File name: Pandora249s1_ChicagoIL_20240218_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T085430.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240218_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240218T131646.8Z 8814.553319 155 1 54.11 2 84.87 110.75 110.96 358.04 0.00 1 0.00 1 0 25 7.591e-01 4.916e-02 3.324e-01 1.845e-02 1.487677e+00 1.214876e-02 1.875476e-02 -6.000000e+00 4.714956e-01 224.88 -2.00 3.53 -2.00 322.55 0.00e+00 -5.482022e-02 4.663856e-03 4.603711e-03 -6.000000e+00 2.108066e-02 273.45 -2.00 20.00 -2.00 322.11 0.00e+00 9.661 0.017 302.00 328.00 3 -1.9319e-01 4.2606e-02 1.4372e-01 -6.0000e+00 1.1676e+00 3.0693e+00 5.0769e-02 1.5009e-01 -6.0000e+00 1.2727e+00 -3.2062e+00 3.3983e-02 4.1973e-02 -6.0000e+00 7.5211e-01 1.0808e+00 1.9429e-02 4.4064e-02 -6.0000e+00 3.1635e-01 8.3232e-06 -1.4660e-03 4.2614e-04 7.0986e-04 -6.0000e+00 2.3973e-02 -9.6896e-03 0.0000e+00 12 8 8 10 0 0 15.70 23.53 1.40 -0.00969 -0.02071 50 5 1 5 0 1082.000 31.25 20.68 23.53 2.27 8.9 814.90 900000 81344 39515 265351 59291 900000 -38596 -16760 78675 900000 60030 46306 172054 900000 47612 900000 20518 128821 71881 900000 222449 17858 -33806 -769 65641 -45137 290056 95798 -26544 93637 900000 189552 -85002 80895 900000 -36174 21084 81170 59055 -7023 900000 1938 104939 63778 31300 27479 21068 -29033 900000 -22273 162201 900000 116461 16846 27131 366174 3854 900000 19691 34527 -49509 194329 900000 824 59164 155460 2877 51288 55072 11068 58213 74557 900000 -24822 77025 22043 -51443 -9252 -63388 10256 -2704 7015 48755 35352 165427 52903 34685 31572 28758 10490 -17409 -4155 -29156 11323 22406 -8138 -5581 1100 12114 4493 631 -17188 -2195 9647 6082 3355 3257 153 -6755 3797 -46 -1094 1366 1949 98 -1189 2492 2042 -3384 2229 -2725 653 -1070 -2659 -1879 7544 6032 -1931 -1829 -1050 -1589 -4083 5849 538 -1463 2855 -91 -1693 -2440 1452 -1220 1894 1711 900000 4743 2895 4761 2128 900000 -3347 -1453 3294 900000 4308 4003 4209 900000 3650 900000 1908 3782 3400 900000 3991 1019 -3308 -65 3640 -8687 5204 3594 -2598 2291 900000 3401 -13726 2507 900000 -3068 997 2383 2697 -779 900000 243 4450 3537 1991 1524 1100 -2368 900000 -1853 2910 900000 3761 1484 2629 6570 553 900000 2155 2726 -7639 3487 900000 84 3715 3905 346 4141 4842 1728 6267 7090 900000 -5611 5390 2254 -9784 -1162 -15353 1417 -514 1447 7698 7040 9498 9681 7717 7194 6501 2673 -5435 -1081 -9939 2864 6030 -3606 -2894 628 7020 2967 420 -12336 -1177 4154 2695 1595 1636 86 -4690 2854 -43 -1237 1683 2538 133 -1619 3264 2740 -4931 3091 -3804 810 -1246 -3001 -2050 7336 5909 -2172 -2426 -1702 -3116 -8657 12669 1368 -4164 8334 -282 -5341 -7614 4126 -3231 4338 3947 SS 20240218T132820.2Z 8814.561345 158 1 54.48 2 82.87 112.77 110.98 0.66 0.00 1 0.00 1 0 17 7.336e-01 1.889e-02 2.544e-01 3.307e-03 1.232688e+00 1.955312e-03 1.323498e-02 -6.000000e+00 4.371260e-01 224.88 -2.00 3.53 -2.00 322.21 0.00e+00 2.674238e-03 1.107139e-03 6.147084e-03 -6.000000e+00 1.919959e-02 273.45 -2.00 20.00 -2.00 321.84 0.00e+00 7.428 0.008 302.00 328.00 3 1.9442e-01 7.3419e-03 1.0689e-01 -6.0000e+00 1.0834e+00 1.1915e+00 1.2188e-02 8.9506e-02 -6.0000e+00 1.1765e+00 -1.4725e+00 1.3746e-02 4.5975e-02 -6.0000e+00 6.9673e-01 5.7423e-01 6.1290e-03 1.4910e-02 -6.0000e+00 2.9644e-01 8.2189e-05 -1.5354e-03 7.8305e-05 2.1971e-04 -6.0000e+00 2.2488e-02 -1.0479e-02 0.0000e+00 12 8 8 10 0 0 30.96 23.56 0.53 -0.01048 -0.02202 194 20 1 5 0 280.790 31.25 20.38 23.56 2.52 8.8 816.72 900000 -142033 -242804 -172387 -218129 -106310 -279865 -258125 -158338 900000 -250818 -173456 -171375 17351 -192516 24381 -13058 -102042 -78105 -116686 92078 -57189 -93247 -114390 48014 -163119 18270 -100693 -158598 -99031 900000 2345 -82612 -43948 37253 -64301 1816 141001 33995 -22990 59254 17084 32202 24267 20930 32589 20932 25770 60661 29941 38315 71450 44103 44832 38669 62260 29580 59082 17344 21953 13552 39296 41569 35871 28671 33282 14840 23398 20872 18076 17485 20673 20151 7695 8616 2839 -1180 599 -16182 247 -1447 3774 5679 3404 8439 7863 1352 3208 3705 1566 -707 1509 -4423 216 -1638 -3100 -1334 -1075 -770 -867 -1601 -3084 -1735 -2812 -3426 -2197 -2268 -1541 -2750 -1947 -1301 -1545 -907 -650 -593 -237 298 362 66 880 734 1531 1518 1305 1617 1624 1906 1043 292 266 606 -65 823 442 -225 322 176 -162 -362 -159 -451 -305 -1088 900000 -707 -3557 -1212 -2173 -343 -4510 -3479 -835 900000 -3748 -1372 -1707 56 -4287 79 -73 -1555 -1007 -2256 297 -570 -1311 -2078 183 -5305 96 -1682 -4647 -1741 900000 26 -2662 -1076 408 -1865 28 591 493 -704 917 440 747 618 546 756 560 698 1271 955 1284 1980 1819 2037 2031 2729 1849 2723 1151 1302 847 2001 2371 2555 2513 3003 1693 2647 2704 2755 2998 3624 3520 1416 1397 428 -171 88 -3244 52 -382 1135 1933 1300 3255 3203 554 1319 1660 694 -303 601 -1865 93 -767 -1797 -928 -894 -734 -808 -1469 -2845 -1382 -2064 -2528 -1680 -1839 -1351 -2769 -2105 -1660 -2099 -1334 -989 -902 -354 443 552 106 1420 1156 2238 2241 1845 2208 2162 2499 1444 435 477 1187 -147 1886 1110 -576 872 490 -454 -1006 -422 -1178 -719 -2557 SS 20240218T133906.1Z 8814.568821 161 1 54.46 2 81.04 114.68 110.90 3.09 0.00 1 0.00 1 0 25 9.443e-01 1.377e-02 8.572e-02 1.343e-03 1.044200e+00 7.586938e-04 1.145982e-02 -6.000000e+00 5.616081e-01 224.88 -2.00 3.53 -2.00 321.49 0.00e+00 5.388999e-03 3.749205e-04 1.613648e-03 -6.000000e+00 2.417094e-02 273.45 -2.00 20.00 -2.00 321.09 0.00e+00 6.087 0.004 302.00 328.00 3 2.3985e-01 2.5398e-03 8.2620e-02 -6.0000e+00 1.3893e+00 4.7182e-01 3.9680e-03 6.0542e-02 -6.0000e+00 1.5080e+00 -5.7036e-01 4.5953e-03 3.3336e-02 -6.0000e+00 8.9548e-01 2.2310e-01 2.1278e-03 1.3968e-02 -6.0000e+00 3.8039e-01 3.6026e-04 -8.7711e-04 3.2403e-05 1.6415e-04 -6.0000e+00 2.8916e-02 -1.0709e-02 0.0000e+00 12 8 8 10 0 0 19.21 23.60 0.40 -0.01071 -0.01730 431 44 1 5 0 126.330 31.50 19.42 23.60 2.95 8.9 819.71 900000 -318881 -310327 -292031 -291911 -281879 -322431 -304272 -280332 -121601 -269927 -283834 -176664 -165220 -223521 -106173 -125992 -132333 -128486 -138302 -85591 -99133 -125253 -113472 -100091 -138322 -49086 -86599 -113213 -105470 26092 -25576 -65937 -39861 -9163 -37387 -30780 11317 -16257 -15173 16396 8955 17569 6864 8055 5827 13807 5486 19244 9022 13071 23275 17127 18021 16085 17405 12081 13519 6905 7732 5775 7422 12195 9398 10936 8996 6799 6199 5731 5878 6478 6087 5653 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