File name: Pandora249s1_ChicagoIL_20240302_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240303T060927.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240302_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240302 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240302T130733.4Z 8827.546915 244 1 54.63 2 82.80 106.04 73.37 212.05 0.00 1 0.00 1 0 17 6.878e-01 2.734e-02 3.400e-01 7.859e-03 9.774571e-01 4.626006e-03 1.077913e-02 -6.000000e+00 4.113822e-01 225.44 -2.00 3.53 -2.00 322.07 0.00e+00 1.324622e-03 2.459527e-03 1.715836e-03 -6.000000e+00 1.788707e-02 274.33 -2.00 20.00 -2.00 321.67 0.00e+00 7.362 0.007 302.00 328.00 3 1.5413e+00 1.7021e-02 9.0059e-02 -6.0000e+00 1.0176e+00 1.1527e+00 2.2678e-02 5.5641e-02 -6.0000e+00 1.1033e+00 -1.5153e+00 2.0994e-02 2.9941e-02 -6.0000e+00 6.5479e-01 6.1154e-01 9.9133e-03 9.5627e-03 -6.0000e+00 2.7702e-01 2.9963e-05 -1.8482e-03 2.1571e-04 1.5797e-04 -6.0000e+00 2.0964e-02 -1.4119e-02 1.9320e-04 12 8 8 10 0 0 62.62 24.35 0.85 -0.01412 -0.02801 52 5 1 5 0 1050.420 31.75 20.30 24.35 9.74 9.2 867.48 -116730 -44340 -116243 3971 -10466 900000 -162759 -145614 29682 251594 -83209 -56542 169026 12097 -24766 143711 2692 29989 -12291 150416 71183 54215 -60414 -39220 87711 -118118 171084 205496 -59882 16298 900000 104023 -5693 7570 81260 -5894 34250 330236 126111 -912 186055 18882 80727 108584 30981 10163 46005 36669 207545 23789 58577 131320 47214 32821 40136 69248 35468 44700 19719 37609 -4927 38491 94686 25350 34803 31335 17598 23829 17972 8660 16382 22550 32934 2015 8134 16154 -15027 1910 -24944 -3227 -2552 4125 4175 4161 13129 7022 4045 4326 3624 -327 -4505 547 -7155 -575 -1842 -6794 -5373 -2929 1100 -1561 -1914 -4791 -834 -7431 -1722 -2210 -1290 -3150 -4766 -1073 -1742 -832 -444 -310 -313 -1014 741 688 -103 1774 -425 1350 1694 1563 3698 3815 3277 1885 307 1147 -126 -1163 2313 1350 -513 258 266 -485 -653 -214 -353 -716 -1409 -3902 -803 -4372 41 -109 900000 -6575 -5071 227 1927 -1681 -945 1295 152 -552 1101 60 543 -351 1152 843 717 -2440 -1311 855 -9131 1311 1574 -2252 295 900000 1087 -206 258 1302 -235 918 2530 1739 -52 1853 1070 2536 2579 1567 623 1974 1770 1908 1476 2827 3421 3147 2741 3321 4456 3261 3698 1994 2997 -585 3096 4860 2971 4106 3985 2602 3450 3002 1791 3489 4768 6257 491 1682 2735 -3177 341 -6459 -801 -759 1349 1551 1683 5160 3099 1921 2108 1782 -163 -2216 241 -3327 -260 -950 -4351 -4051 -2536 943 -1457 -1753 -4145 -681 -6046 -1344 -1834 -1125 -3024 -4703 -1174 -2218 -1179 -669 -475 -472 -1500 1069 1022 -161 2827 -690 2061 2445 2171 4871 4873 4124 2471 458 1986 -255 -2424 5059 3209 -1336 709 753 -1401 -1881 -593 -914 -1713 -3175 SS 20240302T131828.1Z 8827.554492 247 1 54.57 2 80.86 107.94 74.47 214.30 0.00 1 0.00 1 0 17 6.991e-01 1.325e-02 1.239e-01 2.231e-03 8.513573e-01 1.248273e-03 9.432752e-03 -6.000000e+00 4.169587e-01 225.44 -2.00 3.53 -2.00 321.29 0.00e+00 2.967096e-03 5.879632e-04 9.647544e-04 -6.000000e+00 1.837325e-02 274.33 -2.00 20.00 -2.00 320.87 0.00e+00 5.979 0.004 302.00 328.00 3 1.2631e+00 4.0596e-03 7.4034e-02 -6.0000e+00 1.0344e+00 2.8975e-01 5.8977e-03 4.7191e-02 -6.0000e+00 1.1221e+00 -3.9508e-01 6.5307e-03 2.6247e-02 -6.0000e+00 6.6510e-01 1.5829e-01 3.0916e-03 