File name: Pandora249s1_ChicagoIL_20240701_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240702T060341.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240701_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240701T105534.3Z 8948.455258 162 1 54.01 2 85.02 63.24 44.69 108.79 0.00 1 0.00 1 0 17 7.236e-01 4.309e-02 3.682e-01 1.800e-02 1.134088e+00 1.149239e-02 1.396676e-02 -6.000000e+00 4.531165e-01 232.85 -2.00 3.53 -2.00 322.41 0.00e+00 -2.737685e-02 6.259135e-03 1.699060e-02 -6.000000e+00 2.171945e-02 286.67 -2.00 20.00 -2.00 321.95 0.00e+00 9.828 0.018 302.00 328.00 3 -1.3159e-01 4.6739e-02 1.4524e-01 -6.0000e+00 1.1431e+00 2.1272e+00 5.6688e-02 1.2038e-01 -6.0000e+00 1.2389e+00 -2.4237e+00 3.6464e-02 5.1134e-02 -6.0000e+00 7.3131e-01 8.9011e-01 1.8592e-02 1.1270e-02 -6.0000e+00 3.0558e-01 1.1381e-05 -8.0207e-04 4.8532e-04 5.3664e-04 -6.0000e+00 2.3085e-02 -9.2519e-03 1.7234e-04 12 8 8 10 0 0 19.01 25.48 1.38 -0.00925 -0.01528 46 5 1 5 0 1174.010 32.50 20.00 25.48 22.38 9.6 949.51 -6817 900000 63498 220172 8170 900000 148545 -10256 189352 218079 249741 79487 900000 900000 -12014 46457 50680 900000 900000 900000 900000 -39802 -46919 76700 40663 -49656 106074 900000 137869 60372 272729 900000 -84128 -9095 -22064 -3453 17274 143028 900000 121902 162516 -16479 36520 900000 54167 32284 38490 43096 199327 34926 76122 900000 18946 16354 71575 900000 99465 62048 33551 32301 -22242 57806 44459 16125 3620 329262 69132 31707 16835 -1944 30219 42986 37926 11211 -3696 42952 -14938 28330 -65716 -15735 3773 4708 271 14497 46970 28958 19293 17619 4581 -8783 2854 9882 -10440 16629 15554 -11125 -7160 3027 4350 102 1405 -2204 2487 -5023 6701 -4571 2920 1409 -11888 -7645 -1153 773 -1315 -2054 -195 -2369 -1611 3032 -4161 2273 -1236 783 16 54 -439 8470 8778 1012 -986 708 1648 -1393 3100 2783 -1390 1868 -1219 -1678 1009 374 -1942 246 -837 -537 900000 2131 3855 322 900000 2601 -539 3315 3818 4373 2151 900000 900000 -956 2145 2259 900000 900000 900000 900000 -3294 -4182 2198 1877 -5928 2533 900000 2414 1538 4775 900000 -11383 -594 -1545 -187 770 2504 900000 3105 3104 -1967 2500 900000 2587 1747 1838 1921 3490 2018 3199 900000 1725 1661 4512 900000 5225 4672 3114 2715 -2960 3441 3269 1750 482 5765 4963 3498 2388 -378 4709 6172 5645 2022 -686 4362 -2459 3026 -19906 -3416 806 1171 80 4061 10116 7859 5979 5646 1652 -3476 944 2890 -3711 4804 5202 -5766 -4237 1892 3024 77 1026 -1525 1468 -2999 3637 -2937 1845 979 -10595 -7604 -1257 939 -1762 -2855 -265 -3231 -2181 4039 -6222 3279 -1820 1074 21 68 -540 9314 9499 1236 -1407 1178 3161 -3102 6603 6490 -3668 5096 -3547 -4961 2883 1033 -5082 575 -2036 SS 20240701T110706.3Z 8948.463267 165 1 54.57 2 83.09 65.07 42.69 111.37 0.00 1 0.00 1 0 25 7.340e-01 1.474e-02 2.431e-01 3.260e-03 9.411724e-01 1.932871e-03 1.035119e-02 -6.000000e+00 4.499502e-01 232.85 -2.00 3.53 -2.00 321.87 0.00e+00 1.906096e-04 1.182860e-03 1.661729e-03 -6.000000e+00 2.043067e-02 286.67 -2.00 20.00 -2.00 321.39 0.00e+00 7.602 0.008 302.00 328.00 3 1.5243e-01 7.7219e-03 9.1720e-02 -6.0000e+00 1.1315e+00 4.9532e-01 1.1977e-02 5.5772e-02 -6.0000e+00 1.2187e+00 -6.3728e-01 1.2392e-02 3.0604e-02 -6.0000e+00 7.2343e-01 2.4970e-01 