File name: Pandora249s1_ChicagoIL_20240127_L2Fit_fnvs5c3d20230501p1-8.txt File generation date: 20240912T084741.0Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240127_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 888 1434 Nominal wavelengths inside fitting window [nm]: 400.0694 400.2014 400.3334 400.4653 400.5973 400.7292 400.8611 400.9930 401.1249 401.2568 401.3887 401.5205 401.6523 401.7842 401.9160 402.0478 402.1795 402.3113 402.4431 402.5748 402.7065 402.8382 402.9699 403.1016 403.2333 403.3649 403.4965 403.6282 403.7598 403.8913 404.0229 404.1545 404.2860 404.4176 404.5491 404.6806 404.8121 404.9436 405.0750 405.2065 405.3379 405.4693 405.6007 405.7321 405.8635 405.9948 406.1262 406.2575 406.3888 406.5201 406.6514 406.7827 406.9140 407.0452 407.1764 407.3077 407.4389 407.5700 407.7012 407.8324 407.9635 408.0946 408.2258 408.3569 408.4879 408.6190 408.7501 408.8811 409.0121 409.1431 409.2741 409.4051 409.5361 409.6670 409.7980 409.9289 410.0598 410.1907 410.3216 410.4525 410.5833 410.7142 410.8450 410.9758 411.1066 411.2374 411.3681 411.4989 411.6296 411.7603 411.8910 412.0217 412.1524 412.2831 412.4137 412.5443 412.6750 412.8056 412.9361 413.0667 413.1973 413.3278 413.4583 413.5889 413.7194 413.8498 413.9803 414.1108 414.2412 414.3716 414.5021 414.6325 414.7628 414.8932 415.0236 415.1539 415.2842 415.4145 415.5448 415.6751 415.8054 415.9356 416.0658 416.1961 416.3263 416.4565 416.5866 416.7168 416.8469 416.9771 417.1072 417.2373 417.3674 417.4975 417.6275 417.7576 417.8876 418.0176 418.1476 418.2776 418.4076 418.5375 418.6674 418.7974 418.9273 419.0572 419.1871 419.3169 419.4468 419.5766 419.7064 419.8362 419.9660 420.0958 420.2256 420.3553 420.4850 420.6148 420.7445 420.8741 421.0038 421.1335 421.2631 421.3927 421.5224 421.6520 421.7815 421.9111 422.0407 422.1702 422.2997 422.4292 422.5587 422.6882 422.8177 422.9471 423.0765 423.2060 423.3354 423.4648 423.5941 423.7235 423.8528 423.9822 424.1115 424.2408 424.3701 424.4993 424.6286 424.7578 424.8870 425.0162 425.1454 425.2746 425.4038 425.5329 425.6621 425.7912 425.9203 426.0494 426.1785 426.3075 426.4366 426.5656 426.6946 426.8236 426.9526 427.0816 427.2105 427.3395 427.4684 427.5973 427.7262 427.8551 427.9839 428.1128 428.2416 428.3704 428.4992 428.6280 428.7568 428.8856 429.0143 429.1430 429.2717 429.4004 429.5291 429.6578 429.7864 429.9151 430.0437 430.1723 430.3009 430.4295 430.5581 430.6866 430.8151 430.9436 431.0722 431.2006 431.3291 431.4576 431.5860 431.7144 431.8429 431.9712 432.0996 432.2280 432.3563 432.4847 432.6130 432.7413 432.8696 432.9979 433.1261 433.2544 433.3826 433.5108 433.6390 433.7672 433.8954 434.0235 434.1517 434.2798 434.4079 434.5360 434.6641 434.7922 434.9202 435.0482 435.1763 435.3043 435.4323 435.5602 435.6882 435.8161 435.9441 436.0720 436.1999 436.3277 436.4556 436.5835 