File name: Pandora249s1_ChicagoIL_20240424_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T092321.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240424_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240424T170757.9Z 8880.713865 417 1 54.23 2 30.13 159.84 152.32 322.85 0.00 1 0.00 1 0 17 4.419e-02 1.727e-02 1.812e-02 6.354e-03 2.436896e-01 3.357338e-03 3.035001e-03 -6.000000e+00 2.667733e-02 229.23 -2.00 3.53 -2.00 317.02 0.00e+00 1.590419e-04 4.461298e-04 1.439552e-04 -6.000000e+00 1.157644e-03 279.68 -2.00 20.00 -2.00 316.36 0.00e+00 1.156 0.000 302.00 328.00 3 7.9451e+00 8.8361e-03 1.7352e-02 -6.0000e+00 6.6521e-02 6.5074e-02 9.8783e-03 1.2847e-02 -6.0000e+00 7.1896e-02 -2.4476e-02 5.8471e-03 6.3452e-03 -6.0000e+00 4.2741e-02 1.2372e-02 2.8014e-03 1.7746e-03 -6.0000e+00 1.7964e-02 4.2829e-05 -8.7284e-04 1.9958e-04 2.3682e-05 -6.0000e+00 1.3470e-03 -1.8127e-03 0.0000e+00 12 9 8 11 8 0 99.95 24.71 -0.42 -0.00181 -0.00837 20 2 2 5 0 2711.180 32.00 19.84 24.71 12.39 9.3 885.64 -13870 8519 -7510 6942 -12744 22118 -4931 -13569 5043 3116 2430 -5130 1181 12837 -3144 -1942 -4959 9295 3646 11389 4467 2495 -4075 -1462 1639 -12063 1908 7526 662 7916 9005 3815 -4622 -3694 -254 -4829 -4756 -3608 -1780 -3102 2329 -4024 336 3887 1392 -2381 -396 -3114 726 -4147 1348 6239 826 -1746 1211 6307 -1090 3147 541 -733 -3093 2340 4558 -697 1505 2417 -1273 -615 -1025 -1880 -728 -796 3934 -661 1248 1310 -4443 -1890 -7613 -394 -2700 -2422 -623 214 1770 869 1354 321 1063 380 -2125 -200 664 783 738 -2280 -223 160 2247 1194 -571 -2257 553 -2213 135 -1170 -414 656 -91 1085 198 2208 -7 -1007 -542 -1172 646 1122 -793 86 -866 -490 448 -417 341 1081 612 1214 -367 -587 473 -832 2046 2601 -1294 -307 -782 -761 -371 328 -860 -147 533 -1860 1013 -1092 849 -1737 2166 -632 -2052 700 471 376 -865 199 2156 -699 -472 -1318 2217 951 2830 1215 694 -1217 -439 501 -4388 608 2182 193 2051 2332 1104 -1555 -1282 -84 -1601 -1630 -1375 -784 -1618 1286 -2521 208 2358 865 -1527 -245 -1927 421 -2503 789 3677 544 -1239 865 4377 -827 2295 400 -542 -2371 1783 3649 -626 1348 2052 -1038 -474 -808 -1632 -688 -800 3840 -661 1157 1110 -3595 -1383 -5874 -305 -2391 -2366 -645 232 2004 964 1583 395 1312 462 -2500 -232 701 776 740 -2531 -267 191 2828 1542 -720 -2964 662 -2697 170 -1589 -533 873 -127 1586 307 3442 -12 -1504 -745 -1654 865 1524 -1158 121 -1275 -724 642 -581 493 1474 797 1535 -487 -828 698 -1288 3137 4076 -2004 -496 -1315 -1309 -642 557 -1434 -235 820 SS 20240424T180021.0Z 8880.750244 448 1 7.09 2 28.88 185.79 156.33 348.94 0.00 1 0.00 1 0 17 6.682e-03 5.418e-03 1.523e-03 1.018e-03 2.250221e-01 5.496677e-04 2.771708e-03 -6.000000e+00 4.038547e-03 229.23 -2.00 3.53 -2.00 315.08 0.00e+00 1.363365e-04 4.726382e-05 3.062482e-05 -6.000000e+00 1.754702e-04 279.68 -2.00 20.00 -2.00 314.52 0.00e+00 1.142 0.000 302.00 328.00 3 3.4859e+00 1.4117e-03 1.6347e-02 -6.0000e+00 1.0071e-02 2.9200e-02 1.5622e-03 1.1633e-02 -6.0000e+00 1.0887e-02 -3.5926e-04 8.9482e-04 5.7322e-03 -6.0000e+00 6.4669e-03 -8.5402e-04 3.9460e-04 1.6059e-03 -6.0000e+00 2.7361e-03 3.9544e-03 3.0694e-05 3.1434e-05 2.3813e-05 -6.0000e+00 2.0493e-04 -7.6657e-03 0.0000e+00 12 1 1 12 