File name: Pandora249s1_ChicagoIL_20240322_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T091018.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240322_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240322T164258.8Z 8847.696514 373 1 54.80 2 44.26 152.75 125.38 7.20 0.00 1 0.00 1 0 17 1.956e-02 7.430e-03 6.010e-03 2.389e-03 2.515329e-01 1.257109e-03 3.112704e-03 -6.000000e+00 1.170116e-02 226.57 -2.00 3.53 -2.00 316.74 0.00e+00 4.692436e-04 1.556381e-04 5.793154e-05 -6.000000e+00 5.058454e-04 276.02 -2.00 20.00 -2.00 316.16 0.00e+00 1.394 0.000 302.00 328.00 3 6.4890e+00 3.2746e-03 1.8969e-02 -6.0000e+00 2.9033e-02 5.4622e-02 3.6536e-03 1.3017e-02 -6.0000e+00 3.1467e-02 -1.7248e-02 2.1567e-03 6.4658e-03 -6.0000e+00 1.8689e-02 4.4405e-03 1.0338e-03 1.8789e-03 -6.0000e+00 7.9251e-03 1.4707e-04 -3.6708e-05 7.5296e-05 2.4733e-05 -6.0000e+00 5.9920e-04 -7.7379e-03 0.0000e+00 11 9 0 11 32 0 99.99 24.25 0.11 -0.00774 -0.00801 26 3 1 5 0 2107.400 31.75 20.20 24.25 8.81 9.1 861.25 900000 -5854 -8887 555 -6113 1172 -5148 -6814 1123 1160 7506 -5757 1879 6063 -15 845 -1757 1513 758 4938 3091 -702 -754 1402 770 -3521 394 2490 -911 2550 -189 2451 -1574 -1440 -503 -2296 -1696 -1083 -288 -1580 187 -1875 -604 -378 1272 -978 -158 -887 1247 -1143 1581 1389 1075 268 1008 1745 211 1097 487 492 -345 986 2610 176 1267 55 -503 -695 -104 -219 -440 192 1404 -773 407 -279 -1797 -1252 -2423 -1042 -1588 -1717 -1140 -920 65 -94 165 -146 371 318 -10 221 138 277 498 -76 52 778 1116 109 -332 -973 -203 73 -232 -1011 -578 -166 -135 565 101 803 -19 -81 -143 -138 289 340 -403 234 -579 -467 99 -249 640 640 596 686 211 412 606 -119 820 378 -224 -5 -443 -511 -228 58 -488 -80 -116 900000 -916 -1499 83 -897 148 -694 -1011 170 188 1165 -1033 334 1165 -3 216 -490 424 222 1430 933 -221 -239 449 261 -1292 140 837 -298 774 -60 805 -577 -550 -187 -838 -638 -455 -128 -836 109 -1188 -391 -248 821 -643 -102 -561 754 -702 971 905 745 197 763 1341 168 864 381 381 -273 809 2078 153 1113 47 -400 -576 -87 -185 -410 189 1389 -764 376 -237 -1527 -984 -1923 -883 -1387 -1663 -1187 -1011 75 -107 199 -183 469 393 -11 257 146 278 504 -84 58 951 1462 147 -431 -1182 -248 88 -274 -1283 -767 -230 -195 797 150 1223 -29 -116 -203 -182 368 442 -557 343 -825 -668 149 -362 879 834 739 901 266 551 856 -176 1225 584 -338 -7 -733 -865 -390 98 -800 -126 -177 SS 20240322T165923.3Z 8847.707909 386 1 6.40 2 42.99 158.41 124.95 11.89 0.00 1 0.00 1 0 25 9.152e-03 6.003e-03 6.098e-03 3.136e-03 2.432767e-01 1.660809e-03 3.003884e-03 -6.000000e+00 5.476870e-03 226.57 -2.00 3.53 -2.00 315.99 0.00e+00 2.502751e-04 1.729708e-04 3.822432e-05 -6.000000e+00 2.367341e-04 276.02 -2.00 20.00 -2.00 315.43 0.00e+00 1.366 0.000 302.00 328.00 3 5.1001e+00 4.2902e-03 1.8407e-02 -6.0000e+00 1.3589e-02 1.7261e-02 4.7737e-03 1.2497e-02 -6.0000e+00 1.4728e-02 -9.3977e-03 2.7587e-03 6.2038e-03 -6.0000e+00 8.7475e-03 9.7708e-04 1.2701e-03 1.7694e-03 -6.0000e+00 3.7099e-03 6.2524e-04 4.5076e-05 9.7779e-05 2.4675e-05 -6.0000e+00 2.8041e-04 -8.7638e-03 0.0000e+00 12 1 1 12 9 1 98.49 24.30 0.16 -0.00876 -0.00843 4 4 1 5 0 1278.810 31.75 20.33 24.30 9.43 9.1 864.57 900000 -566 -2416 -1389 -3707 