609429 306 1 54.46 2 79.24 134.43 60.91 224.70 0.00 1 0.00 1 0 25 3.704e-01 6.625e-03 3.250e-02 8.681e-04 7.205351e-01 4.645873e-04 8.252988e-03 -6.000000e+00 2.186017e-01 223.19 -2.00 3.53 -2.00 320.34 0.00e+00 2.393199e-03 1.701112e-04 7.092946e-04 -6.000000e+00 9.473165e-03 273.92 -2.00 20.00 -2.00 319.87 0.00e+00 5.158 0.002 302.00 328.00 3 5.2720e-01 1.3635e-03 6.2514e-02 -6.0000e+00 5.3861e-01 1.3679e-01 1.7467e-03 3.8177e-02 -6.0000e+00 5.8513e-01 -1.2255e-01 1.7762e-03 1.9986e-02 -6.0000e+00 3.4821e-01 3.8783e-02 9.0032e-04 7.3461e-03 -6.0000e+00 1.4764e-01 9.4087e-04 -5.1802e-04 2.3899e-05 8.0235e-05 -6.0000e+00 1.1271e-02 -1.0171e-02 1.1911e-04 11 8 0 10 0 0 94.22 23.77 0.37 -0.01017 -0.01406 494 50 1 5 0 110.220 31.50 19.55 23.77 4.22 9.0 829.79 -162712 -111626 -110132 -128628 -125718 -96102 -148133 -112714 -116515 -60038 -100861 -101027 -66235 -41752 -60415 -33119 -34321 -34907 -29076 -33725 -8946 -21892 -26372 -29433 -19297 -33360 -12720 -22664 -26463 -26579 313 -6925 -13449 -10614 -5096 -12354 -8199 -1781 -436 -2624 2375 -539 250 700 611 1964 1393 1514 2655 2741 2477 4625 4135 3295 2235 2176 1564 1574 -311 556 406 1988 3388 2113 1913 917 397 575 1438 1170 675 802 717 -216 -115 -731 -1570 -1104 -1641 -958 -1049 -1059 -1479 -1662 -882 -915 -604 -7 304 315 466 716 205 756 628 352 482 373 35 78 -335 -507 -78 -115 -686 -842 -761 -399 -410 -15 -160 -320 -84 -11 194 493 594 424 85 -105 -191 59 60 57 268 336 607 995 519 171 -45 -61 58 90 -119 -151 -31 7 -292 -231 2 -35 -79 -1478 -739 -876 -1252 -1139 -635 -1743 -1050 -1282 -417 -1153 -1326 -768 -495 -1110 -572 -703 -813 -704 -914 -197 -560 -735 -917 -595 -1268 -407 -800 -972 -1046 11 -318 -779 -662 -306 -796 -541 -128 -38 -280 279 -72 35 102 91 296 218 246 452 458 459 945 947 835 617 635 476 483 -96 166 123 638 1210 794 785 389 169 251 675 576 373 471 426 -124 -61 -382 -765 -530 -862 -538 -697 -756 -1188 -1347 -756 -835 -542 -7 282 285 425 611 168 626 569 344 517 434 45 100 -437 -608 -90 -126 -784 -966 -922 -514 -546 -21 -240 -522 -135 -18 308 747 886 649 138 -169 -309 96 94 86 410 495 864 1433 823 279 -79 -117 113 176 -250 -323 -69 16 -658 -506 5 -71 -159 SS 20240104T144335.9Z 8769.613609 309 1 54.51 2 78.45 135.59 61.71 226.10 0.00 1 0.00 1 0 25 3.095e-01 6.582e-03 2.801e-02 9.216e-04 6.822612e-01 4.906165e-04 7.894619e-03 -6.000000e+00 1.825543e-01 223.19 -2.00 3.53 -2.00 320.13 0.00e+00 2.007033e-03 1.683035e-04 5.397718e-04 -6.000000e+00 7.912711e-03 273.92 -2.00 20.00 -2.00 319.64 0.00e+00 4.833 0.002 302.00 328.00 3 9.8191e-01 1.4200e-03 5.8715e-02 -6.0000e+00 4.4979e-01 1.3015e-01 1.7707e-03 3.5791e-02 -6.0000e+00 4.8872e-01 -1.1174e-01 1.7316e-03 1.8592e-02 -6.0000e+00 2.9084e-01 3.5066e-02 8.8928e-04 6.3130e-03 -6.0000e+00 1.2326e-01 8.3523e-04 -9.9695e-04 2.5730e-05 7.3217e-05 -6.0000e+00 9.4185e-03 -9.1122e-03 3.5970e-05 11 8 0 10 0 0 99.69 23.80 0.31 -0.00911 -0.01660 395 40 1 5 0 137.970 31.50 20.25 23.80 4.72 9.0 833.19 -130167 -109896 -95798 -99854 -114985 -80811 -127847 -97445 -92937 -39395 -85965 -84774 -42674 -37043 -54519 -15550 -22018 -25683 -19582 -29029 -6629 -9999 -16969 -19865 -10814 -23943 -9111 -18619 -18192 -14812 -6306 -3787 -8903 -8332 -4829 -8364 -2464 -2632 -1450 -961 1159 -601 -136 -548 769 -375 2464 181 1594 983 1446 4239 3164 3146 1969 1931 1859 1633 -155 98 296 2178 3290 1781 1978 1328 540 805 1671 1137 661 757 450 -423 -495 -901 -1356 -1061 -1485 -854 -1332 -1094 -1373 -1514 -862 -884 -385 -30 219 56 325 594 248 688 746 215 313 372 91 -140 -463 -527 -17 33 -682 -913 -774 -495 -403 -109 -142 -276 -19 -17 174 454 628 558 78 -176 -116 107 41 61 529 424 633 949 502 197 10 -71 102 84 -88 -203 -83 -15 -342 -213 -77 -111 -5 -1392 -1156 -964 -1059 -1354 -661 -1770 -1121 -1161 -319 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