436.7113 436.8391 436.9669 437.0947 437.2225 437.3503 437.4780 437.6057 437.7334 437.8611 437.9888 438.1165 438.2442 438.3718 438.4994 438.6270 438.7546 438.8822 439.0098 439.1373 439.2648 439.3924 439.5199 439.6473 439.7748 439.9023 440.0297 440.1571 440.2846 440.4119 440.5393 440.6667 440.7940 440.9214 441.0487 441.1760 441.3033 441.4306 441.5578 441.6851 441.8123 441.9395 442.0667 442.1939 442.3210 442.4482 442.5753 442.7025 442.8296 442.9566 443.0837 443.2108 443.3378 443.4649 443.5919 443.7189 443.8459 443.9728 444.0998 444.2267 444.3536 444.4805 444.6074 444.7343 444.8612 444.9880 445.1148 445.2417 445.3685 445.4952 445.6220 445.7488 445.8755 446.0022 446.1289 446.2556 446.3823 446.5090 446.6356 446.7622 446.8888 447.0154 447.1420 447.2686 447.3952 447.5217 447.6482 447.7747 447.9012 448.0277 448.1542 448.2806 448.4070 448.5334 448.6598 448.7862 448.9126 449.0390 449.1653 449.2916 449.4179 449.5442 449.6705 449.7968 449.9230 450.0492 450.1754 450.3016 450.4278 450.5540 450.6802 450.8063 450.9324 451.0585 451.1846 451.3107 451.4368 451.5628 451.6888 451.8148 451.9408 452.0668 452.1928 452.3188 452.4447 452.5706 452.6965 452.8224 452.9483 453.0742 453.2000 453.3258 453.4516 453.5774 453.7032 453.8290 453.9547 454.0805 454.2062 454.3319 454.4576 454.5833 454.7089 454.8346 454.9602 455.0858 455.2114 455.3370 455.4626 455.5881 455.7137 455.8392 455.9647 456.0902 456.2157 456.3411 456.4666 456.5920 456.7174 456.8428 456.9682 457.0935 457.2189 457.3442 457.4695 457.5949 457.7201 457.8454 457.9707 458.0959 458.2211 458.3463 458.4715 458.5967 458.7219 458.8470 458.9722 459.0973 459.2224 459.3475 459.4725 459.5976 459.7226 459.8477 459.9727 460.0977 460.2226 460.3476 460.4726 460.5975 460.7224 460.8473 460.9722 461.0971 461.2219 461.3467 461.4716 461.5964 461.7212 461.8459 461.9707 462.0954 462.2202 462.3449 462.4696 462.5943 462.7189 462.8436 462.9682 463.0928 463.2174 463.3420 463.4666 463.5912 463.7157 463.8402 463.9647 464.0892 464.2137 464.3382 464.4626 464.5871 464.7115 464.8359 464.9603 465.0846 465.2090 465.3333 465.4576 465.5820 465.7062 465.8305 465.9548 466.0790 466.2033 466.3275 466.4517 466.5758 466.7000 466.8242 466.9483 467.0724 467.1965 467.3206 467.4447 467.5687 467.6928 467.8168 467.9408 468.0648 468.1888 468.3127 468.4367 468.5606 468.6845 468.8084 468.9323 469.0562 469.1800 469.3039 469.4277 469.5515 469.6753 469.7991 469.9228 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-710: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 711-1257: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240127T164039.7Z 8792.694904 383 1 8.98 2 63.40 157.96 110.87 315.21 0.00 1 0.00 1 0 33 1.227e-03 1.223e-03 1.141e-03 1.127e-03 2.441789e+02 2.132922e+02 3.034969e+01 3.510332e+02 2.405738e+02 273.20 -2.00 20.00 -2.00 444.99 0.00e+00 1.010108e-04 1.239495e-04 