709 -2026 -2307 41 520 718 -237 -1976 834 598 481 -1094 -729 3210 2119 889 69 715 813 332 96 323 -785 981 1182 1618 1784 36 -1401 -1535 -756 -925 -714 -221 -1286 -78 -2009 -790 -427 -19 -833 -682 -1124 124 67 454 -203 1058 536 512 1339 473 554 779 692 561 1054 1647 555 176 -121 406 -85 707 275 -50 -303 402 -313 -330 -62 -374 373 -571 -147 -740 -1454 -1201 -1623 -577 -541 -118 -193 -54 44 112 636 579 898 1341 142 647 876 26 -49 -625 -824 -219 -404 -107 -1223 -775 -215 -43 -125 -122 533 70 -247 -230 319 675 602 361 36 -300 -152 -489 35 73 674 345 1174 705 660 200 -154 389 -6 -277 224 -66 -289 -349 -115 -174 -289 -210 900000 -117 -533 -296 -742 126 -371 -459 9 119 168 -56 -513 236 176 158 -387 -267 1170 805 350 28 285 335 144 40 136 -350 404 466 644 753 16 -630 -678 -347 -407 -353 -119 -819 -51 -1435 -577 -316 -14 -617 -497 -803 85 45 317 -151 825 414 411 1091 395 464 643 565 465 915 1439 522 170 -112 347 -74 622 250 -48 -307 412 -317 -316 -57 -333 306 -472 -130 -697 -1442 -1285 -1749 -651 -621 -143 -244 -65 55 132 721 634 924 1389 152 759 1076 33 -63 -779 -1006 -263 -480 -128 -1572 -993 -287 -57 -176 -172 772 100 -350 -315 405 867 789 477 48 -423 -216 -683 50 98 895 438 1444 900 855 275 -220 540 -9 -417 339 -103 -467 -546 -185 -272 -438 -324 SS 20240322T170424.1Z 8847.711391 389 1 54.09 2 42.66 160.19 124.77 13.30 0.00 1 0.00 1 0 17 2.838e-02 9.974e-03 9.051e-03 3.456e-03 2.546727e-01 1.821540e-03 3.151732e-03 -6.000000e+00 1.697959e-02 226.57 -2.00 3.53 -2.00 316.96 0.00e+00 -7.262771e-06 2.346375e-04 4.917484e-05 -6.000000e+00 7.341981e-04 276.02 -2.00 20.00 -2.00 316.37 0.00e+00 1.358 0.000 302.00 328.00 3 6.9715e+00 4.7553e-03 1.8845e-02 -6.0000e+00 4.2129e-02 8.1175e-02 5.3181e-03 1.3153e-02 -6.0000e+00 4.5665e-02 -2.4433e-02 3.1493e-03 6.5484e-03 -6.0000e+00 2.7122e-02 8.1667e-03 1.5067e-03 1.8692e-03 -6.0000e+00 1.1498e-02 9.2571e-05 -5.5707e-04 1.0878e-04 2.4971e-05 -6.0000e+00 8.6973e-04 -6.2552e-03 0.0000e+00 12 9 9 12 9 1 99.98 24.32 0.06 -0.00626 -0.01044 20 2 1 5 0 2575.520 31.75 20.27 24.32 9.51 9.2 866.14 900000 -3411 -7406 1139 -10018 10834 -11990 -10865 1711 4511 -1803 -9128 -1071 7276 -1901 -2354 -1279 2766 1342 7655 3505 828 -2159 2691 1982 -7349 1432 2965 393 5216 2910 2313 -2380 -2479 700 -1529 -3605 740 451 -2831 957 -2373 327 2111 2259 -526 -996 -1385 1794 -2002 1505 889 1226 304 1262 3346 232 676 268 503 -1977 1097 2934 308 982 -79 -1915 -965 -465 -847 -883 283 1261 -881 29 1130 -2690 -1153 -4276 -1906 -1571 -1744 -1066 -622 1295 117 543 621 807 553 -542 229 -517 460 244 -734 365 176 1106 705 -324 -1095 -269 -939 19 -1015 -282 -495 225 449 157 903 59 161 -211 -818 506 251 -409 -101 -692 160 -31 175 516 799 470 526 -106 211 558 -330 1256 922 -467 196 -490 -488 -162 -188 -776 -18 175 900000 -501 -1183 163 -1469 1194 -1661 -1611 248 681 -296 -1631 -188 1322 -429 -591 -338 729 371 2048 999 243 -658 808 630 -2667 480 944 121 1459 843 717 -828 -901 242 -521 -1298 287 206 -1569 520 -1421 197 1268 1355 -322 -604 -822 1107 -1158 949 542 790 208 888 2359 171 499 196 362 -1476 833 2352 270 874 -68 -1562 -743 -363 -725 -833 280 1260 -879 27 955 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