File name: Pandora249s1_ChicagoIL_20240508_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240516T064624.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240508_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T111200.6Z 8894.466674 53 1 53.63 2 84.85 71.32 85.47 65.86 0.00 1 0.00 1 0 25 7.193e-01 7.855e-02 2.242e-01 2.527e-02 1.177910e+00 1.531399e-02 1.431948e-02 -6.000000e+00 4.372250e-01 230.42 -2.00 3.53 -2.00 321.21 0.00e+00 -3.642925e-02 3.609287e-03 3.839173e-03 -6.000000e+00 1.945074e-02 281.23 -2.00 20.00 -2.00 320.40 0.00e+00 9.612 0.017 302.00 328.00 3 -9.2598e-02 4.5265e-02 1.2461e-01 -6.0000e+00 1.0948e+00 2.9073e+00 5.2416e-02 1.0690e-01 -6.0000e+00 1.1819e+00 -2.4737e+00 2.9700e-02 2.9695e-02 -6.0000e+00 7.0080e-01 7.0122e-01 1.5706e-02 3.1178e-02 -6.0000e+00 2.9559e-01 8.8366e-06 9.7603e-04 6.0629e-04 4.5884e-04 -6.0000e+00 2.1941e-02 -1.3257e-02 2.0868e-04 12 8 8 10 0 0 -5.57 25.25 0.91 -0.01326 -0.00592 29 3 1 5 0 1849.220 32.50 20.00 25.25 20.08 9.6 937.24 25388 90919 -121 89209 -6013 231184 -30864 -32373 40657 900000 68230 14107 80996 144933 5904 29708 45063 94220 29638 439059 74604 -8259 -24631 -18963 68695 -36929 67021 78155 -20150 -7815 900000 56848 -56312 66339 22517 -51375 -19892 -9319 15700 12071 85674 -11810 24260 81598 55447 -9045 427723 -55029 37622 -10587 18411 254286 13305 -1884 34496 135343 19526 36339 18616 12703 -48288 46865 92625 -4276 33072 36851 -7588 8729 38024 400 20616 40640 90447 -14512 9212 45224 -32382 -30658 -71898 -24034 5587 -10757 26987 34493 71421 36467 27218 12093 31740 10899 -20380 4252 -5653 9576 10507 -12485 68 6660 17400 10795 -1863 -10706 4551 -15882 4255 -179 -2501 4244 -10317 3135 -667 6565 2854 -3753 2202 -3952 18720 2838 -5711 211 -7114 -2814 2149 -1632 -1254 6985 5429 -2362 -3194 2084 49 -2843 5530 2889 -2589 -634 -1530 -2900 -1254 1026 -2031 2776 5289 4066 7093 -21 5128 -728 5696 -4689 -5915 4174 900000 6164 2259 7438 7142 1190 4791 6157 7597 4315 10817 5848 -1387 -5020 -4205 7385 -12159 7355 6477 -3656 -1120 900000 4711 -15387 5349 2623 -11622 -3341 -1607 2567 2460 9403 -3545 4836 8224 6334 -1742 10538 -14790 4045 -1944 2763 6265 2533 -451 6181 9397 4461 6837 3794 2390 -14925 6004 7987 -1064 6030 6537 -2113 2172 7775 134 6146 10213 13370 -5578 2428 7131 -9973 -9215 -35782 -8645 1762 -4638 8976 11473 17244 12938 10796 5572 11652 4645 -10996 1687 -2451 3798 4711 -8275 47 4922 12818 8777 -1643 -9285 2994 -11934 2652 -122 -1836 3137 -9863 3043 -784 8103 3924 -5650 3093 -5764 21631 3936 -8936 317 -11182 -3986 2722 -2063 -1533 7659 5966 -2945 -4627 3405 95 -6408 12644 7424 -6946 -1781 -4487 -8716 -3679 2819 -5859 6989 12211 SS 20240508T112351.9Z 8894.474906 56 1 54.54 2 82.75 73.22 83.50 67.64 0.00 1 0.00 1 0 17 7.520e-01 1.896e-02 2.414e-01 3.885e-03 1.063388e+00 2.287461e-03 1.153179e-02 -6.000000e+00 4.566839e-01 230.42 -2.00 3.53 -2.00 322.01 0.00e+00 1.784723e-03 1.348808e-03 2.999977e-03 -6.000000e+00 1.983240e-02 281.23 -2.00 20.00 -2.00 321.58 0.00e+00 7.312 0.007 302.00 328.00 3 4.8900e-01 8.8954e-03 9.5895e-02 -6.0000e+00 1.1413e+00 9.1370e-01 1.3606e-02 6.9199e-02 -6.0000e+00 1.2313e+00 -1.1567e+00 1.4128e-02 3.4416e-02 -6.0000e+00 7.3210e-01 