File name: Pandora249s1_ChicagoIL_20240731_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240801T060430.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240731_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240731 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240731T124213.7Z 8978.529325 218 1 54.75 2 69.82 83.49 27.37 111.97 0.00 1 0.00 1 0 25 4.243e-02 6.748e-03 2.201e-02 2.195e-03 3.940307e-01 1.174883e-03 4.661791e-03 -6.000000e+00 2.594977e-02 232.27 -2.00 3.53 -2.00 318.83 0.00e+00 2.297984e-04 2.685385e-04 1.402737e-04 -6.000000e+00 1.151828e-03 288.27 -2.00 20.00 -2.00 318.03 0.00e+00 2.867 0.000 302.00 328.00 3 4.5646e+00 3.2514e-03 3.5194e-02 -6.0000e+00 6.5003e-02 1.4821e-02 3.7393e-03 2.1047e-02 -6.0000e+00 6.9947e-02 -1.0336e-03 2.6120e-03 1.0226e-02 -6.0000e+00 4.1692e-02 -5.3782e-03 1.3579e-03 2.8535e-03 -6.0000e+00 1.7623e-02 2.0235e-04 2.5208e-05 6.8783e-05 3.4626e-05 -6.0000e+00 1.2949e-03 -1.5973e-02 2.4888e-04 11 8 0 10 0 0 98.81 26.97 0.56 -0.01597 -0.01578 43 4 1 5 0 1273.110 33.50 20.00 26.97 30.79 9.8 1003.80 -6377 33058 -4290 1858 -2746 -12059 5649 -11530 12638 -4315 -1920 2940 -8044 1203 1806 -5755 -5207 12334 4060 156 1816 -6014 -3957 1514 -5739 -10603 -2713 -6238 403 -1621 -1947 2910 -1648 797 -7189 -4908 65 -126 3442 2653 2385 -5530 -855 1526 1320 254 -1377 -2406 -756 674 -852 5465 257 1209 706 94 2150 216 958 -100 1935 1185 1362 754 73 542 167 272 -172 907 455 598 -70 182 -1012 309 -548 15 -2487 -460 -565 -1267 -1621 -1075 -175 -183 -150 -215 272 56 403 1116 923 73 1081 79 -191 346 295 -200 -234 -527 -354 -826 -155 -1281 -378 -339 -418 -148 -68 566 35 -249 114 267 313 402 -3 90 -411 -648 -82 2 245 1081 523 1289 418 501 246 -231 -60 850 -201 -192 192 12 -317 -158 -456 -309 -61 -180 722 -145 58 -85 -390 158 -427 414 -182 -83 127 -437 70 124 -488 -483 1027 390 16 194 -705 -466 179 -780 -1598 -386 -897 52 -212 -270 428 -281 142 -1379 -902 12 -26 839 774 720 -1953 -302 539 472 92 -509 -895 -277 249 -336 2192 117 585 362 50 1158 120 521 -54 1046 683 856 475 48 350 112 178 -108 623 349 489 -59 149 -789 217 -386 10 -1725 -317 -444 -1126 -1464 -1031 -176 -198 -172 -238 305 67 451 1147 882 68 1024 82 -226 422 392 -275 -310 -651 -406 -1004 -183 -1626 -500 -474 -577 -219 -108 935 58 -399 171 375 456 598 -5 140 -664 -1048 -128 3 355 1586 739 1783 612 743 393 -391 -98 1437 -362 -364 355 24 -612 -301 -890 -576 -109 SS 20240731T124820.3Z 8978.533568 221 1 54.43 2 68.69 84.46 26.35 113.79 0.00 1 0.00 1 0 17 1.091e-01 7.285e-03 2.943e-02 2.453e-03 3.767525e-01 1.313666e-03 4.411520e-03 -6.000000e+00 6.682288e-02 232.27 -2.00 3.53 -2.00 318.74 0.00e+00 -1.990157e-04 2.950814e-04 1.994496e-04 -6.000000e+00 2.968986e-03 288.27 -2.00 20.00 -2.00 317.93 0.00e+00 2.725 0.000 302.00 328.00 3 4.8839e+00 3.6293e-03 3.3486e-02 -6.0000e+00 1.6740e-01 -1.0478e-05 4.1661e-03 2.0071e-02 -6.0000e+00 1.8015e-01 3.0091e-02 2.9149e-03 9.7094e-03 -6.0000e+00 1.0729e-01 -2.0630e-02 1.5189e-03 2.7183e-03 -6.0000e+00 4.5647e-02 1.7310e-04 1.5208e-03 7.7294e-05 3.1867e-05 -6.0000e+00 3.3494e-03 -1.8458e-02 5.1205e-04 11 8 0 10 0 0 99.98 26.98 0.41 -0.01846 -0.00703 34 3 1 5 0 1600.620 33.50 20.00 26.98 31.16 9.8 1006.30 900000 82508 10630 25032 -38635 43641 52267 15460 31790 1856 2433 10293 1309 10576 2680 -6995 -2147 14234 7229 9173 7617 -1126 -7115 3705 -1741 -10200 -1212 -4488 1374 5419 -3712 3318 -846 -2234 -4537 -4086 -66 -4224 2755 3143 -279 -4363 -366 1605 247 -2513 -2339 -1666 -2484 535 742 6272 1440 -1028 -297 975 947 -806 959 543 630 643 2123 -475 -63 126 311 385 681 817 -224 298 241 120 -119 350 -609 216 -3659 -323 -204 -634 -1918 -674 -270 24 -31 338 423 20 586 1585 789 638 711 52 4 630 413 -370 -358 -170 -572 -454 -158 -1052 -603 -474 -73 148 10 649 -297 62 48 84 -3 298 -125 -302 -708 -668 -126 427 -45 442 330 1280 195 230 -71 0 -95 880 114 -141 213 -141 -16 -171 -380 -368 98 900000 1144 323 652 -1783 845 962 458 905 78 106 436 68 587 189 -622 -200 1202 695 908 794 -130 -897 444 -236 -1595 -177 -662 183 684 -541 499 -147 -419 -868 -763 -12 -951 692 935 -89 -1562 -132 581 92 -961 -893 -628 -943 200 292 2525 657 -513 -155 522 521 -456 528 296 349 376 1334 -333 -42 90 209 251 459 559 -172 243 200 98 -92 246 -428 142 -2545 -239 -158 -552 -1851 -685 -268 25 -35 394 500 23 643 1593 801 622 714 53 5 801 531 -492 -459 -218 -684 -532 -195 -1392 -776 -642 -104 226 15 1029 -474 95 73 120 -4 423 -187 -482 -1096 -1033 -203 660 -66 623 445 1819 272 348 -115 -1 -157 1497 206 -252 396 -269 -31 -325 -701 -693 177 SS 20240731T125845.4Z 8978.540803 224 1 53.50 2 66.76 86.14 24.64 117.16 0.00 1 0.00 1 0 17 3.911e-02 7.705e-03 1.595e-02 2.367e-03 3.449351e-01 1.262074e-03 4.096710e-03 -6.000000e+00 2.391974e-02 232.27 -2.00 3.53 -2.00 318.35 0.00e+00 1.061076e-05 2.490322e-04 1.270815e-04 -6.000000e+00 1.061669e-03 288.27 -2.00 20.00 -2.00 317.53 0.00e+00 2.514 0.000 302.00 328.00 3 5.0627e+00 3.4400e-03 3.0819e-02 -6.0000e+00 5.9918e-02 7.9000e-03 3.9068e-03 1.8355e-02 -6.0000e+00 6.4474e-02 2.0827e-03 2.5490e-03 8.9086e-03 -6.0000e+00 3.8430e-02 -5.6990e-03 1.3081e-03 2.4477e-03 -6.0000e+00 1.6245e-02 1.8451e-04 3.1673e-04 7.4622e-05 2.9437e-05 -6.0000e+00 1.1935e-03 -1.5797e-02 2.6721e-04 11 9 0 11 8 0 99.59 27.03 0.25 -0.01580 -0.01342 24 2 1 5 0 2228.750 33.50 20.00 27.03 31.65 9.7 1008.47 6975 13236 -9924 7538 14031 3441 -1247 -5771 19002 -17617 8440 52 -3715 661 922 -11864 -3363 8846 1958 5442 2665 -4806 -5194 270 -1946 -8358 -6724 -4211 -675 1722 -4905 5150 2162 -19 -4890 -3893 -1136 -2950 2761 2786 1557 -3167 215 1454 749 -712 -1119 -1466 -1522 876 -376 6391 -212 87 1705 1279 1383 72 2077 721 562 1035 1572 966 -124 476 1055 -348 -345 1382 -198 201 601 412 -657 319 -963 -852 -3632 -1157 -683 -1119 -2096 -1184 -1144 -9 -60 140 11 197 222 844 584 243 592 140 96 104 590 -675 7 -675 -214 -121 -325 -779 -615 -240 123 -17 89 891 -164 -102 104 221 405 533 125 -268 -468 -539 6 29 52 803 432 905 556 421 359 -113 -397 831 -425 13 231 -336 264 -451 -289 -650 245 279 562 -561 352 570 148 -58 -310 895 -1293 495 3 -285 56 91 -1509 -427 1054 264 739 384 -756 -837 43 -341 -1642 -1321 -785 -116 283 -900 937 444 -4 -1131 -872 -260 -784 827 987 573 -1315 90 615 321 -310 -488 -635 -655 373 -169 2896 -110 48 972 757 837 45 1246 434 344 666 1093 668 -90 333 756 -245 -251 1002 -162 174 530 356 -542 238 -721 -599 -2663 -834 -554 -1021 -2108 -1160 -1190 -10 -71 171 13 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