1.551352e-06 1.432844e-05 1.343062e-04 273.20 -2.00 20.00 -2.00 454.41 0.00e+00 1.591212e-04 1.018183e-05 1.096084e-06 7.230830e-06 1.122190e-05 226.96 -2.00 2.18 -2.00 434.74 0.00e+00 9.468298e+05 1.571340e+05 7.573397e+03 2.222853e+05 1.769928e+05 255.72 -2.00 11.25 -2.00 457.03 0.00e+00 2.989639e-01 3.233198e-02 1.423732e-03 8.747579e-03 3.827993e-02 224.03 -2.00 3.53 -2.00 453.81 0.00e+00 5.527945e-06 4.076602e-06 2.394925e-07 1.111139e-06 4.714126e-06 273.20 -2.00 20.00 -2.00 455.13 0.00e+00 2.221 0.000 397.00 473.00 4 6.6981e+00 1.1920e-03 5.5054e-03 3.7994e-04 1.2509e-03 4.7896e-02 1.4239e-03 1.1496e-03 2.2356e-04 1.5473e-03 -5.6989e-03 8.2560e-04 1.5118e-04 9.2044e-05 8.9144e-04 -1.7521e-04 2.7411e-04 2.2773e-05 2.3561e-05 2.9797e-04 6.0471e-04 1.3872e-04 1.3416e-05 1.3266e-05 1.4879e-04 1.4821e-03 7.9224e-03 7.9345e-04 1.2400e-05 3.3844e-05 7.6320e-04 7.7771e-06 1.2486e-05 1.9010e-07 3.3319e-07 1.3315e-05 4.6698e-05 1.6999e-05 1.6229e-07 4.0509e-07 1.8187e-05 -9.7653e-03 -1.0417e-04 7.4955e-01 1.1364e-01 9.4390e-04 2.0103e-03 1.1687e-01 12 9 1 12 1 1 99.92 24.50 1.27 -0.00977 -0.01356 7 5 1 4 0 1122.220 32.00 20.21 24.50 11.22 9.2 878.29 -34 -21 -109 235 -127 297 20 -36 -71 182 -43 -137 176 1 218 -51 208 34 -42 -108 -99 -47 -76 -55 -114 16 -154 -127 -90 -98 -73 -31 -80 107 -163 248 -7 -165 7 -115 149 121 -41 50 98 -290 147 -62 5 204 -40 -129 -146 301 -9 41 -170 14 -120 193 -6 62 94 257 29 37 -84 42 143 -93 85 142 -178 -63 110 -127 -70 -19 25 201 -128 -103 171 34 65 15 -45 203 -31 92 -190 -136 85 -106 -25 103 -48 82 88 -14 10 -22 -271 93 -136 83 -49 81 -204 159 -108 -49 -214 118 17 -53 184 -153 8 -57 -55 31 -26 -27 -66 193 24 122 54 -154 51 -211 -35 -70 -72 2 94 212 6 -140 38 -211 29 98 -195 151 -219 -123 -80 -72 -50 26 -186 54 24 -45 -14 34 159 -114 268 113 -34 58 130 77 -139 -24 -26 138 -195 156 180 82 -192 53 80 -105 -34 105 -160 136 119 44 105 49 -10 -54 6 -103 20 -223 80 -131 126 -4 -127 -58 197 115 199 71 27 -21 -1 -23 -140 -87 -47 140 -108 99 -87 56 -243 196 77 111 13 -160 -195 179 -35 -193 127 14 86 -242 94 3 23 -79 -115 118 200 28 23 113 13 155 179 -55 -234 -221 226 95 156 113 -31 -17 52 -71 56 48 161 -188 235 162 17 -21 8 -111 55 -11 14 179 18 288 7 -28 283 -49 -33 -168 -143 3 39 -48 285 59 148 -187 -15 -298 -27 19 -63 -242 -68 -164 -132 -327 85 -31 118 -152 13 -195 -148 -90 83 -168 53 -121 -32 57 -87 -257 115 52 -275 -83 118 -242 -123 37 75 64 98 24 15 57 195 20 144 168 -21 -149 34 50 -33 17 -56 15 -18 41 2 -78 170 -29 238 -24 -132 -91 -180 -22 132 -222 141 -378 -60 -196 168 121 166 -105 -169 36 -19 -38 6 52 -102 129 87 56 -130 37 -3 125 -64 -19 -46 121 19 -6 25 113 -197 40 168 25 -6 -9 -91 189 12 144 -105 43 -11 -43 34 38 -74 228 -61 89 44 -64 -27 -121 -197 -124 162 54 -21 116 25 62 164 204 43 30 101 -23 -65 -148 -103 211 -17 -211 43 119 111 -106 34 -3 