4.5724e-01 6.2879e-03 1.2176e-02 -6.0000e+00 3.0903e-01 8.1744e-05 -1.1179e-03 9.7994e-05 1.5408e-04 -6.0000e+00 2.2937e-02 -1.4297e-02 2.1676e-04 12 8 8 10 0 0 10.52 25.28 0.51 -0.01430 -0.02270 130 13 1 5 0 419.470 32.50 20.01 25.28 20.78 9.6 941.76 -221177 -143768 -262309 -123954 -196710 -242814 -257352 -215940 -186541 -126845 -154718 -80180 -166641 -109385 -140261 -55596 -63344 300027 12657 -85296 38359 12050 -113647 -100260 -30501 -159752 34119 -63011 -28292 -93129 900000 137266 -78020 -37718 34594 -36482 -6751 468 20260 61331 132135 288 39586 42632 4613 10717 53622 -4765 61823 33454 37259 85007 44418 35466 40431 43511 27181 46982 14608 23686 10152 33681 38231 24396 35214 27261 16504 19459 15585 12889 11360 14467 15641 4226 5021 5847 -2854 1175 -11994 -835 -5001 2625 2700 1043 5462 2951 1644 952 2534 1337 -1314 -87 -3138 -1478 126 -3379 -2565 -1936 -655 -590 -1308 -1287 -2101 -2167 -1476 -2725 -1813 -1310 -2568 -1088 -1174 -1523 -94 -486 -356 -352 368 302 -40 367 350 1284 1329 719 1885 1794 2061 1240 626 385 263 72 888 826 -155 157 -41 -80 -461 -148 -388 -370 -1219 -2666 -941 -5962 -683 -2032 -3680 -4520 -2677 -1863 -743 -1279 -359 -2238 -1093 -2464 -517 -742 1137 83 -1528 198 79 -2622 -2141 -347 -6877 212 -1098 -343 -2329 900000 520 -3044 -1086 485 -1009 -143 10 445 1069 1302 12 1125 1195 189 414 1381 -231 1663 1318 1595 2576 2272 2190 2573 2835 2152 3044 1256 1768 854 2373 2926 2486 3615 3202 2226 2706 2492 2417 2423 3173 3389 967 1029 1057 -519 208 -2740 -206 -1569 905 1064 457 2439 1430 767 460 1209 691 -661 -41 -1498 -731 70 -2106 -1908 -1694 -645 -615 -1341 -1207 -1767 -1696 -1163 -2296 -1605 -1249 -2777 -1231 -1548 -2274 -148 -727 -569 -550 569 483 -62 584 550 2060 2012 1050 2635 2438 2744 1722 991 664 528 149 2010 2026 -385 414 -112 -222 -1272 -393 -960 -900 -2790 SS 20240508T113443.2Z 8894.482445 59 1 54.46 2 80.81 74.96 81.66 69.26 0.00 1 0.00 1 0 17 7.299e-01 9.053e-03 1.048e-01 1.463e-03 8.870415e-01 8.309348e-04 9.871237e-03 -6.000000e+00 4.431179e-01 230.42 -2.00 3.53 -2.00 321.20 0.00e+00 2.873240e-03 4.087335e-04 1.210717e-03 -6.000000e+00 1.923948e-02 281.23 -2.00 20.00 -2.00 320.70 0.00e+00 5.946 0.004 302.00 328.00 3 4.5820e-01 2.7988e-03 7.5904e-02 -6.0000e+00 1.1076e+00 2.3570e-01 4.0922e-03 4.9748e-02 -6.0000e+00 1.1951e+00 -2.7776e-01 4.4159e-03 2.7700e-02 -6.0000e+00 7.1038e-01 1.0405e-01 2.0633e-03 1.0493e-02 -6.0000e+00 2.9915e-01 3.9371e-04 -2.0284e-04 3.8048e-05 1.2848e-04 -6.0000e+00 2.2255e-02 -1.4554e-02 2.2248e-04 11 8 0 10 0 0 35.68 25.35 0.44 -0.01455 -0.01608 310 31 1 5 0 175.650 32.50 20.01 25.35 21.41 9.6 945.22 -291928 -204087 -235801 -189214 -215685 -260287 -272417 -225674 -185607 -85284 -214773 -136547 -131236 -132712 -144352 -112082 -85962 -55806 -69413 -114056 -56406 -42393 -103674 -89567 -49978 -107679 -44563 -66316 -58327 -94768 -24394 -17267 -46642 -35558 -17186 -33913 -13010 -16140 -4979 1908 11928 -6377 1660 4382 -2128 4783 8922 354 3965 2945 7142 9446 6005 6157 8442 8223 3612 4015 1241 2407 1535 2346 7462 5871 4109 5870 3297 2939 2954 2195 2398 1822 2282 1247 -433 -1110 -1179 -1777 -3887 -2135 -1271 -765 -1127 -971 4 690 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