5.4891e-03 9.8817e-03 -6.0000e+00 3.0589e-01 1.1111e-04 -4.3187e-04 8.7138e-05 1.3682e-04 -6.0000e+00 2.2430e-02 -1.1122e-02 2.1546e-04 12 8 8 10 0 0 -17.28 25.52 0.55 -0.01112 -0.01437 178 18 1 5 0 306.530 32.50 20.01 25.52 22.94 9.6 953.93 -150593 900000 -276333 -145618 -31277 -307519 -262913 -284164 -90503 900000 -226225 -179465 -86211 -165543 -211807 -133776 -148585 -33228 -18779 -151873 -15790 -33243 -114276 -98181 -49068 -159627 -45474 -104624 -46998 -117334 484 44837 -90254 -41586 -9353 -62974 3423 28673 53204 25699 89980 -474 17890 30858 15759 24790 27019 10980 22417 34626 26443 36104 27642 11078 22552 18831 20533 20430 5897 5072 6824 6554 17420 17453 8604 15287 11731 9918 8093 7725 8368 8867 7167 3797 949 930 -1143 4552 -11374 -1991 -634 719 -790 139 2292 3427 -279 7 828 899 654 257 -2157 522 -51 -1852 -870 -1707 -703 -806 -90 -1458 -1085 -1645 -664 -1988 -1664 -1216 -2096 -968 -720 -204 279 85 -24 -278 -107 915 125 268 52 605 785 344 729 1248 1023 1545 398 469 196 331 297 283 -191 -12 -100 32 -264 -149 -249 -300 -609 -479 900000 -2954 -463 -99 -4087 -2355 -3531 -288 900000 -2157 -1245 -299 -1674 -4406 -1585 -2404 -192 -103 -3335 -91 -231 -1849 -1475 -546 -5212 -535 -2195 -553 -3021 5 342 -3184 -1005 -166 -1901 57 428 761 588 1258 -18 603 942 566 827 910 457 898 1354 1269 1802 1696 891 1763 1628 1821 1831 596 500 661 683 1855 2141 1283 2230 1816 1652 1520 1670 2021 2274 1884 984 231 204 -238 904 -2964 -566 -215 283 -359 62 1074 1691 -150 4 460 487 338 126 -1062 261 -29 -1258 -697 -1618 -682 -824 -89 -1461 -976 -1408 -578 -1863 -1650 -1189 -2296 -1200 -1023 -296 425 131 -36 -411 -157 1375 198 441 86 951 1172 497 1100 1818 1464 2269 612 838 372 698 680 650 -475 -33 -257 83 -689 -401 -630 -704 -1354 SS 20240701T111753.0Z 8948.470753 168 1 54.49 2 81.26 66.76 40.86 113.92 0.00 1 0.00 1 0 17 5.427e-01 7.535e-03 1.133e-01 1.301e-03 7.987135e-01 7.365978e-04 8.978946e-03 -6.000000e+00 3.323595e-01 232.85 -2.00 3.53 -2.00 321.02 0.00e+00 1.361464e-03 3.566081e-04 1.367714e-03 -6.000000e+00 1.475031e-02 286.67 -2.00 20.00 -2.00 320.44 0.00e+00 6.213 0.004 302.00 328.00 3 1.0273e-01 2.4919e-03 7.4980e-02 -6.0000e+00 8.3416e-01 1.6643e-01 3.4979e-03 4.4582e-02 -6.0000e+00 8.9776e-01 -1.8607e-01 3.5552e-03 2.3597e-02 -6.0000e+00 5.3448e-01 6.4277e-02 1.6816e-03 7.6242e-03 -6.0000e+00 2.2611e-01 4.9589e-04 6.0632e-05 3.5654e-05 1.0024e-04 -6.0000e+00 1.6583e-02 -1.1863e-02 2.2310e-04 11 8 0 10 0 0 -1.64 25.59 0.46 -0.01186 -0.01141 401 41 1 5 0 135.870 32.50 20.01 25.59 23.64 9.6 958.02 -185017 900000 -166663 -178190 62577 -240383 -175475 -170458 -148084 -134395 -180417 -89575 -109095 -99047 -140744 -83146 -84594 -31646 -47357 -89792 -23401 -40165 -58356 -56150 -59491 -80816 -40289 -65179 -26175 -74638 -34190 -8360 -30999 -21321 -19572 -14345 -3914 -10139 6535 9898 2963 -2792 -1293 2886 -514 -343 3970 2780 50 2080 2462 9933 5169 4953 5024 4130 4022 2993 1479 2515 1676 2141 3192 2650 3205 2791 2401 1083 1623 1576 1504 2256 1469 749 -296 -934 -1659 -1250 -3517 -1618 -1746 -673 -1315 -1092 -430 -547 152 230 118 321 665 626 -432 123 47 9 124 45 11 -104 -371 -579 -336 -440 -964 -994 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