110 -1 23 74 -36 222 92 309 -48 50 -59 -118 -56 -73 -104 -47 100 -114 -323 -58 -141 -218 32 -129 -65 35 -33 105 83 34 -20 -5 106 -142 -158 -122 125 -31 128 4 -128 -114 36 84 106 57 174 -211 83 -72 -30 233 -23 -78 43 -66 -45 -28 -229 -84 -25 128 -42 116 88 -52 -40 62 141 274 -38 -13 1 127 64 -75 -1 -156 -1 58 44 37 96 -48 280 -191 -146 115 121 106 -147 -181 -30 -221 -23 -52 14 283 -31 -38 -133 46 120 -278 -115 -86 -49 -27 104 -117 83 -56 67 8 122 48 22 95 -20 -30 -18 -97 202 -109 254 18 -32 -64 167 -40 -126 161 1 200 -47 194 32 -39 -102 -93 -44 -70 -49 -100 14 -138 -117 -85 -93 -69 -30 -73 94 -139 212 -6 -152 7 -109 137 111 -37 45 89 -262 134 -56 4 177 -36 -119 -136 277 -8 38 -153 12 -109 177 -6 58 89 244 28 36 -82 41 142 -92 82 137 -168 -59 102 -110 -60 -16 22 179 -119 -97 164 33 63 14 -44 205 -32 92 -188 -133 83 -104 -25 101 -47 80 85 -13 10 -20 -261 90 -138 84 -49 80 -200 153 -104 -49 -211 118 17 -52 182 -149 7 -55 -53 30 -25 -28 -68 196 24 121 54 -151 50 -202 -33 -66 -69 2 90 204 6 -135 36 -200 28 95 -186 148 -216 -121 -80 -69 -48 24 -172 50 23 -43 -14 34 161 -117 275 113 -34 58 127 75 -137 -24 -27 138 -192 143 159 72 -176 50 78 -105 -34 102 -152 128 113 43 102 49 -10 -54 6 -100 19 -210 76 -126 120 -4 -121 -55 185 107 189 69 27 -21 -1 -22 -129 -78 -42 125 -99 93 -83 55 -235 187 73 104 12 -150 -176 163 -32 -174 116 13 78 -214 79 3 18 -61 -91 94 157 22 18 87 10 128 156 -51 -233 -228 233 97 156 107 -29 -16 46 -65 54 48 164 -189 239 160 16 -19 7 -96 47 -10 13 173 17 287 6 -28 273 -46 -32 -163 -142 3 38 -48 289 61 154 -193 -16 -300 -27 19 -62 -234 -65 -158 -130 -327 84 -29 107 -135 11 -175 -137 -87 79 -161 51 -119 -32 56 -86 -255 113 51 -260 -79 113 -228 -120 37 75 65 99 24 15 58 196 21 147 170 -21 -151 35 52 -34 18 -56 15 -17 40 2 -80 172 -30 240 -24 -132 -92 -185 -23 134 -225 145 -379 -59 -189 162 116 160 -100 -164 36 -18 -38 6 52 -102 130 87 57 -133 39 -3 128 -66 -19 -47 122 19 -6 26 117 -203 41 170 26 -6 -9 -95 197 13 150 -111 46 -12 -46 36 41 -78 245 -65 94 46 -66 -28 -126 -207 -130 169 57 -22 119 25 62 164 205 42 30 102 -23 -67 -156 -110 225 -18 -224 45 123 116 -110 35 -3 114 -1 24 78 -38 238 101 338 -53 54 -62 -125 -60 -78 -113 -51 108 -124 -356 -64 -155 -234 34 -137 -68 37 -35 111 90 37 -21 -5 115 -153 -169 -131 134 -33 140 4 -138 -124 39 92 119 64 197 -239 93 -80 -34 260 -26 -88 49 -75 -50 -31 -260 -96 -29 145 -47 132 99 -58 -45 70 159 308 -42 -14 1 143 72 -82 -2 -174 -1 64 50 42 108 -54 318 -221 -166 130 139 120 -166 -198 -33 -243 -25 -58 16 319 -35 -43 -152 52 137 -316 -131 -97 -56 -31 119 -133 95 -63 76 10 139 54 25 106 -23 SQ 20240127T164519.6Z 8792.698144 386 1 54.85 2 63.08 159.14 111.47 316.19 0.00 1 0.00 1 0 33 1.851e-03 1.827e-03 7.996e-04 7.896e-04 5.455230e+02 1.502139e+02 5.151314e+01 3.510207e+02 3.629174e+02 273.20 -2.00 20.00 -2.00 445.00 0.00e+00 