File name: Pandora249s1_ChicagoIL_20240228_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240229T061045.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240228_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240228T145449.4Z 8824.621405 319 1 3.56 2 65.95 127.34 99.04 263.95 0.00 1 0.00 1 0 17 8.762e-02 8.586e-03 4.369e-02 5.138e-03 4.848382e-01 2.685459e-03 5.531428e-03 -6.000000e+00 5.243530e-02 225.31 -2.00 3.53 -2.00 318.52 0.00e+00 9.170703e-04 5.636806e-04 1.981989e-04 -6.000000e+00 2.250352e-03 274.13 -2.00 20.00 -2.00 318.00 0.00e+00 2.437 0.000 302.00 328.00 3 3.8147e+00 7.2387e-03 3.4250e-02 -6.0000e+00 1.2983e-01 6.5922e-02 8.2546e-03 2.4473e-02 -6.0000e+00 1.4063e-01 -3.4723e-02 5.9757e-03 1.2431e-02 -6.0000e+00 8.3508e-02 1.1903e-02 3.1676e-03 4.7713e-03 -6.0000e+00 3.5671e-02 5.5309e-04 5.1514e-03 1.5320e-04 4.9497e-05 -6.0000e+00 2.6801e-03 -2.4716e-02 1.1184e-03 12 9 1 12 1 1 99.11 23.59 0.37 -0.02472 0.01399 3 6 1 5 0 889.330 31.50 19.77 23.59 0.03 8.8 798.45 900000 -38763 -22772 -15420 -31655 1428 -36128 -39597 -27710 -23398 -20162 -31116 -24847 12518 -15961 1887 -4859 -1353 3485 5152 6155 7969 -3435 -4803 4777 -5438 -4689 2842 -7798 -4531 5116 474 -509 -4096 803 -672 -560 90 -744 -523 -336 484 146 -133 617 -1137 -1111 -474 1009 2397 -46 2640 2551 1556 1186 1524 -228 2201 726 9 1024 2431 2688 237 1207 83 -78 -46 426 830 -1111 -147 -246 -637 573 951 -72 826 -538 -1614 -1584 -1772 -2090 -1420 -1506 -363 -97 -761 54 -75 332 840 1331 760 1197 102 686 495 -213 -146 -327 -884 -149 -55 -723 -1158 -1300 -1470 -214 392 480 305 -98 5 92 179 859 3 485 -450 -551 -298 95 319 980 701 279 1049 1167 1116 180 -300 927 134 118 15 -17 -13 -583 -528 -364 -473 -443 900000 -1495 -810 -510 -1158 36 -1357 -1706 -1194 -1055 -929 -1715 -1481 621 -1271 147 -455 -133 349 534 654 842 -416 -626 608 -812 -712 393 -1160 -656 728 80 -89 -804 151 -126 -109 20 -199 -166 -112 173 55 -52 241 -455 -447 -191 406 983 -21 1255 1219 807 654 871 -136 1293 426 6 595 1475 1660 165 819 56 -54 -32 308 620 -880 -123 -209 -526 467 702 -53 568 -389 -1233 -1302 -1652 -2025 -1460 -1553 -395 -111 -861 61 -88 365 903 1330 743 1221 110 790 611 -289 -194 -439 -1104 -179 -64 -884 -1511 -1697 -2030 -296 585 740 475 -154 9 137 263 1223 4 710 -698 -874 -466 143 484 1413 968 390 1445 1624 1702 287 -486 1547 226 209 27 -32 -25 -1115 -988 -649 -836 -754 SS 20240228T150944.9Z 8824.631770 327 1 2.40 2 63.79 130.65 101.76 266.29 0.00 1 0.00 1 0 17 5.398e-02 7.403e-03 3.703e-02 5.573e-03 4.508456e-01 2.900711e-03 5.392650e-03 -6.000000e+00 3.214778e-02 225.31 -2.00 3.53 -2.00 318.18 0.00e+00 -6.409770e-05 5.401455e-04 1.926661e-04 -6.000000e+00 1.382200e-03 274.13 -2.00 20.00 -2.00 317.65 0.00e+00 2.251 0.000 302.00 328.00 3 3.7243e+00 7.7501e-03 3.2039e-02 -6.0000e+00 7.9583e-02 5.1823e-02 8.7597e-03 2.2996e-02 -6.0000e+00 8.6299e-02 -2.7705e-02 5.9378e-03 1.1522e-02 -6.0000e+00 5.1283e-02 1.0110e-02 3.1172e-03 3.3187e-03 -6.0000e+00 2.1677e-02 7.5492e-04 -1.2050e-04 1.6696e-04 4.1338e-05 -6.0000e+00 1.6433e-03 -1.5681e-02 1.7424e-04 12 9 1 12 1 1 999.00 23.60 0.22 -0.01568 -0.01659 2 7 1 5 0 798.710 31.50 20.12 23.60 0.31 8.7 800.09 -14585 -11970 -28907 -10057 -16764 -22355 -12712 -23736 -16537 7114 -3021 -16835 -2057 10318 -785 4814 -1720 3507 1354 422 6884 -491 -2042 -1166 2134 -6837 2782 976 -11677 -244 3385 -309 -6692 -605 3245 -3215 -1935 1265 797 2090 -1451 -713 359 -218 141 128 1420 -1020 1595 -706 1420 1425 972 1501 75 1116 -431 1415 467 684 1071 1585 1523 43 1010 1399 -400 213 370 -652 694 284 552 -856 -775 -57 84 36 -1847 -569 -950 -855 -1335 -1307 -523 -950 -921 201 -241 502 134 -74 677 903 556 70 994 0 98 3 -963 -92 -312 -477 -91 -1515 -1162 -514 -75 671 501 -186 221 -678 147 607 493 829 255 -118 -421 -157 -23 -234 1111 801 805 1012 184 743 -126 -13 -9 -108 -15 -97 87 29 -138 -190 -209 -311 -618 -587 -540 -1650 -470 -784 -1057 -567 -1316 -962 356 -176 -1199 -144 763 -77 518 -219 456 174 57 905 -70 -305 -183 349 -1294 488 170 -2221 -41 594 -63 -1630 -148 765 -793 -495 359 250 768 -580 -306 159 -100 65 59 648 -477 733 -342 714 723 537 884 44 676 -273 884 290 416 656 1022 1076 32 771 1048 -292 152 276 -512 597 247 485 -740 -664 -47 63 26 -1379 -467 -844 -807 -1318 -1377 -551 -1072 -1045 234 -285 576 152 -78 697 899 579 77 1159 1 129 4 -1264 -116 -380 -567 -113 -1928 -1550 -686 -107 975 756 -297 354 -1054 221 891 705 1204 375 -184 -647 -238 -35 -346 1617 1116 1123 1394 259 1083 -193 -21 -15 -181 -25 -174 156 52 -253 -342 -374 -532 -1058 SS 20240228T152954.1Z 8824.645765 342 1 54.43 2 61.05 135.35 105.43 269.48 0.00 1 0.00 1 0 25 1.482e-02 5.269e-03 3.279e-03 4.672e-04 4.147170e-01 2.435223e-04 4.973771e-03 -6.000000e+00 8.825299e-03 225.31 -2.00 3.53 -2.00 318.19 0.00e+00 2.141858e-04 4.520336e-05 1.552000e-04 -6.000000e+00 3.794771e-04 274.13 -2.00 20.00 -2.00 317.64 0.00e+00 2.056 0.000 302.00 328.00 3 2.4591e+00 6.5081e-04 2.9403e-02 -6.0000e+00 2.1847e-02 2.2438e-02 7.3603e-04 2.1208e-02 -6.0000e+00 2.3692e-02 -3.7893e-03 4.9929e-04 1.0636e-02 -6.0000e+00 1.4079e-02 -2.3331e-03 2.6130e-04 3.1040e-03 -6.0000e+00 5.9502e-03 3.4110e-03 1.3867e-04 1.4224e-05 3.7883e-05 -6.0000e+00 4.5116e-04 -1.4633e-02 1.8786e-04 10 0 0 10 0 0 100.00 23.60 0.37 -0.01463 -0.01359 2134 216 1 5 0 25.500 31.25 19.40 23.60 -0.15 8.7 797.48 -2547 -2577 -4865 -4285 -7718 -4502 -3679 -2533 -2845 -1044 -4622 -3658 -3311 113 305 -1072 -1841 -470 -434 -1567 -395 255 -1735 -1367 -668 -2069 -1687 -1854 -2821 -1078 427 1050 -383 -1465 -1841 -2526 -1491 -585 353 -158 -490 -482 -531 -417 -348 -204 -342 -260 -20 299 980 880 1484 969 1195 1035 689 603 624 703 1035 1509 1768 1329 219 192 47 149 579 696 177 -190 -283 -228 -413 -369 -78 103 34 -278 -678 -1122 -1571 -1381 -1079 -798 -897 -377 -243 -71 317 543 708 1048 992 788 707 369 -50 -215 -270 -476 -46 159 -414 -768 -791 -509 -319 -95 -16 -273 -26 124 176 519 587 424 129 -177 -422 -127 -183 4 448 423 726 1102 790 405 336 24 58 176 -107 -153 -22 -72 -312 -287 -150 -241 -239 -95 -110 -226 -195 -339 -183 -154 -116 -147 -58 -277 -230 -235 9 29 -120 -229 -62 -61 -232 -59 39 -274 -228 -119 -393 -325 -349 -515 -192 80 218 -82 -336 -422 -571 -351 -156 112 -60 -192 -204 -235 -189 -159 -93 -156 -119 -9 140 480 467 780 548 710 638 437 385 393 435 647 994 1178 967 169 144 34 104 423 562 148 -170 -258 -201 -343 -299 -58 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