1 1 99.70 24.85 0.32 -0.00767 -0.00744 29 23 1 5 0 236.120 32.25 19.91 24.85 14.12 9.3 897.39 900000 -1393 -1903 -2238 -1587 -1005 -491 -83 364 310 -557 -242 -276 107 -437 189 -179 269 610 604 1224 1026 552 534 712 256 393 -247 370 958 1327 1550 686 -106 -887 -685 -729 -630 -546 -586 -767 -913 -901 -682 -757 -512 -662 -661 -219 35 540 579 889 729 676 445 679 580 643 800 847 1170 1204 784 256 -77 -65 -82 418 570 108 -485 -73 -155 -150 -224 71 -43 226 -268 -613 -1016 -1423 -1291 -1021 -792 -776 -211 -309 -275 151 212 318 867 969 835 678 352 -94 -229 -310 -333 -121 291 -268 -674 -553 -460 -294 -31 234 -157 -175 -135 100 269 658 468 103 24 -198 -156 -72 162 494 422 711 1049 917 478 478 109 134 312 -36 -190 83 -153 -390 -323 -334 -475 -539 900000 -432 -618 -708 -490 -286 -139 -25 114 104 -192 -84 -101 41 -179 85 -81 125 291 297 611 515 280 266 370 139 215 -131 193 474 659 812 366 -59 -489 -364 -401 -371 -360 -413 -579 -705 -719 -551 -612 -410 -523 -508 -170 27 420 457 740 613 589 383 591 507 555 682 732 1059 1128 756 252 -72 -59 -73 377 541 110 -508 -75 -162 -153 -217 64 -37 195 -241 -594 -1019 -1499 -1435 -1161 -931 -939 -257 -381 -332 176 241 340 896 1008 903 784 422 -118 -292 -380 -404 -142 337 -321 -837 -700 -591 -394 -42 328 -220 -247 -184 129 341 804 584 132 32 -269 -212 -96 215 638 533 877 1259 1136 612 626 144 181 431 -50 -275 122 -230 -579 -487 -489 -690 -762 SS 20240424T180414.9Z 8880.752950 452 1 4.74 2 28.97 187.74 156.47 351.12 0.00 1 0.00 1 0 17 6.454e-03 5.349e-03 6.601e-04 4.531e-04 2.246551e-01 2.447987e-04 2.769463e-03 -6.000000e+00 3.900848e-03 229.23 -2.00 3.53 -2.00 315.00 0.00e+00 1.378827e-04 2.068777e-05 3.578599e-05 -6.000000e+00 1.694856e-04 279.68 -2.00 20.00 -2.00 314.44 0.00e+00 1.142 0.000 302.00 328.00 3 1.5187e+00 6.2795e-04 1.6341e-02 -6.0000e+00 9.7275e-03 1.6288e-02 6.9483e-04 1.1618e-02 -6.0000e+00 1.0516e-02 -1.6410e-04 3.9821e-04 5.7233e-03 -6.0000e+00 6.2464e-03 -8.6733e-04 1.7476e-04 1.6043e-03 -6.0000e+00 2.6428e-03 2.8428e-02 4.6591e-05 1.4012e-05 2.3865e-05 -6.0000e+00 1.9794e-04 -7.7343e-03 0.0000e+00 12 1 1 12 1 1 99.95 24.86 0.29 -0.00773 -0.00738 146 171 1 5 0 32.200 32.25 20.00 24.86 14.26 9.4 899.14 900000 -1220 -1728 -1642 -1450 -1030 -1043 89 411 -153 -419 -492 -288 -7 -138 165 -47 329 609 665 732 1201 1004 628 654 590 37 -224 384 999 920 1347 1034 -71 -849 -675 -956 -704 -156 -634 -936 -885 -764 -651 -676 -465 -624 -598 -463 18 431 644 869 619 692 607 635 543 466 723 956 1152 1071 794 107 -82 -121 -98 370 517 114 -222 -260 -160 -142 -119 -13 162 131 -217 -680 -1059 -1422 -1325 -1056 -834 -695 -421 -259 -174 210 325 449 798 1097 818 694 419 -48 -222 -252 -465 -36 283 -298 -566 -708 -336 -293 0 91 -249 -89 -126 52 358 453 556 342 -23 -252 -138 -135 24 444 376 692 1053 903 605 365 84 101 184 -4 -106 -67 -56 -382 -353 -275 -445 -432 900000 -395 -585 -540 -462 -322 -326 28 143 -54 -151 -179 -111 -3 -60 75 -22 157 299 336 361 593 500 325 354 318 20 -123 197 509 474 698 573 -39 -468 -374 -527 -419 -100 -448 -715 -697 -601 -520 -540 -368 -487 -469 -353 14 330 519 715 519 602 524 557 478 406 622 832 1021 992 762 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