9.8151e-03 -6.0000e+00 2.8094e-01 1.8492e-04 -4.8081e-04 6.0407e-05 1.2214e-04 -6.0000e+00 2.1283e-02 -1.4709e-02 2.0989e-04 12 8 8 10 0 0 88.79 24.38 0.59 -0.01471 -0.01832 164 17 1 5 0 332.720 32.00 19.72 24.38 10.26 9.2 870.44 -292010 -251005 -242351 -188363 -193550 -133010 -271293 -248685 -197168 900000 -197757 -202422 -59421 -15512 -140333 -29788 -76076 -36544 -91922 -83663 7891 -33396 -99526 -65382 -40940 -115600 51903 -3134 -82728 -65710 90754 4864 -36486 -38179 8538 -34615 -19204 19079 -1443 37 24097 10024 4885 3548 -627 3901 5127 -4548 22598 8146 13902 21626 15718 11455 11928 12652 5623 11502 2165 5950 731 9224 10775 7810 7958 7341 1969 5717 4591 2127 3746 3776 5075 -653 670 -1464 -4153 -1024 -5221 -2664 -2530 -714 -940 -1538 1042 443 -710 -81 927 343 99 810 -288 281 -114 -1548 -897 -525 27 -307 -486 -1229 -388 -1070 -1144 -1456 -1195 -952 -1063 -517 -344 -317 93 29 94 -199 483 443 -40 61 345 556 465 314 831 891 1340 964 548 347 196 170 659 133 122 12 -162 -204 -342 -352 -87 -416 -377 -4273 -2978 -2924 -1341 -1378 -500 -4238 -3443 -1833 900000 -2229 -2762 -247 -55 -2276 -220 -1059 -390 -1880 -1674 65 -421 -2511 -1266 -677 -4300 373 -39 -2286 -1658 573 90 -1222 -1453 208 -1288 -648 506 -57 2 1038 550 301 230 -43 263 354 -363 1475 672 1213 1985 1720 1445 1624 1811 897 1744 352 906 118 1469 1920 1646 1856 1793 515 1502 1334 655 1274 1369 1832 -239 222 -491 -1322 -316 -1858 -996 -1132 -367 -549 -982 691 288 -491 -58 658 239 65 549 -191 191 -79 -1270 -863 -541 31 -372 -574 -1341 -378 -1074 -1088 -1472 -1276 -1090 -1343 -683 -516 -489 151 47 147 -303 721 680 -65 102 576 891 712 497 1263 1308 1910 1411 834 608 366 349 1362 295 273 29 -400 -510 -857 -858 -199 -938 -806 SS 20240302T132941.3Z 8827.562284 252 1 54.43 2 78.88 109.94 75.67 216.56 0.00 1 0.00 1 0 17 3.728e-01 6.325e-03 4.991e-02 1.061e-03 7.339109e-01 5.718645e-04 8.300179e-03 -6.000000e+00 2.220943e-01 225.44 -2.00 3.53 -2.00 320.50 0.00e+00 2.257317e-03 2.208201e-04 7.068204e-04 -6.000000e+00 9.551438e-03 274.33 -2.00 20.00 -2.00 320.04 0.00e+00 5.007 0.002 302.00 328.00 3 1.0173e+00 1.7152e-03 6.2205e-02 -6.0000e+00 5.4993e-01 1.0484e-01 2.2379e-03 3.9375e-02 -6.0000e+00 5.9625e-01 -1.2349e-01 2.3269e-03 2.0817e-02 -6.0000e+00 3.5433e-01 4.1166e-02 1.1660e-03 7.7761e-03 -6.0000e+00 1.4977e-01 6.5888e-04 -1.5688e-04 2.9145e-05 8.3774e-05 -6.0000e+00 1.1347e-02 -1.5153e-02 2.0898e-04 10 0 0 10 0 0 33.29 24.41 0.44 -0.01515 -0.01633 352 36 1 5 0 154.600 31.75 20.03 24.41 10.79 9.2 874.66 -126898 -112280 -101301 -124181 -108229 -151353 -128560 -109539 -108423 -82673 -110993 -94341 -71931 -73869 -62865 -37858 -45641 -37899 -23014 -35491 -13379 -32479 -35115 -28082 -18792 -38612 -21398 -37538 -28860 -35608 -17587 -10188 -14678 -15477 -7909 -8968 -5334 -5284 -1359 1086 2072 -2580 -262 -685 -750 429 969 -130 1735 550 2474 4931 3193 3476 2737 2000 2142 1870 318 610 961 1620 2412 2318 2940 1304 1021 943 1370 931 1197 1353 614 232 45 -1002 -1540 -1214 -1950 -792 -1480 -1193 -1710 -1566 -712 -680 -419 132 494 333 525 811 289 515 638 274 540 249 246 -89 -332 -619 -66 -190 -800 -863 -811 -651 -519 -82 -62 -283 -121 51 76 424 376 418 35 -151 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