4.394084e-04 8.683958e-05 1.483408e-06 1.427571e-05 2.030580e-04 273.20 -2.00 20.00 -2.00 454.43 0.00e+00 2.175529e-04 7.159003e-06 1.490772e-06 7.231961e-06 1.693541e-05 226.97 -2.00 2.18 -2.00 434.56 0.00e+00 8.794949e+05 1.107716e+05 8.827258e+03 2.222661e+05 2.669624e+05 255.72 -2.00 11.25 -2.00 457.19 0.00e+00 2.895247e-01 2.270060e-02 1.336265e-03 8.711327e-03 5.776716e-02 224.03 -2.00 3.53 -2.00 453.83 0.00e+00 -2.184046e-06 2.861989e-06 2.294243e-07 1.111091e-06 7.112478e-06 273.20 -2.00 20.00 -2.00 455.18 0.00e+00 2.197 0.000 397.00 473.00 4 7.8502e+00 8.3670e-04 5.4461e-03 3.7933e-04 1.8901e-03 6.1700e-02 9.9339e-04 1.1372e-03 2.2223e-04 2.3300e-03 -1.3868e-02 5.8173e-04 1.4982e-04 9.1578e-05 1.3543e-03 -4.3369e-04 1.9175e-04 2.0323e-05 2.3399e-05 4.4954e-04 1.1691e-03 9.7199e-05 1.0968e-05 1.3232e-05 2.2461e-04 4.7311e-04 8.4989e-04 5.5703e-04 1.2741e-05 3.4575e-05 1.1716e-03 -7.0591e-05 8.7857e-06 2.0358e-07 3.2957e-07 2.0081e-05 4.8743e-05 1.1877e-05 1.8682e-07 3.9970e-07 2.7432e-05 -1.1950e-02 -6.4665e-05 7.9074e-01 7.9773e-02 9.6126e-04 1.9833e-03 1.7624e-01 12 8 8 10 0 0 99.94 24.51 1.28 -0.01195 -0.01764 20 2 1 4 0 2741.980 32.00 20.26 24.51 11.51 9.2 880.25 33 -227 -208 94 -234 183 -225 58 -26 49 373 -12 183 211 525 100 160 -332 -249 -40 -380 -4 -179 113 602 107 -327 145 -296 105 -170 -112 -113 -191 -339 166 -77 29 -33 -43 198 -135 214 -6 349 -27 543 30 -353 -204 14 -41 -187 100 -138 125 216 273 -84 203 -286 14 -26 172 169 195 75 7 236 64 155 227 -259 14 27 -392 -147 158 -296 245 -289 -215 424 -162 211 -90 -125 345 -311 -316 -44 115 -40 -39 85 201 116 302 50 -258 -62 -153 -17 95 -112 -208 -229 -33 44 80 -103 -195 -226 176 -39 94 174 -26 -210 -140 -246 -53 -26 233 47 -158 208 -190 -50 -184 33 -142 -390 -88 -254 -70 137 -91 166 308 212 -195 -269 -17 -240 210 -268 -82 114 -146 146 -255 -27 181 31 18 -2 261 157 -138 229 154 -221 -26 524 386 -48 -105 -187 199 -306 -43 48 272 166 133 152 -266 14 296 3 -69 145 25 37 83 -101 188 -399 176 38 -160 -19 -130 207 34 -123 -56 199 64 146 -287 161 -36 26 -45 -437 308 77 100 -148 -366 -117 319 -253 -126 167 -41 -19 -14 119 251 239 -219 294 79 190 -138 316 26 76 -95 15 68 35 138 -195 -150 96 -284 264 148 -84 -124 230 479 -127 7 -182 173 -204 333 -95 197 219 21 117 74 -112 237 -147 161 -98 -161 -282 425 2 17 122 -177 532 -84 38 18 51 -144 -178 134 1 19 -12 167 -107 -151 -171 -240 -165 -383 55 -227 -109 -125 41 224 -276 57 18 -449 -210 -19 -90 55 319 0 -543 -195 53 82 175 -91 -99 101 -298 -185 78 -236 139 -57 -69 206 -65 -177 -172 -154 61 488 -136 -6 -169 -6 -190 310 168 80 -13 -68 65 -16 16 166 204 -328 -109 -199 101 30 88 -67 92 -299 -1 45 60 -185 317 -83 -102 307 119 -175 2 -100 -121 14 276 185 48 -191 63 158 -179 -140 -19 15 151 -29 93 63 151 -184 -43 -73 -76 -175 -74 -61 38 33 -8 19 63 3 138 -120 58 12 -14 167 -138 -129 228 156 -244 -152 291 17 -50 325 -280 83 379 107 -75 -186 244 217 -232 -325 -112 35 -26 -165 132 317 -108 76 23 64 367 -145 -143 -140 151 17 -79 39 -204 -7 307 249 134 -165 -94 -97 -122 -288 -154 43 -57 -14 92 -193 177 254 -45 -15 237 -130 259 -163 -35 -283 -54 -62 129 -30 -74 -78 -55 194 18 -60 148 156 -26 -108 28 -1 -175 233 387 0 141 -173 64 -36 -340 15 70 212 85 114 38 -167 -336 -205 39 183 -115 14 -165 -215 141 -51 -49 131 103 122 215 -87 74 82 53 5 18 93 199 -248 61 -68 -133 -68 -132 -104 231 219 -90 218 -69 111 182 -581 -186 39 -118 -80 -152 -46 -110 -61 52 152 326 -204 -78 309 -48 31 -202 -188 82 -203 159 -202 52 -23 45 342 -11 166 192 479 93 149 -308 -232 -38 -358 -4 -167 100 535 96 -295 137 -281 101 -164 -105 -103 -173 -296 145 -69 28 -31 -42 188 -125 193 -6 317 -25 480 28 -316 -182 13 -38 -174 92 -128 114 195 244 -79 181 -266 13 -25 169 166 186 74 7 239 64 151 226 -252 13 25 -348 -124 137 -252 221 -269 -208 416 -161 202 -88 -126 352 -319 -320 -44 114 -40 -39 85 199 114 294 50 -253 -59 -147 -16 93 -114 -218 -239 -33 42 78 -101 -188 -224 176 -39 92 167 -25 -208 -133 -240 -53 -27 244 48 -159 215 -194 -51 -181 32 -138 -376 -85 -249 -67 132 -88 160 297 203 -185 -254 -16 -230 205 -272 -83 114 -141 142 -242 -26 170 30 18 -2 266 156 -138 230 156 -222 -25 526 384 -48 -104 -188 196 -301 -40 42 234 149 124 152 -260 14 286 3 -64 137 24 37 81 -100 184 -384 170 36 -150 -17 -125 202 34 -120 -54 186 60 138 -283 158 -36 25 -44 -403 279 68 88 -136 -342 -114 313 -240 -123 161 -39 -18 -13 106 230 219 -196 266 72 171 -123 272 21 61 -75 12 52 28 106 -147 -113 76 -234 231 139 -83 -125 239 493 -126 7 -166 150 -180 309 -91 193 220 21 117 72 -106 216 -129 135 -84 -141 -257 408 2 17 118 -175 509 -80 36 18 50 -141 -178 135 1 20 -12 173 -109 -153 -170 -236 -159 -364 54 -215 -105 -122 40 211 -253 50 16 -409 -193 -19 -88 52 302 0 -535 -194 53 82 171 -87 -96 96 -284 -178 75 -237 139 -57 -69 202 -66 -173 -172 -158 63 499 -139 -6 -171 -6 -194 315 170 80 -13 -66 64 -16 17 172 208 -332 -111 -204 100 30 90 -68 92 -303 -1 42 56 -171 294 -78 -97 297 118 -170 2 -97 -119 14 277 190 51 -195 64 164 -183 -139 -18 15 153 -30 97 65 153 -187 -44 -74 -78 -179 -76 -63 40 34 -8 20 67 3 148 -128 61 13 -15 173 -142 -136 241 165 -252 -157 309 17 -51 321 -282 82 371 106 -74 -186 247 216 -238 -341 -118 38 -28 -173 137 326 -110 79 24 67 381 -152 -146 -145 158 18 -86 42 -221 -8 323 262 142 -176 -101 -105 -131 -312 -168 47 -62 -14 99 -206 186 266 -47 -16 256 -143 284 -179 -38 -306 -58 -67 138 -32 -80 -84 -60 210 20 -67 166 176 -30 -123 32 -1 -197 260 433 0 159 -196 72 -41 -388 17 80 241 96 129 43 -188 -377 -229 43 201 -127 16 -184 -238 159 -56 -54 144 115 138 245 -100 84 94 59 6 21 106 224 -285 68 -74 -141 -72 -142 -115 260 250 -104 251 -79 126 205 -656 -210 44 -136 -93 -176 -54 -127 -70 60 175 377 -237 -90 350 -53